In early July 2026 I commented on a quite plausible hypothesis that energy from repeated impacts played the primary role in forming the first Hadean crust. That would also help explain why rocks from those early times are vanishingly rare: they may have been remelted and recrystallised numerous times. But there are Hadean zircon grains from the Archaean Jack Hills sandstone of Western Australia that have underpinned a cottage industry for some geochemists for three decades. Such grains must have crystallised from magma, and inherited trace elements from the igneous processes that formed them. An experiment to test the early impact-melt hypothesis appears in a new publication soon to appear in Nature (Szumila, I. and 11 others 2026. A missing continental impact melt sheet signal in the early Earth detrital zircon record. Nature Communications, In press. DOI: 10.1038/s41467-026-76529-w). Led by Ian Szumila of the Carnegie Institute, Washington DC a group of geochemists from the US, UK and Canada compared a range of elements in zircons from the well-established 1.85 Ga impact melt sheet at Sudbury – the largest of its kind preserved on Earth – with those from more typical, internal igneous processes. They used the data from these known settings to ‘train’ a machine-learning model that can be applied to ancient, detrital zircon grains: the ‘unknowns’ with ages between 3.2 to 4.3 Ga.
The Sudbury complex is made up of a basal sheet of mafic igneous rocks (norite and quartz gabbro) and an upper granitic (granophyre) sheet. Essentially, trace-element data from Sudbury zircons result from ‘exogenous’ melting triggered by a massive impact, whereas those formed by internal magmatic processes are of ‘endogenous’ origin. Finding statistically different geochemical features is, however, a tall order as earlier investigations demonstrate. One study comparing the titanium concentration in Sudbury and Hadean zircons found that crystallisation temperatures of those in the accredited impact melt sheet differed from those of Hadean age. This suggested impact melting was not a primary source for the Hadean crystals. Another based on mineral inclusions in the two populations of zircons did support Hadean impact melting, as did a repeat of the Ti approach to crystallisation temperatures. Szumila et al.’s approach using a more sophisticated comparison of a wider range of the zircons’ trace elements seeks to resolve the issue: their U/Yb, Th/U, Yb, and Gd/Yb ratios.
Predicted identity of detrital zircons dated to between 3200 and 4300 Ma: endogenous – pink; exogenous – blue. Credit Szumila et al. Fig 4.
Of the 250 detrital zircon grains dated between 3200 to 4300 Ma-old only a single 4150 Ma-old grain was assigned to an exogenous/impact origin. Apparently, the repeated impact-melt hypothesis for the formation of Earth’s original, Hadean crust is not supported by this experiment. Maybe it did happen, indeed the lunar cratering proxy record for Hadean bombardment of the Earth is unchallengeable. Possibly repeated mega-impacts obliterated and churned up their predecessors’ legacy thereby thermally modifying the tiny zircon grains’ geochemistry before erosion freed them to early and repeatedly reworked sediments. Such a conclusion begs the question of whether or not sustained bombardment repeatedly heated surface water or even boiled it away episodically. On that hangs the vexed question of when self-reproducing organic chemistry was able to result in the earliest life forms: I doubt we will ever know when that fait accompli happened …
Earth’s magnetic field diverts charged particles in the solar ‘wind’
The aspect of geomagnetism that is most familiar to geologists is the magnetic field’s repeated reversals of polarity. It manifests as the magnetic ‘striping’ of modern ocean floors: key to the discovery of plate tectonics. Relatively easy to measure in intricate detail using modern magnetometers, the ‘stripes’ record plate motions back to about the Middle Jurassic (~165 Ma). There are some examples of polarity reversals from Meso- and Neoproterozoic continental rocks but not a continuum. Measuring the direction of remanent magnetism in rock samples in ancient blocks of crust allow geologists to assess their former positions and orientation relative to magnetic poles of the past, and thus evidence of ancient continental drift. Measuring the intensity of past geomagnetism – its field strength – is more difficult than either. That is critically important for Earth’s biosphere because the magnetic field deflects high-energy charged particles from the Sun and cosmic rays that would otherwise reach the surface. Without a geomagnetic field it is possible that living cells could not survive. Even with the modern protective efficiency of geomagnetism, such particles are a likely source of genetic mutations in DNA: a key requirement of biological evolution.
In 2022 an extremely low magnetic field strength – about 15 times less than it is today – was found in a 565 Ma-old anorthosite intrusion from Quebec, Canada that crystallised in the late Ediacaran Period. Samples from as far back as 3500 Ma in the Archaean showed a slow decline in field strength that culminated in its near vanishing in the Ediacaran. This fostered speculation that maybe increased genetic mutation by such an extraterrestrial bombardment of primitive eukaryote cells may have triggered the evolution of the multicelled Ediacara Fauna and perhaps even the first single-celled eukaryotes. A follow up in 2024 by a multinational group of scientists analysed minerals in igneous rocks from South Africa (2054 Ma) and Brazil (591 Ma) to check the magnetic-field strength in the Palaeoproterozoic Era and the Ediacaran Period (Wentao Huang and 16 others, 2024. Near-collapse of the geomagnetic field may have contributed to atmospheric oxygenation and animal radiation in the Ediacaran Period. Nature Communications: Earth and Environment, v. 5, article 207; DOI: 10.1038/s43247-024-01360-4). A more recent study by British and Brazilian geophysicists (Lloyd, S.J. et al. 2026. Earth’s magnetic field remained weak for 40 million years after the Cambrian radiation, Science Advances, v. 12, article eaeg2325; DOI: 10.1126/sciadv.aeg2325) suggested that field strength remained very low until about 505 Ma in the late Cambrian.
The very low magnetic field strength during the Ediacaran (pink), selenium isotope proxy for oxygen availability and radiation of bilaterian and non-bilaterian animals. (Credit: Wentao Huang et al., Fig 3b)
The slow decline in magnetic field strength during the Precambrian probably reflects slowing of turbulent motion in the early, completely molten core as it cooled. Eventually, at the time of very low magnetic field strength around 565 Ma the solid inner core slowly began to form through crystallisation of Fe-Ni alloy, reaching about half its present radius by the end of the Ordovician Period (~450 Ma). This roughly 100 Ma period encompasses the emergence of the Ediacara Fauna and the Cambrian ‘Explosion’ when the basal groups of almost all ‘modern’ eukaryote phyla evolved. Such a geologically swift burst of evolution now seems to be connected to more rapid genetic mutation when the Earth almost lost its ability to be shielded from radiation by its magnetic field. Natural selection had a wealth of options to test, promote or snuff out. To plagiarise the Duke of Wellington, it may have been ‘the nearest run thing you ever saw in your life’. But according to Wentao Huang et al. another beneficial factor for eukaryote evolution may have been that solar-wind bombardment could have split water into its component oxygen and hydrogen. Being so light, hydrogen would have been driven into outer space leaving Earth’s atmosphere with more oxygen, which is vital for eukaryotes.
Ocean floors, especially those of the Pacific and Indian oceans, are bespattered by tens of thousands of seamounts and volcano-based islands. Some of them define chains roughly aligned with the direction of sea-floor spreading and whose age of activity changes progressively along the chains. A few include bends linked to past changes in plate motions (see: The Great Bend of the Pacific Ocean Floor; May 2009). There are also vast, drowned plateaus, which mark oceanic equivalents of flood-basalt provinces on continents. The July 2026 issue of Nature Geoscience is dominated by four papers that are focused on such magmatism within oceanic plates, together with several commentaries and a striking cover image. The findings reported by the authors are briefly summarised by the Issue’s editor and two News & Views items (Editor 9 July 2026. Emerging insights on oceanic intraplate volcanism. Nature Geoscience v. 19, p. 739; DOI: 10.1038/s41561-026-02051-9; Ito, G. 2026. The deep link between intraplate volcanism and plate tectonics. Nature Geoscience v. 19, p. 743-744; DOI: 10.1038/s41561-026-02027-9. Whittaker, J. 2026. Linking plates to plumes in the Cretaceous Pacific. Nature Geoscience v. 19, p. 745-746: DOI: 10.1038/s41561-026-02026-w).
Fig 3-D simulation of geodynamics beneath the Pacific and Indian Ocean floors on the cover of the July 2026 Issue of Nature Geoscience. Credit: Hao Dong, Institute of Geology and Geophysics, Chinese Academy of Sciences.
Age-progressive seamount chains have been ascribed since the birth of plate tectonics to the movement of an oceanic plate over ‘hot spots’ or mantle plumes. Yet the vast majority of sea mounts are apparently distributed at random. They have posed a bone of contention for oceanographers. One of the papers proposes a clear explanation (Hao Dong et al. 2026. Deep mantle plume origin of oceanic intraplate volcanism. Nature Geoscience v. 19, p. 828-836; DOI: 10.1038/s41561-026-02006-0. See also: Iyer, D, 2026 New 270‑Million‑Year Simulation Reveals Hidden Heat Zones Behind Thousands of Seamounts. Bioscience/Marine Science10 June 2026). The authors, based at the Institute of Geology and Geophysics of the Chinese Academy of Sciences, have produced a simulation of changing mantle dynamics beneath the Indian and Pacific Oceans over the last 290 Ma. In their model, hot mantle rising from the core-mantle boundary has repeatedly interacted with the oceanic upper mantle and lithosphere. This rise of hot mantle seems not always to manifest as discrete plumes from the depths. Rather it diffusely heats the asthenosphere to produce large-scale hot regions over which clusters of isolated seamounts formed while the thermal anomaly remained. They liken them to “seamount breweries”, and posit fragmentation of the rising mass of hot mantle, sometimes at depth or within the upper mantle. Such mechanisms drift with the overall mantle and lithospheric flow, so that seamount-volcanoes continue to develop, provided the ‘brewing zones’ retain sufficient heat.
But what might have launched such rising deep mantle? Another study notes that seamount volcanism is more voluminous on ocean floors that once passed over large low-shear-velocity provinces (LLSVPs) in the lowermost mantle beneath Africa and the Pacific Ocean (Conrad, C.P. & Domeier, M. Seamount volcanism associated with Earth’s basal mantle structures. Nature Geoscience v. 19, p. 822-827; DOI: 10.1038/s41561-026-02007-z) These massive deep-mantle provinces are hotter than their surroundings so they are less rigid, which is why seismic S-waves travel more slowly through them. They also lie on opposite sides of the Earth and may have done so for several billion years. Two other, independent studies in the same issue of Nature Geoscience also imply a connection to the deep mantle (Jinchang Zhang et al. 2026. Ontong Java Plateau formed by a thermochemical mantle plume. Nature Geoscience v. 19, p.846-854; DOI: 10.1038/s41561-026-02019-9; Dingshan Deng et al. 2026. Vigorous mantle convection triggered the Cretaceous Pacific large igneous provinces. Nature Geoscience v. 19, p. 837-845; DOI: 10.1038/s41561-026-02016-y).
Extrusion of large igneous provinces (LIPs) on the floor of the Pacific Ocean peaked during the Early Cretaceous. Dingshan Deng and colleagues modelled mantle flow that links subduction, plume activity and mid-ocean ridge activity, which suggests that deep-mantle upwelling peaked around 130 to 125 Ma ago and was driven by increased subduction around the ocean’s margin. This slowed down the rate of spreading at mid-ocean ridges so that heat had to be dissipated by increased melting elsewhere to outpour magma that created LIPs such as the Ontong Java Plateau. The article by Jinchang Zhang et al. focuses on the Ontong Java Plateau, the largest such volcanogenic structure known on Earth. Long regarded as having been produced by a huge buoyant, hot plume, they calculate that such a phenomenon would have had to have uplifted the ocean floor above sea level. That clearly did not happen. To reconcile the sheer volume of magma production with extrusion on deep ocean floor, the authors considered a denser and hotter source mantle, perhaps 135 to 200°C higher than ambient mantle temperature. One possibility is that it had incorporated a lot of older subducted slab materials and was hot enough to thermally erode the plate on which the Ontong Java Plateau was emplaved.
In the 70 years since ideas on plate tectonics began to develop the approach has changed. It began in a ‘compartmentalised’ fashion: spreading at mid-ocean ridges; descent at subduction zones; hot spots and mantle plumes, and so on. Most, if not all Earth scientists involved in this scientific revolution adhered to a reductionist philosophy; i.e. breaking down the hugely complex Earth system into simpler components – the whole is the sum of its parts – an approach begun in the 17th century by by René Descartes. Now, instead of a focus on and separation of cause and effect, it is becoming clearer that the Earth system is fundamentally one of global interconnections, in continuous motion and change. A change in one part inescapably rebounds on all the others, so that the system continually evolves. The tools available to geoscientists have evolved too.
The Hadean Eon (~4.6 to 4.0 Ga) is short on rocks that represent it. In fact geologists only know of a single 20 km2 outcrop within that age span (~4.3 Ga): the Nuvvuagittuq Greenstone Belt (~4.3 Ga)on the eastern shore of Hudson Bay. Even that age remains disputed. But a few, tiny detrital zircon grains extracted from much younger sandstones yield an age range up to 4.4 Ga: barely enough to refute James Hutton’s ‘No vestige of a beginning’. So, the Hadean is long on speculation, most based on less than 3% of all the detrital zircon grains that have been dated. What zircons can tell us is based on their isotopic geochemistry, their trace-element content and even tinier granules of a few other minerals that they encapsulate. The data from them suggest the presence of some kind of felsic magma production that crystallised at low temperatures (~700° C) and was exposed to watery fluids. All very vague compared with what can be gleaned with confidence from post-4.0 Ga rock exposures. But there is a sound astronomical context and a theory based on geophysical and geochemical processes known from experiment and observation of later geology, that can shed a little light.
The planetary system began to form by gravitational accretion of material in a protoplanetary disc of pre-solar gas and dust. The first step would have been gravitational sticking together of dust particles. Fast when this cloud was dense but slowing as the available starting material was depleted by growing planetesimals. This early accretion would easily have radiated away the heat generated by the gravitational potential energy that was released. But that became less effective as the accreting bodies grew to sizes of tens to hundreds of kilometres. Studies of meteorites, formed by collisions of larger planetesimals, show that they became hot enough to melt their contents and even to undergo internal, geochemical differentiation. The current view of the next step is that gravitational perturbations associated with Jupiter drove bodies ranging from asteroidal to Mars size into chaotic motion through the Solar System. Assembly of protoplanets thereafter was dominated by collisions. In the case of the proto-Earth this involved its collision with another, Mars-sized body, to result in the formation of the Moon and the early Earth, each initially enveloped by magma oceans. This event can be considered to be the starting point for all subsequent geological processes on both bodies. But that did not ‘calm down’ planetary bombardment. Plenty of large asteroids were still around: their size range can be judged roughly from those that remain in the Asteroid Belt, that are up to 940 km across in the case of the dwarf planet Ceres. This repository of Hadean objects is what motivated Tim Johnson of Curtin University, Western Australia and three Australian colleagues to ponder on the influence on the Hadean Earth of far more bodies, large and small, hurtling around the early Solar System (Johnson, T.E. et al. 2026. Impact heating and the hidden Hadean. Science, v. 392, p. 1408-1412; DOI: 10.1126/science.aeb5402. PDF requests to tim.johnson@curtin.edu.au).
The impact history of the Earth has largely been expunged by tectonics, erosion and sedimentary burial. Johnson et al. assumed an early impact flux from the almost pristine ‘stratigraphy’ of lunar cratering scaled up to the roughly 13 times greater gravitational pull of the Earth. They calculated that energy being released by impacts and partly incorporated into the Earth during the Hadean outweighed that being generated by internal radioactive decay by several orders of magnitude. Hadean tectonics was thus thermally dominated by impact energy, whose supply probably fluctuated wildly because of different sizes of impacting bodies. By far the largest crater on the Moon – the South Pole-Aitken basin – is 2500 km across. It formed about 4.3 Ga ago when a body 200 km wide struck the lunar surface. Being larger and having a greater gravitational pull, Earth would have suffered up to ten collisions of this magnitude.
In Archaean and later times tectonics became the main means of shedding ‘smoothly’ generated internal radiogenic heating. Dated lunar rock samples strongly suggest that such awesome bombardment lasted until the early Archaean, around 3.8 Ga ago. Traces of this Late Heavy Bombardment are anomalous tungsten isotopes in gneisses of that age from West Greenland (see: Tungsten and Archaean heavy bombardment; July 2002). Internal heating now governs the physical behaviour of rock: whether it is ductile or brittle. Modern-style lithosphere is brittle, hence plate tectonics. The mantle beneath, in the long term, behaves in a ductile fashion, hence convection. As thermal energy built up with each massive impact neither thermal conduction nor bulk convection in the deeper mantle – i.e. the general state of Earth’s present thermal balance – would have been sufficient to check its effects. Rock would need to melt and magma move rapidly in vast amounts to the surface to dissipate energy by radiation into space: by far the most efficient planet-cooling process. The authors also modelled the geotherm – the variation of temperature with depth – established by conductive heat loss and radiation from the surface under Hadean conditions. This is shown in the figure and explained below.
Melting conditions in an early Hadean basaltic crust. Credit: Johnson et al., Fig 4
The thick white line is the modelled conductive geotherm for the ‘coolest’ impact-heating scenario; a usually safe scientific approach. The thin white line shows beginning of melting of hydrous basaltic crust: the ‘mafic solidus’ – the blue area to its left remains solid. The dark to light green shading towards the right marks increasing percentages of basalt melting in 10% steps (dashed white lines). The palest area at right represents a completely molten crust, beyond the ‘mafic liquidus’. The dashed purple line is the liquidus of mantle peridotite. Moving leftwards, the solid purple, pink and orange lines represent the beginning of melting (solidus) for peridotite, anhydrous basalt and sodium-rich granite respectively
The modelled Hadean geotherm shows very rapid temperature increase down to about 7.5 km. It passes across the solidi of granite, hydrous basalt, anhydrous basalt and mantle peridotite: everything begins to melt. Clearly, whatever its composition, the uppermost Hadean crust would have been in a partially molten condition below about 3.5 km. At depths of 10 km or more, between 40 to 70 % of basalt would be molten. The distinction between brittle and ductile becomes meaningless in the light of Johnson et al.’s analysis of Hadean impact heating. Not only does the modelling rule out any rigid lithosphere and plate tectonics during the Hadean, it also explains the almost complete absence today of tangible Hadean rock. In particular, continental crust dominated by granitic rocks was probably recycled continually and literally into the Hadean ‘melting pot’. Convection would have dominated Hadean tectonics, but rather than taking the modern form of isolated plumes it would have been chaotic.
Simulated convective patterns for a Hadean upper mantle subject only to radiogenic heating (A) compared with its dynamic behaviour when heated by continuous heavy bombardment The grey areas represent dense residues left by very high degrees of partial melting at more shallow depths (B). Credit: Johnson et al., Fig 3 A and B.
Suddenly, beginning about 3.9 Ga a rich record of albeit disputed tectonics emerges during the Palaeoarchaean and then evolves onwards to modern planetary behaviour. The heavy bombardment had stopped.
Over the last few decades improved analytical techniques have made it possible to analyse tiny mineral grains for a variety of trace elements and several isotopes. Zircons obtained directly from crushed granitic igneous rocks vary in chemistry according to the magmatic processes that generated them and their tectonic context. Elevated ratios between uranium and niobium (U/Nb) and scandium and ytterbium (Sc/Yb) are characteristic of zircons in intermediate granites. These contain 52 to 63 % SiO2 – between mafic and felsic magmas – which formed by melting of hydrated mafic crust in settings akin to modern continental arcs; i.e. in subduction zones. But such partial melting can also take place where the base of continental crust delaminates and ‘drips’ into the mantle. That process is part of what is known as stagnant lid tectonics, believed by many to have been important in the Palaeoarchaean and Hadean. Such a process would have involved nearly anhydrous conditions and thus different geochemical partitioning of elements in the magmas and minerals that crystallised from them. Exposures of crystalline continental crust become increasingly rare further back in geological time, and there are none older than 4.0 Ga – i.e. of Hadean age – with a granitic component. Consequently studying the generation of continental crust in the Hadean and the early Archaean is almost entirely dependent on ancient zircons that found their way into much younger sedimentary rocks. The most famous of these occur as detrital grains in the 3.6 Ga Jack Hills conglomerate of Western Australia. Others have been extracted from similar ~3.3 Ga sedimentary rocks in the Barberton Greenstone Belt of South Africa and Eswatini.
Cartoon of possible Hadean stagnant lid tectonics, dominated by mantle plumes. (Credit: Bédard, J.H. 2018, Fig 3B, DOI: 10.1016/j.gsf.2017.01.005)
John Valley of the University of Wisconsin-Madison, USA, and co-workers from the US, Germany, Australia and France have worked on a large number of zircons newly extracted from Jack Hills. They have radiometrically dated them, and analysed Nb, Sc, U and Yb trace elements and hafnium (Hf) and oxygen isotopes Together with data from earlier studies, including Barberton zircons, they have teased out some remarkable insights into ‘continent-forming’ magmatism as far back in time as 4.4 billion years ago (Valley, J.W. and 11 others 2026. Contemporaneous mobile- and stagnant-lid tectonics on the Hadean Earth. Nature, Open access; DOI: 10.1038/s41586-025-10066-2). More than 70% of the >4.0 Ga Jack Hills zircons have elevated U/Nb and Sc/Yb ratios, which suggest that they formed in a setting akin to continental-arc subduction (CAS) zones, to produce now-vanished Hadean continental crust. The remainder seem to represent processes at mid-ocean ridge (MOR) and oceanic island (OI) settings. In contrast, the bulk of Barberton zircons of Hadean age show OI affinities, with only around 22% showing Nb–Sc–U–Yb signatures of probable CAS origins. From about 4.4 to 3.8 Ga two distinct forms of continental crust generation seem to have operated on Earth. In the erosional source region for the Barberton zircons their host granites seem to have formed during the Hadean and Eoarchaean by remelting of foundered lower crust, i.e. probably in a stagnant-lid-like tectonic setting. But at around 3.6 Ga they ‘flip’ to a subduction-like setting. The zircons yielded by Jack Hills conglomerates suggest substantially different conditions: alternating CAS and OI settings during the Hadean and a fall-off in crust generation during the Eoarchaean (4.0 to 3.8 Ga).
Plots of Sc/Yb and U/Nb against ages of zircons (vertical scale logarithmic). Black points are from Jack Hills, red from Barberton. The yellow field represents zircons formed in subduction zones; green suggests stagnant lid tectonics; grey the overlap between the two settings. Credit: Valley et al. Fig 3 a and b.
The mixed Hadean zircon signatures from Jack Hills possibly indicate that they were derived by erosion and transport from several distinct terranes that had been generated by two different processes: some kind of upper crustal recycling and stagnant lid tectonics. Meanwhile, that part of the Hadean Earth represented by the Barberton zircons may have been a long-lived regime of stagnant lid tectonics, replaced by dominant subduction at the end of the Eoarchaean. Yet the data suggest that into the Palaeoarchaean (3.6 to 3.2 Ga) and perhaps later, lid tectonics continued to operate somewhere, but at no time after 4.4 Ga was the Earth entirely subject to lid tectonics. Likewise, the authors insist that subduction was not of the plate-tectonic style, referring to some form of recycling of hydrated upper crustal mafic and ultramafic rocks into the mantle to undergo partial melting. Plate tectonics as we know it probably developed later in the Archaean. The early Earth had much higher heat flow than in later times, and thus the lithosphere was more ductile rather than brittle. The essence of modern tectonics is a series of rigid plates that extend down to the asthenosphere. When they deform it is largely through brittle failure of the entire lithosphere.
I must have been about ten years old when I last saw a ‘lucky dip’ or ‘bran tub’ at a Christmas fair. You paid two shillings (now £0.1) to rootle around in the bran for 30 seconds and grab the first sizeable wrapped object that came to hand:. In my case that would be a cheap toy or trinket, but you never knew your luck as regards the top prize. There is a small asteroid called 101955 Bennu, about half a kilometre across, whose orbit around the Sun crosses that of the Earth. So it’s a bit scary, being predicted to pass within 750,000 km of Earth in September 2060 and has a 1 in 1,880 chance of colliding with us between 2178 and 2290 CE. Because Earth-crossing asteroids are a cheaper target than those in the Asteroid Belt, in 2016 NASA launched a mission named OSIRIS-REx to intercept Bennu, image it in great detail, snaffle a sample and ultimately return the sample to Earth for analysis. This wasn’t a shot in the dark, as a lot of effort and funds were expended to target and then visit Bennu. But unlike me at the fair ground, NASA will be very happy with the outcome.
The asteroid Bennu, showing its oblate spheroidal shape, due to rotation, and its rubbly structure. Source: NASA/Goddard/University of Arizona via Wikimedia Commons
Bennu is a product of what might be regarded as ‘space sedimentation’, indeed a kind of conglomerate, being made up of boulders up to 58 m across set in gravelly and finer debris or ‘regolith’. High-resolution images revealed veins of carbonate minerals in the boulders. They suggest hydrothermal activity in a much larger parent body – one of many proto-planets accreted from interstellar gas and dust as the Solar System first began to form over 4.5 billion years ago. Its collision with another sizeable body knocked off debris to send a particulate cloud towards the Sun, subsequently to clump together as Bennu by mutual gravitational attraction. The carbonate veins can only have formed by circulation of water inside Benno’s parent.
The ‘REx’ in the mission’s name is an acronym for ‘Regolith Explorer’. Sampling was accomplished on 20 October 2020 by a soft landing that drove a sample into a capsule, and then OSIRIS-REx ‘pogo-sticked’ off with the booty. The capsule was dropped off by parachute after the mission’s return on 24 September 2023, in the manner of an Amazon delivery by drone to a happy customer. So, you can understand my ‘lucky dip’ metaphor. And NASA certainly was ‘lucky’ as the contents turned out to be astonishing, as related two years later by the analytical team in the US, led by NASA’s Angel Mojarro (Mojarro, A. et al. 2025.Prebiotic organic compounds in samples of asteroid Bennu indicate heterogeneous aqueous alteration. Proceedings of the National Academy of Science, v. 122, article e2512461122; DOI: 10.1073/pnas.2512461122).
The rock itself is made from bits of carbonaceous chondrite, the most primitive matter orbiting the Sun. It contains fifteen amino acids, including all five nucleobases that make up RNA and DNA – adenine (A), guanine (G), cytosine (C), thymine (T) and uracil (U) – as in AUGC and AGCT. Benno’s complement of amino acids included 14 of the 20 used by life on Earth to synthesise proteins. The fifteenth, tryptophan, has never confidently been seen in extraterrestrial material before. Alkylated polycyclic aromatic hydrocarbons, also found in Bennu, are seen in abundance in interstellar gas clouds and comets by detecting their characteristic fluorescence when illuminated by mid-infrared radiation from hot stars using data from the Spitzer and James Webb Space Telescopes. These prebiotic organic compounds have been suggested to have played a role in the origin of life, but exposure to many produced by human activities are implicated in many cancers and cardiovascular issues. A second paper by Japanese biochemists and colleagues from the US was also published in early December 2025 (Furukawa, Y. and 13 others 2025. Bio-essential sugars in samples from asteroid Bennu. Nature Geoscience, v. 12, online article; DOI: 10.1038/s41561-025-01838). The authors identified several kinds of sugars in a sample from Bennu, including ribose – essential for building RNA – and glucose. Bennu also contains formaldehyde – a precursor of sugars – perhaps originally in the same brines in which the amino acids formed.
Yet another publication coinciding with the aforementioned two focuses on products of the oldest event in the formation of Bennu: its content of pre-solar grains (Nguyen, A.N. et al. 2025. Abundant supernova dust and heterogeneous aqueous alteration revealed by stardust in two lithologies of asteroid Bennu. Nature Astronomy, v. 9, p. 1812-1820; DOI: 10.1038/s41550-025-02688-3). In 1969 a 2 tonne carbonaceous chondrite fell near Allende in Mexico. The largest of this class ever found, it contained tiny, pale inclusions that eight years of research revealed to represent materials completely alien to the Solar System. They are characterised by proportions of isotopes of many elements that are very different from those in terrestrial materials. The anomalies could only have formed by decay of extremely short-lived isotopes that highly energetic cosmic rays produce in a manner analogous to neutron bombardment: they are products of nuclear transmutation. It is possible to estimate when the parent isotopes produced the anomalous ‘daughter’ products. One study found ages ranging from 4.6 to 7.5 Ga: up to three billion years before the Solar System began to form. It is likely that the grains are literally ‘star dust’ formed during supernovae in nearby parts of the Milky Way galaxy. Bennu samples contain six-times more presolar grains than any other chondritic meteorites. Nguyen et al. geochemically teased out grains with different nucleosynthetic origins. These ancient relics point to Bennu’s formation in a region of the presolar cloud that preceded the protoplanetary disk and was a mix of products from several stellar settings.
The results from asteroid Bennu support the key idea that that amino acid building blocks for all proteins and the nucleobases of the genetic code, together with other biologically vital compounds arose together in a primitive asteroid. Its evolution provided the physical conditions, especially the trapping of water, for the interaction of simpler components manufactured in interstellar clouds. Such ‘fertile’ planetesimals and debris from them almost certainly accreted to form planets and endowed them with the potential for life. What astonishes me is that Bennu contains the five nucleobases used in terrestrial genetics and 70% of the amino acids from which all known proteins are assembled by terrestrial life. But, as I try to explain in my book Stepping Stones: The Making of Our Home World, life as we know it arose, survived and evolved through a hugely complex concatenation of physical and chemical events lasting more than 4.5 billion years. The major events and the sequences in which they manifested themselves may indeed have been unique. Earth is a product of luck and so are we!
Artist’s impression of the impact of a roughly Mars-size planet with the proto-Earth to form an incandescent cloud, from part of which the Moon formed.
Geochemists have gradually built a model of the proportions of the 92 naturally occurring elements that characterise the Solar System. It is based on systematic chemical analysis of meteorites, especially the ‘stony’ ones. One hypothesis for Earth formation is that the bulk of it chemically resembles a class of meteorites known as C1 carbonaceous chondrites. But there are important deviations between that and reality. For instance the relative proportions of the isotopes of several elements in meteorites have been found to differ. Because nuclei of all the elements and their individual isotopes have been shown to form in supernovae through nucleosynthesis, such instances are known as ‘nucleosynthetic anomalies’. An example is that of the isotopes of potassium (K), which was investigated by a team of geochemists from the Carnegie Institution for Science in Washington DC, USA and the Chengdu University of Technology, China led by Nicole Nie (Nie, N.X. et al. 2023. Meteorites have inherited nucleosynthetic anomalies of potassium-40 produced in supernovae. Science, v.379, p, 372-376; DOI: 10.1126/science.abn1783).
A measure for the magnitude of this nucleosynthetic anomaly is the ratio between the abundance in a sample of potassium’s rarest (40K) and its most common isotope (39K), divided by the ratio in an accepted standard of terrestrial rock. Since isotopically identical samples would yield a value of 1, the result has 1.0 subtracted from it to emphasise anomalies. Samples that are relatively depleted in 40K give negative values, whereas enriched samples give positive values. This measure is signified by ε40K, ε being the Greek letter epsilon. The authors found significant and variable positive anomalies of ε40K in carbonaceous chondrite (CC) meteorites, compared with non-carbonaceous (NC) meteorites. They also found that ε40K data in terrestrial rocks are quite different from those of CC meteorites. Indeed, they suggested that Earth was more likely to have formed from NC meteoritic material. Clearly, there seems to be something seriously amiss with the hypothesis that Earth largely accreted from C1 carbonaceous chondrites.
The correlation between ε40K and ε100Ru in meteorites (EC – enstatite chondrites, OC – ordinary chondrites; CC – carbonaceous chondrites), Earth and a geochemically modelled proto-Earth. Credit: Da Wang et al., Fig 2
Three of the authors of Nie et al. and other researchers from MIT in Cambridge MA and Scripps Institution of Oceanography in San Diego CA, USA and ETH in Zurich, Switzerland have produced more extensive potassium isotope data to examine Earth’s possible discrepancy with the chondritic Earth hypothesis (Da Wang et al. 2025. Potassium-40 isotopic evidence for an extant pre-giant-impact component of Earth’s mantle. Nature Geoscience, v. 18, online article; DOI: 10.1038/s41561-025-01811-3). To better approximate the bulk Earth’s potassium isotopes they analysed a large number of terrestrial rock samples of all kinds and ages to compare with meteorites of different classes. Meteorites also have variable nucleosynthetic anomalies for ruthenium-100 (ε100Ru). So, ε40K and ε100Ru may be useful tracers with regards to Earth’s history. But, for some reason, the research group did not analyse ruthenium isotopes in the terrestrial samples.
Most samples of igneous rocks from different kinds of Phanerozoic volcanic provinces (continental flood basalts, island arcs, and ocean ridge basalts) showed no evidence of anomalous potassium isotopes. However, some young ocean-island basalts from Réunion and Hawaii showed considerable depletion in 40K. A quarter of early Archaean (>3.5 Ga) metamorphosed basaltic rocks from greenstone belts also showed clear 40K depletion. Yet no samples of granitic crust of similar antiquity showed any anomaly and nor did marine sediments derived from younger continental crust. Even the oldest known minerals – zircon grains from Jack Hills Western Australia – showed no anomalies. The authors suggest that both the anomalous groups of young and very ancient terrestrial basalts show signs that their parent magmas may have formed by partial mantle melting of substantial bodies of the relics of proto-Earth. To account for this anomalous mantle Da Wang et al. suggest from modelling that proto-Earths 40K deficit may have arisen from early accretion of meteorites with that property. Later addition of material more enriched with that isotope, perhaps as meteorites or through the impact with a smaller planet that triggered Moon-formation. That cataclysm was so huge that it left the Earth depleted in ‘volatile’ elements and in a semi-molten state. It reset Earth geochemistry as a result of several processes including the mixing induced by very large-scale melting. No radiometric dating has penetrated that far back in Earth history. However, in February 2004, Alex Halliday used evidence from several isotopic systems (Pb, Xe, Sr, W) to show that about two thirds of Earth’s final mass may have accreted in the first 11 to 40 Ma of its history.
Curiously, none of the hundreds of meteorites that have been geochemically analysed show the level of 40K depletion in the terrestrial samples. Nicole Nie has comments, “… our study shows that the current meteorite inventory is not complete, and there is much more to learn about where our planet came from.”
I’m persuaded to write this by ‘Piso Mojado’. And today – 23rd October – is the anniversary of the Creation of Earth, Life and the Universe in 4004 BCE, according to Archbishop James Ussher (1581-1656) by biblical reckoning, which always tickles me!
Since 1999, the rocks generally acknowledged to be the oldest on Earth were part of the Acasta gneisses in the Slave Craton in Canada’s Northwest Territories; specifically the Idiwhaa tonalitic gneisses. Zircons extracted from that unit yielded an age of 4.02 billion years (Ga) using U-Pb radimetric dating, revealing the time of their crystallisation from granitic magma. But nine years later some metabasaltic rocks from the tiny (20 km2) Nuvvuagittuq Greenstone Belt on the eastern shore of Hudson Bay were dated using the Sm-Nd method at almost 4.3 Ga (see: At last, 4.0 Ga barrier broken; November 2008). Taken at face value the metabasaltic rocks seemed to be well within the Hadean Eon (4.6 to 4.0 Ga) and could thus represent primary crust of that antiquity. However, U-Pb dating of zircons from thin sodium-rich granitic rocks (trondhjemites) that intrude them yielded ages no older than about 3.8 Ga. Similar ages emerged from zircons found in metasediments interleaved in the dominant mafic unit. Discrepancies between the two completely different dating methods resulted in the Hadean antiquity of the mafic rocks having been disputed since 2008. It was possible that the Sm-Nd results from the metabasalts may have resulted from the original mafic magmas having inherited a Hadean Sm-Nd isotopic ‘signature’ from their mantle source. That is, they may have been contaminated and could have formed in the early Archaean.
Glacially smoothed outcrops near Inukjuak, Quebec that reveals rocks of the Nuvvuagittuq Greenstone Belt. Credit: Jonathan O’Neil, University of Ottawa
Jonathan O’Neil, now at Ottawa University in Canada, led the first isotopic investigation of the Nuvvuagittuq Greenstone Belt and has engaged in research there ever since. Further field and laboratory studies revealed that the previously dated mafic rocks had been intruded by large, chemically differentiated gabbro sills. A team of geochemists from the University of Ottawa and Carleton University, including O’Neil, has now published isotopic evidence from the intrusions that suggests a Hadean age for their parent magma (C. Sole et al. 2025. Evidence for Hadean mafic intrusions in the Nuvvuagittuq Greenstone Belt, Canada. Science, v. 388, p. 1431-1435. DOI: 10.1126/science.ads8461). The authors used the decay schemes of two radioactive samarium isotopes 147Sm and 146Sm; a significant advance in radiometric dating. The first decays to 143Nd with a half-life of about 1011 years, the second to 142Nd with a much shorter half life of about 108 years. Due to its more rapid decay, in geological terms,146Sm is now much rarer than 147Sm. Consequently, using the short-lived 146Sm-142Nd decay system is technically more difficult than that of the 147Sm-143Nd system. But the team managed to get good results from both the ‘fast’ and the ‘slow’ decay schemes. They tally nicely, yielding ages of 4157 and 4196 Ma. The gabbros provide a minimum age for the metabasalts that they cut through. The original 4.3 Ga Sm-Nd date for the metabasalts is thus plausible. Sole and colleagues consider the dominant metabasaltic rocks to have formed a primary crust in late Hadean times that was invaded by later mantle-derived mafic magma about 100 Ma later. The granitic rocks that constitute about one third of the Nuvvuagittuq terrain seem to have been generated by partial melting more than 300 Ma later still, during the Palaeoarchaean.
Perhaps similar techniques will now be deployed in granite-greenstone terrains in other cratons. Many of the older ones, generally designated as Palaeoarchaean in age, also contain abundant metamorphosed mafic and ultramafic igneous rocks. Perhaps their origin was akin to those of Nuvvuagittuq; i.e. more Hadean crust may await unmasking. Meanwhile, there seems to be more to discover from Nuvvuagittuq. For instance, some of the rocks suggested to be metasediments interleaved in the metabasalts show intricate banding that resembles products of bacterial mat accumulation in younger terrains. Signs of Hadean life?
Since the first reliable radiometric dating of Archaean rocks in 1971, there has been an element of competition to date the oldest rocks on Earth: to push history back towards the initial formation of the Earth. It is one of the most disputatious branches of Earth history. Rivalry may play a significant part in driving the science, as well as the development of novel dating techniques and the continuing discovery of clearly old relationships using ‘old-fashioned’ relative dating, such as signs of intrusion, unconformities etcetera. But in some cases there is a darker side: the potential for profit. Recently, samples from Nuvvuagittuq appeared for sale on the Internet, priced at $10,000. They may have been collected under the guise of supplying museums by a group that shipped-in mechanical excavators in 2016. Unsurprisingly this angered the local Innuit community of Inukjuak. They were also worried about bona fide collection for scientific research that had left parts of the small, once pristine area somewhat battered, including cultural features such as an inukshuk navigational monument. Their fury at commercial exploitation of their homeland resulted in the community council closing the area to collecting in 2024. I emphasise that this violation of basic geological ethics was by commercial rock collectors and dealers, not academic geologists. The local people are now considering careful issue of research permits so that important research can continue. But further rock collecting may remain banned.
False-colour electron microscope image of a shocked grain of zircon recovered from the Stac Fada Member. The red and pink material is a high-pressure polymorph of zircon, arranged in shock lamellae. Zircon is rendered in cyan, some of which is in granulated form. Credit: Kirkland et al. 2025, Fig 2C
Judging by its content of shards and spherules made of murky green glass, one of the lowest units in the Torridonian continental sediments of NW Scotland had long been regarded as simply red sandstone that contained volcanic debris. This Stac Fada Member was thus celebrated as the only sign of a volcanic contribution to a vast thickness (up to 2.5 km) of Neoproterozoic lake and fluviatile sediments. Current flow indicators suggested that the Torridonian was laid down by large alluvial fans derived by erosion of much older crystalline basement far to what is today the west. That is, the Archaean core of the ancient continent of Laurentia, now the other side of the North Atlantic. In 2002 more sophisticated sedimentological and geochemical analysis of the Stac Fada Member revealed a surprise: it contains anomalously elevated platinum-group elements, quartz grains that show signs of shock and otherworldly chromium isotope concentrations. The 10 m thick bed is made from ejecta, perhaps from a nearby impact crater to the WNW concluded from brittle fractures that may have been produced by the impact. Some idea of its age was suggested by Ar-Ar dating of feldspar crystals (~1200 Ma) believed to have formed authigenically in the hot debris. Being the only decent impactite known in Britain, it continues to attract attention.
A group of geoscientists from Western Australia, NASA and the UK, independent of the original discoverers, have now added new insights ( Kirkland, C.L. and 12 others 2025. A one-billion-year old Scottish meteorite impact. Geology, v. 53, early online publication; DOI: 10.1130/G53121.1). They dated shocked zircon grains using U-Pb analyses at 990 ± 22 Ma; some 200 Ma younger than the previously dated, authigenic feldspars. Detrital feldspar grains in the Stac Fada Member yield Rb-Sr radiometric ages of 1735 and 1675, that are compatible with Palaeoproterozoic granites in the underlying Lewisian Gneiss Complex.
Photomicrograph of Bicellum brazieiri: scale bar = 10μm; arrows point to dark spots that may be cell nuclei (credit: Charles Wellman, Sheffield University)
In a separate publication (Kirkland, C.L et al 2025. 1 billion years ago, a meteorite struck Scotland and influenced life on Earth. The Conversation, 29 April 2025) three of the authors take things a little further, as their title suggests. In this Conversation piece they ponder, perhaps unwarily, on the spatial and temporal association of the indubitable impact with remarkably well-preserved spherical fossils found in Torridonian lake-bed sediments (Bicellum brasieri, reported in Earth-logs in May 2021), which are the earliest-known holozoan animal ancestors. The Torridonian phosphatic concretions in which these important fossils were found at a different locality are roughly 40 Ma younger than the Stac Fada impactite. The authors of the Conversation article appeal to the residual thermal effect of the impact as a possible driver for the appearance of these holozoan organisms. Whether a residual thermal anomaly would last long enough for them to evolve to this biological status would depend on the magnitude of the impact, of which we know nothing. Eukaryote fossils are known from at least 650 Ma older sedimentary rocks in northern China and perhaps as far back as 2.2 Ga in a soil that formed in the Palaeoproterozoic of South Africa. Both the Torridonian organism and impactite were found in a small area of fascinating geology that has been studied continuously in minute detail since Victorian times, and visited by most living British geologists during their undergraduate days. Ideas will change as curiosity draws geologists and palaeobiologists to less-well studied sites of Proterozoic antiquity, quite possibly in northern China.
A fully revised edition of Steve Drury’s book Stepping Stones: The Making of Our Home World can now be downloaded as a free eBook
Judging by the coverage in the media, there is huge excitement about a possible sign of life on a very distant planet. It emerged from a Letter to The Astrophysical Journal posted by a British-US team of astronomers led by Nikku Madhusudhan that was publicised by the Cambridge University Press Office (Madhusudhan, N.et al. 2025. New Constraints on DMS and DMDS in the Atmosphere of K2-18 b from JWST MIRI. The Astrophysical Journal, v. 983, article adc1c8; DOI: 10.3847/2041-8213/adc1c8). K2-18 b is a planet a bit smaller than Neptune that orbits a red dwarf star (K2-18) about 124 light years away. The planet was discovered by NASA’s now-defunct Kepler space telescope tasked with the search for planets orbiting other stars. An infrared spectrometer on the Hubble Space Telescope revealed in 2019 that the atmosphere of K2-18 b contained water vapour, making the planet a target for further study as it may possess oceans. The more sophisticated James Webb Space Telescope IR spectrometer was trained on it a year later to reveal methane and CO2: yet more reason to investigate more deeply, for water and carbon compounds imply both habitability and the potential for life forms being there.
The latest results suggest that that the atmosphere of K2-18 b may contain simple carbon-sulfur gases: dimethyl sulfide ((CH3)2S) and dimethyl disulfide (CH3SSCH3). Bingo! for exobiologists, because on Earth both DMS and DMDS are only produced by algae and bacteria. Indeed they are responsible for the odour of the seaside. They became prominent in 1987 when biogeochemist James Lovelock fitted them into his Gaia Hypothesis. He recognised that they encourage cloud formation and thus increase Earth’s reflectivity (albedo) and also yield sulfuric acid aerosols in the stratosphere when they oxidise: that too increases albedo. DMS generates a cooling feedback loop to counter the warming feedback of greenhouse emissions. That is an idea of planetary self-regulation not much mentioned nowadays. Such gases were proposed by Carl Sagan as unique molecular indicators that could be used to search for extraterrestrial life.
The coma of Comet Churyumov-Gerasimenko yielded both dimethyl sulfide and amino acids to the mass spectrometer carried by ESA’s Rosetta. Credit: ESA.
The discovery of possible DMS and DMDS in K2-18 b’s atmosphere is, of course, currently under intense scientific scrutiny. For a start, the statistics inherent in Madhusudhan et al.’s methodology (3σ or 99.7% probability) fall short of the ‘gold standard’ for discoveries in physics (5σ or 99.99999% probability). Moreover, there’s also a chance that exotic, inorganic chemical processes could also create the gases, such as lightning in an atmosphere containing C, H and S. But this is not the first time that DMS has been discovered in an extraterrestrial body. Comets, having formed in the infancy of the Solar System much further from the Sun than any planets, are unlikely to be ‘teeming with life’. The European Space Agency’s Rosetta spacecraft chased comet 67P/Churyumov-Gerasimenko for 2 years, directly sampling dust and gas that it shed while moving closer to the Sun. A single day’s data from Rosetta’s mass spectrometer showed up DMS, and also amino acids. Both could have formed in comets or interstellar dust clouds by chemistry driven by radiation, possibly to contaminate planetary atmospheres. Almost certainly, further remote sensing of K2-18 b will end up with five-sigma precision and some will say, ‘Yes, there is life beyond Earth!’ and celebrate wildly. But that does not constitute proof, even by the ‘weight of evidence’ criterion of some judiciaries. To me such a conclusion would be unseemly romanticism. Yet such is the vastness of the material universe and the sheer abundance of the elements C H O N and P that make up most living matter that life elsewhere, indeed everywhere, (but not life as we know it) is a near certainty. The issue of intelligent lifeforms ‘out there’ is, however, somewhat less likely to be resolved . . .
Earth has been through a great many catastrophes, but the vast majority of those of which we know were slow-burning in a geological sense. They resulted in unusually high numbers of extinctions at the species- to family levels over a few million years and the true mass extinctions seem to have been dominated by build ups of greenhouse gases emitted by large igneous provinces. Even the most famous at the end of the Cretaceous Period, which did for the dinosaurs and considerably more organisms that the media hasn’t puffed, was partly connected to the eruption of the Deccan flood basalts of western India. Yet the event that did the real damage was a catastrophe that appeared in a matter of seconds: the time taken for the asteroid that gouged the Chicxulub crater to pass through the atmosphere. Its energy was huge and because it was delivered in such a short time its sheer power was unimaginable. Gradually geologists have recognised signs of an increasing number of tangible structures produced by Earth’s colliding with extraterrestrial objects, which now stands at 190 that have been confirmed.
Landsat image mosaic of the Palaeoarchaean granite-greenstone terrain of the Pilbara Craton, Western Australia. Granite bodies show as pale blobs, the volcanic and sedimentary greenstone belts in shades of grey. The site of Kirkland et al.’s study site is at the tip of the red arrow
The frequency of impact craters falls off with age, most having formed in the last ~550 million years (Ma) during the Phanerozoic Eon, only 25 being known from the Precambrian, which spanned around 88 percent of geological time. That is largely a consequence of the dynamic processes of tectonics, erosion and sedimentation that may have obliterated or hidden a larger number. Earth is unique in that respect, the surfaces of other rocky bodies in the Solar System showing vastly more. The Moon is a fine example, especially as it has been Earth’s companion since it formed 4.5 billion years ago (Ga) after the proto-Earth collided with a now vanished planet about the size of Mars. The relative ages of lunar impact structures combined with radiometric ages of the surfaces that they hit has allowed the frequency of collisions to be assessed through time. Applied to the sizes of the craters such data can show how the amount of kinetic energy inflicted on the lunar surface has changed with time. During what geologists refer to as the Hadean Eon (before 4 Ga), the moon underwent continuous bombardment that reached a crescendo between 4.1 and about 3.8 Ga. Thereafter impacts tailed off. Always having been close to the Moon, the Earth cannot have escaped the flux of objects experienced by the lunar surface. Because of Earth’s much greater gravitation pull it was probably hit by more objects per unit area. Apart from some geochemical evidence from Archaean rocks (see: Tungsten and Archaean heavy bombardment; July 2002) and several beds of 3.3 Ga old sediment in South Africa that contain what may have been glassy spherules there are no signs of actual impact structures earlier than a small crater dated at around 2.4 Ga in NE Russia.
Shatter cones in siltstone near Marble Bar in the Pilbara Province: finger for scale. Credit: Kirkland et al.; Fig 2a
Now a group of geologists from Curtin University, Perth Western Australia, and the Geological Survey of Western Australia have published their findings of indisputable signs of an impact site in the northern part of Western Australia (Kirkland, C.L. et al. 2025. A Paleoarchaean impact crater in the Pilbara Craton, Western Australia. Nature Communications, v. 16, article 2224; DOI: 10.1038/s41467-025-57558-3). In fact there is no discernible crater at the locality, but sedimentary strata show abundant evidence of a powerful impact in the form of impact-melt droplets in the form of spherules together with shatter cones. These structures form as a result of sudden increase in pressure to 2 to 30 GPa: an extreme that can only be generated in underground nuclear explosions, and thus likely to bear witness to large asteroid impacts. The shocked rocks are immediately overlain by pillow lavas dated at 3.47 Ga, making the impact the earliest known. It has been speculated that impacts during the Archaean and Hadean Eons helped create conditions for the complex organic chemistry that eventually to the first living cells. Considering that entry of hypervelocity asteroids into the early Earth’s atmosphere probably caused such compression that temperatures were raised by adiabatic heating to about ten times that of the Sun’s surface, their ‘entry flashes’ would have sterilised the surface below; the opposite of such notions. Impacts may, however, have delivered both water and simple, inorganic hydrocarbons. Together with pulverisation of rock to make ‘fertiliser’ elements (e.g. K and P) more easily dissolved, they may have had some influence. Their input of thermal energy seems to me to be of little consequence, for decay of unstable isotopes of U, Th and K in the mantle would have heated the planet quite nicely and continuously from Year Zero onwards.
A fully revised edition of Steve Drury’s book Stepping Stones: The Making of Our Home World can now be downloaded as a free eBook
A consortium of geoscientists from Australia, Britain and France, led by Andrew Merdith of the University of Adelaide examines the likely climate cooling mechanisms that may have set off the two great ‘icehouse’ intervals in the last 541 Ma (Merdith, A.S. et al. 2025. Phanerozoic icehouse climates as the result of multiple solid-Earth cooling mechanisms. Science Advances, v. 11, article eadm9798: DOI: 10.1126/sciadv.adm9798). They consider the first to be the global cooling that began in the latter part of the Devonian culminating in the Carboniferous-Permian icehouse. The second is the Cenozoic global cooling to form the permanent Antarctic ice cap around 34 Ma and culminated in cyclical ice ages on the northern continents after 2.4 Ma during the Pleistocene. They dismiss the 40 Ma long, late Ordovician to early Silurian glaciation that left its imprint on North Africa and South America – then combined in the Gondwana supercontinent. The data about two of the parameters used in their model – the degree of early colonisation of the continents by plants and their influence on terrestrial weathering are uncertain in that protracted event. Yet the Hirnantian glaciation reached 20°S at its maximum extent in the Late Ordovician around 444 Ma to cover about a third of Gondwana: it was larger than the present Antarctic ice cap. For that reason, their study spans only Devonian and later times.
Fluctuation in evidence for the extent of glacial conditions since the Devonian: the ‘ice line’ is grey. The count of glacial proxy occurrences in each 10° of latitude through time is shown in the colour key. Credit: Merdith et al., Fig 2A.
Merdith et al. rely on four climatic proxies. The first of these comprises indicators of cold climates, such as glacial dropstones, tillites and evidence in sedimentary rocks of crystals of hydrated calcium carbonate (ikaite – CaCO3.6H2O) that bizarrely forms only at around 0°C . From such occurrences it is possible to define an ‘ice line’ linking different latitudes through geological time. Then there are estimates of global average surface temperature; low-latitude sea surface temperature; and estimates of atmospheric CO2. The ‘ice-line’ data records an additional, long period of glaciation in the Jurassic and early Cretaceous, but evidence does not extend to latitudes lower than 60°. It is regarded by Merdith et al. as an episode of ‘cooling’ rather than an ‘icehouse’. Their model assesses sources and sinks of CO2 since the Devonian Period.
The main natural source of the principal greenhouse gas CO2 is degassing through volcanism expelled from the mantle and breakdown of carbonate rock in subducted lithosphere. Natural sequestration of carbon involves weathering of exposed rock that releases dissolved CO2 and ions of calcium and magnesium. A recently compiled set of plate reconstructions that chart the waxing and waning of tectonics since the Devonian Period allows them to model the tectonically driven release of carbon over time, with time scales on the order of tens to hundreds of Ma. The familiar Milanković forcing cycles on the order of tens to hundreds of ka are thus of no significance in Merdith et al.’s broader conception of icehouse episodes Their modelling shows high degassing during the Cretaceous, modern levels during the late Palaeozoic and early Mesozoic, and low emissions during the Devonian. The model also suggests that cooling stemmed from variations in the positions and configuration of continents over time. Another crucial factor is the tempo of exposure of rocks that are most prone to weathering. The most important are rocks of the ocean lithosphere incorporated into the continents to form ophiolite masses. The release of soluble products of weathering into ocean basins through time acts as a fluctuating means of ‘fertilising’ so that more carbon can be sequestered in deep sediments in the form of organisms’ unoxidised tissue and hard parts made of calcium carbonates and phosphates. Less silicate weathering results in a boost to atmospheric CO2.
Only two long, true icehouse episodes emerge from the empirical proxy data, expressed by the ‘ice-line’ plots. Restricting the modelling to single global processes that might be expected to influence degassing or carbon sequestration produces no good fits to the climatic proxy data. Running the model with all the drivers “off” produces more or less continuous icehouse conditions since the Devonian. The model’s climate-related outputs thus imply that many complex processes working together in syncopation may have driven the gross climate vagaries over the last 400 Ma or so. A planet of Earth’s size without such complexity would throughout that period have had a high-CO2 warm climate. According to Andrew Merdith its fluctuation from greenhouse to icehouse conditions in the late Palaeozoic and the Cenozoic were probably due to “coincidental combination of very low rates of global volcanism, and highly dispersed continents with big mountains, which allow for lots of global rainfall and therefore amplify reactions that remove carbon from the atmosphere”.
Geological history is, almost by definition, somewhat rambling. So, despite despite the large investment in seeking a computed explanation of data drawn from the record, the outcome reflects that in a less than coherent account. To state that many complex processes working at once may have driven climate vagaries over the last 400 Ma or so, is hardly a major advance: palaeoclimatologists have said more or less the same for a couple of decades or more, but have mainly proposed single driving mechanisms. One aspect of Merdith et al.’s results seems to be of particular interest. ‘Icehouse’ conditions seem to be rare events interspersed with broader ice-free periods. We evolved within the mammal-dominated ecosystems on the continents during the latest of these anomalous climatic episodes. And we and those ecosystems now rely on a cool world. As the supervisor of the project commented, ‘Over its long history, the Earth likes it hot, but our human society does not’.
Readers may like to venture into how some philosophers of science deal with a far bigger question; ‘Is intelligent life a rare, chance event throughout the universe?’ That is, might we be alone in the cosmos? In the same issue of Science Advances is a paper centred on just such questions (Mills, D.B. et al. 2025. A reassessment of the “hard-steps” model for the evolution of intelligent life. Science Advances, v. 11, article eads5698; DOI: 10.1126/sciadv.ads5698). It stems from cosmologist Brandon Carter’s ‘Anthropic Principle’ first developed at Nicolas Copernicus’s 500th birthday celebrations in 1973. This has since been much debated by scientists and philosophers – a gross understatement as it knocks the spots off the Drake Equation. To take the edge off what seems to be a daunting task, Mills et al. consider a corollary of the Anthropic Principle, the ‘hard steps model’. That, in a nutshell, postulates that the origin of humanity and its ability to ponder on observations of the universe required a successful evolutionary passage through a number of hard steps. It predicts that such intelligence is ‘exceedingly rare’ in the universe. Icehouse conditions are respectable candidates for evolutionary ‘hard steps’, and in the history of Earth there have been five of them.
A fully revised edition of Steve Drury’s book Stepping Stones: The Making of Our Home World can now be downloaded as a free eBook
Debates around the origin of Earth’s life and what the first organism was like resemble the mythical search for the Holy Grail. Chivalric romanticists of the late 12th and early 13th centuries were pretty clear about the Grail – some kind of receptacle connected either with the Last Supper or Christ’s crucifixion – but never found it. Two big quests that engage modern science centre on how the chemical building blocks of the earliest cells arose and the last universal common ancestor (LUCA) of all living things. Like the Grail’s location, neither is likely to be fully resolved because they can only be sought in a very roundabout way: both verge on the imaginary. The fossil record is limited to organisms that left skeletal remains, traces of their former presence, and a few degraded organic molecules. The further back in geological time the more sedimentary rock has either been removed by erosion or fundamentally changed at high temperatures and pressures. Both great conundrums can only be addressed by trying to reconstruct processes and organisms that occurred or existed more than 4 billion years ago.
Artistic impression of the early Earth dominated by oceans (Credit: Sci-news.com)
In the 1950s Harold Urey of the University of Chicago and his student Stanley Miller mixed water, methane, ammonia and hydrogen sulfide in lab glassware, heated it up and passed electrical discharges through it. They believed the simple set-up crudely mimicked Hadean conditions at the Earth surface. They were successful in generating more complex organic chemicals than their starting materials, though the early atmosphere and oceans are now considered to have been chemically quite different. Such a ‘Frankenstein’ approach has been repeated since with more success (see Earth-logs April 2024), creating 10 of the 20 amino acids plus the peptide bonds that link them up to make all known proteins, and even amphiphiles, the likely founders of cell walls. The latest attempt has been made by Spanish scientists at the Andalusian Earth Sciences Institute, the Universities of Valladolid and Cadiz, and the International Physics Centre in San Sebastian (Jenewein, C. et al 2024. Concomitant formation of protocells and prebiotic compounds under a plausible early Earth atmosphere. Proceedings of the National Academy of Sciences, v. 122, article 413816122; DOI: 10.1073/pnas.241381612).
Biomorphs formed by polymerisation of HCN (Credit: Jenewein, C. et al 2024, Figure 2)
Jenewein and colleagues claim to have created cell-like structures, or ‘biomorphs’ at nanometre- and micrometre scale – spheres and polyp-like bodies – from a more plausible atmosphere of CO2 , H2O, and N2. These ‘protocells’ seem to have formed from minutely thin (150 to 3000 nanometres) polymer films built from hydrogen cyanide that grew on the surface of the reaction chamber as electric discharges and UV light generated HCN and more complex ‘prebiotic’ chemicals. Apparently, these films were catalysed by SiO2 (silica) molecules from the glass reactor. Note: In the Hadean breakdown of olivine to serpentinite as sea water reacted with ultramafic lavas would have released abundant silica. Serpentinisation also generates hydrogen. Intimate release of gas formed bubbles to create the spherical and polyp-like ‘protocells’. The authors imagine the Hadean global ocean permanently teeming with such microscopic receptacles. Such a veritable ‘primordial soup’ would be able to isolate other small molecules, such as amino acids, oligopeptides, nucleobases, and fatty acids, to generate more complex organic molecules in micro-reactors en route to the kind of complex, self-sustaining systems we know as life.
So, is it possible to make a reasonable stab at what that first kind of life may have been? It was without doubt single celled. To reproduce it must have carried a genetic code enshrined in DNA, which is unique not only to all species, but to individuals. The key to tracking down LUCA is that it represents the point at which the evolutionary trees of the fundamental domains of modern life life – eukarya (including animals, plants and fungi), bacteria, and archaea – converge to a single evolutionary stem. There is little point in using fossils to resolve this issue because only multicelled life leaves tangible traces, and the first of those was found in 2,100 Ma old sediments in Gabon (see: The earliest multicelled life; July 2010). The key is using AI to compare the genetic sequences of the hugely diverse modern biosphere. Modern molecular phylogenetics and computing power can discern from their similarities and differences the relative order in which various species and broader groups split from others. It can also trace the origins of specific genes that provides clues about earlier genetic associations. Given a rate of mutation the modern differences provide estimates of when each branching occurred. The most recent genetic delving has been achieved by a consortium based at various institutions in Britain, the Netherlands, Hungary and Japan (Moody, E.R.R. and 18 others 2024. The nature of the last universal common ancestor and its impact on the early Earth system. Nature Ecology & Evolution, v.8, pages 1654–1666; DOI: 10.1038/s41559-024-02461-1).
Moody et al have pushed back the estimated age of LUCA to halfway through the Hadean, between 4.09 to 4.33 billion years (Ga), well beyond the geologically known age of the earliest traces of life (3.5 Ga). That age for LUCA in itself is quite astonishing: it could have been only a couple of hundred million years after the Moon-forming interplanetary collision. Moreover, they have estimated that Darwin’s Ur-organism had a genome of around 2 million base pairs that encoded about 2600 proteins: roughly comparable to living species of bacteria and archaea, and thus probably quite advanced in evolutionary terms. The gene types probably carried by LUCA suggest that it may have been an anaerobic acetogen; i.e. an organism whose metabolism generated acetate (CH3COO−) ions. Acetogens may produce their own food as autotrophs, or metabolise other organisms (heterotrophs). If LUCA was a heterotroph, then it must have subsisted in an ecosystem together with autotrophs which it consumed, possibly by fermentation. To function it also required hydrogen that can be supplied by the breakdown of ultramafic rocks to serpentinites, which tallies with the likely ocean-world with ultramafic igneous crust of the Hadean (see the earlier paragraphs about protocells). If an autotroph, LUCA would have had an abundance of CO2 and H2 to sustain it, and may have provided food for heterotrophs in the early ecosystem. The most remarkable possibility discerned by Moody et al is that LUCA may have had a kind of immune system to stave off viral infection.
The carbon cycle on the Hadean Earth (Credit: Moody et al. 2024; Figure 3e)
The Hadean environment was vastly different to that of modern times: a waterworld seething with volcanism; no continents; a target for errant asteroids and comets; more rapidly spinning with a 12 hour day; a much closer Moon and thus far bigger tides. The genetic template for the biosphere of the following four billion years was laid down then. LUCA and its companions may well have been unique to the Earth, as are their descendants. It is hard to believe that other worlds with the potential for life, even those in the solar system, could have followed a similar biogeochemical course. They may have life, but probably not as we know it . . .
The surface of Venus from the USSR Venera 14 lander
It is often said that Earth has a twin: Venus, the second planet from the Sun. That isn’t true, despite the fact that both have similar size and density. Venus, in fact, is even more inhospitable that either Mars or the Moon, having surface temperatures (~465°C) that are high enough to melt lead or, more graphically, those in a pizza oven. The only vehicles successfully to have landed on Venus (the Russian Venera series) survived for a mere 2 hours, but some did did send back data and images. That near incandescence is masked by the Venusian atmosphere that comprises 96.5% carbon dioxide, 3.5% nitrogen and 0.05 % sulfur dioxide, with mere traces of other gases including extremely low amounts of water vapour (0.002%) and virtually no oxygen. The dense atmosphere imposes a pressure at Venus’s surface tht is 92 times that on Earth: so dense that CO2 and N2 are, strictly speaking, not gases but supercritical fluids at the surface. At present Venus is definitely inimical to any known type of life. It is the victim of an extreme, runaway greenhouse effect.
As it stands, Venus’s geology is also very different from that of the Earth. Because its upper atmosphere contains clouds of highly reflective sulfuric acid aerosols only radar is capable of penetrating to the surface and returning to have been monitored by a couple of orbital vehicles: Magellan (NASA 1990 to 1994) and Venus Express (European Space Agency 2006 to 2014). The latter also carried means of mapping Venus’s surface gravitational field. The radar imagery shows that 80% of the Venusian surface comprises somewhat wrinkled plains that suggests a purely volcanic origin. Indeed more that 85,000 volcanoes have been mapped, 167 of which are over 100 km across. Much of the surface appears to have been broken into polygonal blocks or ‘campuses’ (campus is Latin for field) that give the impression of ‘crazy paving’. A peculiar kind of local-scale tectonics has operated there, but nothing like the plate tectonics on Earth in either shape or scale.
Polygonal blocks or ‘campuses’ on the lowland surface of Venus. Note the zones of ridges that roughly parallel ‘campus’ margins. Credit: Paul K. Byrne, North Carolina State University and Sean C. Solomon, Lamont-Doherty Earth Observatory
Many of the rocky bodies of the solar system are pocked by impact craters – the Earth has few, simply because erosion and sedimentary burial on the continents, and subduction of ocean floors have removed them from view. The Venusian surface has so few that it can, in its entirety, be surmised to have formed by magmatic ‘repaving’ since about 500 Ma ago at least. Earlier geological process can only be guessed at, or modelled in some way. A recent paper postulates that ‘there are several lines of evidence that suggest that Venus once did have a mobile lithosphere perhaps not dissimilar to Earth …’ (Weller, M.B. & Kiefer, W.S. 2025. The punctuated evolution of the Venusian atmosphere from a transition in mantle convective style and volcanic outgassing. Science Advances, v. 11, article eadn986; DOI: 10.1126/sciadv.adn986). One large, but subtle feature may have formed by convergence similar to that of collision tectonics. There are also gravitational features that hint at active subduction at depth, although the surface no longer shows connected features such as trenches and island arcs. Local extension has been inferred from other data.
Weller and Kiefer suspect that Venus in the past may have shifted between a form of mobile plate tectonics and stagnant ‘lid’ tectonics, the vast volcanic plains having formed by processes akin to flood volcanism on a planetary scale. Venus’s similar density to that of Earth suggests that it is made of similar rocky material surrounding a metallic core. However, that planet has a far weaker magnetic field suggesting that the core is unable to convect and behave like a dynamo to generate a magnetic field. That may explain why the atmosphere of Venus is almost completely dry. With no magnetic field to deflect it the solar wind of charged particles directly impacts the upper atmosphere, in contrast to the Earth where only a very small proportion descends at the poles. Together with the action of UV solar radiation that splits water vapour into its constituent hydrogen and oxygen ions, the solar wind adds energy to them so that they escape to space. This atmospheric ‘erosion’ has steadily stripped the atmosphere of Venus – and thus its solid surface – of all but a minute trace of water, leaving behind higher mass molecules, particularly carbon dioxide, emitted by its volcanism. Of course, this process has vastly amplified the greenhouse effect that makes Venus so hot. Early on the planet may have had oceans and even primitive life, which on Earth extract CO2 by precipitating carbonates and by photosynthesis, respectively. But they no longer exist.
The high surface temperature on Venus has made its internal geothermal gradient very different from Earth’s; i.e. increasing from 465°C with depth, instead of from about 15°C on Earth. As a result, everywhere beneath the surface of Venus its mantle has been more able to melt and generate magma. Earlier in its history it may have behaved more like Earth, but eventually flipped to continual magmatic ‘repaving’. To investigate how this evolution may have occurred Weller and Kiefer created 3-D spherical models of geological activity, beginning with Earth-like tectonics – a reasonable starting point because of the probable Earth-like geochemistry of Venus. My simplified impression of what they found is that the periodic blurting of magma well-known from Earth history to have created flood-basalt events without disturbing plate tectonics proceeded on Venus with progressively greater violence. Such events here emitted massive amounts of CO2 into the atmosphere over short (~1 Ma) time scales and resulted in climate change, but Earth’s surface processes have always returned to ‘normal’. Flood-basalt episodes here have had a rough periodicity of around 35 Ma. Weller and Kiefer’s modelling seems to suggest that such events on Venus may have been larger. Repetition of such events, which emitted CO2 that surface processes could not erase before the next event, would progressively ramp up surface temperatures and the geothermal gradient. Eventually climatic heating would drive water from the surface into the atmosphere, to be lost forever through interaction with the solar wind. Without rainfall made acid by dissolved CO2, rock weathering that tempers the greenhouse effect on Earth would cease on Venus. The increased geothermal gradient would change any earlier rigid, Earth-like lithosphere to more ductile material, thereby shutting down the formation of plates, the essence of tectonics on Earth. It may have been something along those lines that made Venus inimical to life, and some may fear that anthropogenic global warming here might similarly doom the Earth to become an incandescent and sterile crucible orbiting the Sun. But as Mark Twain observed in 1897 after reading The New York Herald’s account that he was ill and possibly dying in London, ‘The report of my death was an exaggeration’. It would suit my narrative better had he said ‘… was premature’!
The Earth has a very large Moon because of a stupendous collision with a Mars-sized planet shortly after it accreted. That fundamentally reset Earth’s bulk geochemistry: a sort of Year Zero event. It endowed both bodies with magma oceans from which several tectonic scenarios developed on Earth from Eon to Eon. There is no evidence that Venus had such a catastrophic beginning. By at least 3.7 billion years ago Earth had a strong magnetic field. Protected by that thereafter from the solar wind, it has never lost its huge endowment of water; solid, liquid or gaseous. It seems that it did go through a stagnant lid style of tectonics early on, that transitioned to plate tectonics around the end of the Hadean Eon (~4.0 Ga), with a few hiccups during the Archaean Eon. And it did develop life as an integral part of the rock cycle. Venus, fascinating as it is, shows no sign of either, and that’s hardly surprising. Those factors and its being much closer to the Sun may have condemned it from the outset.
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In March 1989 an asteroid half a kilometre across passed within 500 km of the Earth at a speed of 20 km s-1. Making some assumptions about its density, the kinetic energy of this near miss would have been around 4 x 1019 J: a million times more than Earth’s annual heat production and humanity’s annual energy use; and about half the power of detonating every thermonuclear device ever assembled. Had that small asteroid struck the Earth all this energy would have been delivered in a variety of forms to the Earth System in little more than a second – the time it would take to pass through the atmosphere. The founder of “astrogeology” and NASA’s principal geological advisor for the Apollo programme, the late Eugene Shoemaker, likened the scenario to a ‘small hill falling out of the sky’. (Read a summary of what would happen during such an asteroid strike). But that would have been dwarfed by the 10 to 15 km impactor that resulted in the ~200 km wide Chicxulub crater and the K-Pg mass extinction 66 Ma ago. Evidence has been assembled for Earth having been struck during the Archaean around 3.6 billion years (Ga) ago by an asteroid 200 to 500 times larger: more like four Mount Everests ‘falling out of the sky’ (Drabon, N. et al. 2024. Effect of a giant meteorite impact on Paleoarchean surface environments and life. Proceedings of the National Academy of Sciences, v. 121, article e2408721121; DOI: 10.1073/pnas.2408721121
Impact debris layer in the Palaeoarchaean Barberton greenstone belt of South Africa, which contains altered glass spherules and fragments of older carbonaceous cherts. (Credit: Credit: Drabon, N. et al., Appendix Fig S2B)
In fact the Palaeoarchaean Era (3600 to 3200 Ma) was a time of multiple large impacts. Yet their recognition stems not from tangible craters but strata that contain once glassy spherules, condensed from vaporised rock, interbedded with sediments of Palaeoarchaean ‘greenstone belts’ in Australia and South Africa (see: Evidence builds for major impacts in Early Archaean; August 2002, and Impacts in the early Archaean; April 2014), some of which contain unearthly proportions of different chromium isotopes (see: Chromium isotopes and Archaean impacts; March 2003). Compared with the global few millimetres of spherules at the K-Pg boundary, the Barberton greenstone belt contains eight such beds up to 1.3 m thick in its 3.6 to 3.3 Ga stratigraphy. The thickest of these beds (S2) formed by an impact at around 3.26 Ga by an asteroid estimated to have had a mass 50 to 200 times that of the K-Pg impactor.
Above the S2 bed are carbonaceous cherts that contain carbon-isotope evidence of a boom in single-celled organisms with a metabolism that depended on iron and phosphorus rather than sunlight. The authors suggest that the tsunami triggered by impact would have stirred up soluble iron-2 from the deep ocean and washed in phosphorus from the exposed land surface, perhaps some having been delivered by the asteroid itself. No doubt such a huge impact would have veiled the Palaeoarchaean Earth with dust that reduced sunlight for years: inimical for photosynthesising bacteria but unlikely to pose a threat to chemo-autotrophs. An unusual feature of the S2 spherule bed is that it is capped by a layer of altered crystals whose shapes suggest they were originally sodium bicarbonate and calcium carbonate. They may represent flash-evaporation of up to tens of metres of ocean water as a result of the impact. Carbonates are less soluble than salt and more likely to crystallise during rapid evaporation of the ocean surface than would NaCl.
Time line of possible events following a huge asteroid impact during the Palaeoarchaean. (Credit: Drabon, N. et al. Fig 8)
So it appears that early extraterrestrial bombardment in the early Archaean had the opposite effect to the Chicxulub impactor that devastated the highly evolved life of the late Mesozoic. Many repeats of such chaos during the Palaeoarchaean could well have given a major boost to some forms of early, chemo-autotrophic life, while destroying or setting back evolutionary attempts at photo-autotrophy.
If ever there was one geological locality that ‘kept giving’ it would have to be the Isua supracrustal belt in West Greenland. Since 1971 it has been known to be the repository of the oldest known metasedimentary rocks, dated at around 3.7 Ga. Repeatedly, geochemists have sought evidence for life of that antiquity, but the Isua metasediments have yielded only ambiguous chemical signs. A more convincing hint emerged from iron-rich silica layers (jasper) in similarly aged metabasalts on Nuvvuagittuk Island in Quebec on the east side of Hudson Bay, Canada, which may be products of Eoarchaean sea-floor hydrothermal vents. X-ray micro-tomography and electron microscopy of the jaspers revealed twisted filaments, tubes, knob-like and branching structures up to a centimetre long that contain minute grains of carbon, phosphates and metal sufides, but the structures are made from hematite (Fe2O3) so an inorganic formation is just as likely as the earliest biology. Isua’s most intriguing contribution to the search for the earliest life has been what look like stromatolites in a marble layer (see: Signs of life in some of the oldest rocks; September 2016). Such structures formed in later times on shallow sea floors through the secretion of biofilms by photosynthesising blue-green bacteria.
Structure of the Earth’s magnetosphere that deflects charged particles which form the solar wind. (Credit: Wikipedia Commons)
For life to form and survive depends on its complex molecules being protected from high-energy charged particles in the solar wind. In turn that depends on a strong geomagnetic field deflecting the solar wind as it does today, except for a small proportion that descend towards the poles and form aurora during solar mass ejections. In visits to Isua in 2018 and 2019, geophysicists from the Massachusetts Institute of Technology, USA and Oxford University, UK drilled over 300 rock cores from metasedimentary ironstones (Nichols, C.I.O. and 9 others 2024. Possible Eoarchean records of the geomagnetic field preserved in the Isua Supracrustal Belt, southern West Greenland. Journal of Geophysics Research (Solid Earth), v. 129, article e2023JB027706; DOI: 10.1029/2023JB027706 Magnetisation preserved in the samples (remanent magnetism) suggest that it was formed by a geomagnetic field strength of at least 15 microtesla, similar to that which prevails today. The minerals magnetite (Fe3O4) and apatite (a complex phosphate) in the ironstones have been dated using U-Pb geochronometry and record a metamorphic event only slightly younger that the age of the Isua belt (3.69 and 3.63 Ga respectively). There is no sign of any younger heating above the temperatures that would reset the ironstones’ magnetisation. The Isua remanent magnetisation is at least 200 Ma older than that found in igneous rocks from north-eastern South Africa dated at between 3.2 to 3.45 Ga. So even in the Eoarchaean it seems likely that life, had it formed, would have avoided the hazard of exposure to the high energy solar wind. In all likelihood, however, in a shallow marine environment it would have had to protect itself somehow from intense ultraviolet radiation. That is now vastly reduced by stratospheric ozone (O3) which could only form once the atmosphere had appreciable oxygen (O2) content, i.e. after the Great Oxygenation Event beginning about 2.4 Ga ago. Undoubted stromatolites as old as 3.5 Ga suggest that early photosynthesising bacteria clearly had cracked the problem of UV protection somehow.
Fig Interpreted 2D seismic section across the Nadir crater and central uplift beneath the Guinea Terrace. (Credit: Nicholson, et al. 2022. Fig 2c)
In 2022 four geoscientists from Heriot-Watt University in Edinburgh, Scotland and the Universities of Arizona and Texas (Austin), USA were geologically interpreting seismic-reflection data beneath the seafloor off Guinea and Guinea-Bissau, West Africa. Individual sedimentary strata that cover the upper continental crust show up as many reflectors. They are calibrated to rock cores from exploratory well that had revealed up to 8 km of sedimentary cover deposited continuously since the Upper Jurassic. The team’s objective was to collect information on tectonic structures that had formed when South America separated from Africa during the Cretaceous. The geophysical data were from commercial reconnaissance surveys aimed at locating petroleum fields beneath part of the West African continental shelf known as the Guinea Terrace. One of the seismic sections revealed a ~9 km wide basin-like depression at the level of the Cretaceous-Palaeogene boundary, which is underlain by a prominent upward bulge in reflectors corresponding to the mid-Cretaceous, plus a large number of nearby faults (Nicholson, U., and 3 others 2022. The Nadir Crater offshore West Africa: a candidate Cretaceous-Paleogene impact structure. Science Advances, v. 8, article eabn3096; DOI: 10.1126/sciadv.abn3096). Elsewhere on the Guinea Terrace the strata were featureless by comparison.
The Nadir crater showed many of the signs to be expected from an asteroid impact. That it drew attention stemmed partly from being of roughly the same age as the much larger 66 Ma Chicxulub impact off the Yucatan Peninsula of Mexico: the likely culprit for the K-Pg mass-extinction event. Perhaps both impactors stemmed from the break-up of a large, near-Earth asteroid because of gravitational forces resulting from a previous close encounter with either the Earth or another planet. The crater lies at the centre of a 23 km wide zone of faults that only affect Cretaceous and older strata; i.e. they formed just before the K-Pg event. The seismic data also show signs of widespread liquefaction of nearby Cretaceous sedimentary strata and that the crater had been filled by sediments shortly after it formed. Yet the data were too fuzzy for an astronomical catastrophe to be absolutely certain: similar structures can form from the rise of bodies of rock salt, which is less dense than sediments and will dissolve on reaching the seabed. The owners of the seismic data donated a much larger collection from a grid of survey lines. Processing of such seismic grids turns the collection of individual two-dimensional sections into a 3D regional data set showing the complete shape of subsurface structures. Seismic data of this kind enables more detailed structural and lithological interpretation of both cross section and plan views. They enable sedimentary layers to be ‘peeled’ back to examine the crater at all depths, in much the same manner as CT and MRI scans reveal the inner anatomy of the human body.
Map of faults around the Nadir crater at a level in the 3D seismic data that was about 200 m below the sea bed at the time of the impact. (Credit: Nicholson, et al. 2024, Fig 6)
Uisdean Nicholson and a larger team have now published their findings from the 3D seismic data that show the structure in unique detail (Nicholson, U., and 6 others 2024. 3D anatomy of the Cretaceous–Paleogene age Nadir Crater. Communications Earth & Environment v. 5, article number 547; DOI: 10.1038/s43247-024-01700-4). Nadir crater was affected by spiral-shaped thrust faults that suggest it was formed by an oblique impact from the northeast by an object around 450 m across, probably travelling at 20 km s-1 at 20 to 40° to the surface. Seconds after excavation uplift of deeper sediments was a response to removal of the load on the crust. The energy was sufficient to vaporise both sediment and impactor within a few seconds, the to drive drive seawater outwards in a tsunami about half a kilometre high, which in about 30 seconds exposed the incandescent crater floor. In the succeeding minutes hours and days liquefied sea water sloshed in and out of the crater, repeated tsunami resurgence forming gullies on its flanks and transporting sediment mixed with glass (suevite) flowed to refill the crater.
Time line for the Nadir impact, derived from detail shown by 3D seismic data. (Credit: Nicholson, et al. 2024, Fig 7)
There is no means of assigning any of the K-Pg extinctions to the Nadir crater, just that it happened at roughly the same time as Chicxulub. But it is the first impact crater to reveal the processes involved through complete coverage by high-resolution 3D seismic data. The majority of the roughly 200 craters are on the continental surface, and were thus ravaged to some extent by later erosion. Yet of the influx of hypervelocity objects through time at least 70% must have struck the oceans, but only 15 to 20 are known. That may reflect the fact that much deeper water could have buffered even giant impacts from affecting the oceanic crust beneath the abyssal plains, whose average depth is about 4 km. Only a small proportion of the continental shelves deemed to contain petroleum reserves have been explored seismically. Chicxulub itself has been drilled, but only two seismic reflection sections have crossed its centre since its discovery, although earlier 3D data from petroleum exploration cover its outermost northern parts. More detail is available for Nadir and its lower energy did not smash its structural results, unlike Chicxulub. So, despite Nadir’s smaller size, fortuitously it gives more clues to how such marine craters formed. It looks to be an irresistible target for drilling.
You can follow my ‘reportage’ on the long running story of the Snowball Earth events during the Neoproterozoic Cryogenian Period (850 to 635 Ma) since 2000 through the index to annual Palaeoclimatology logs (15 posts). Once these dramatic events were over sedimentary rocks deposited around the world during the Ediacaran Period (635 to 541 Ma) record the sudden appearance of large-bodied fossils: the first multicellular animals. This explosion from slimy biofilms and colonies of single-celled prokaryotes and eukaryotes laid the basis for the myriad ecological niches that have characterised Planet Earth ever since. The change saw specialised eukaryote cells (see: The rise of the eukaryotes; December 2017), whose precursors had originated in single-celled forms, begin to cooperate inthe development of complex tissues, organs, and organ systems to form bodies rather than just cell walls. The pulsating evolution, diversification and repeated extinction that followed during the last one tenth of geological time shaped a planet that is unique in the Solar System and possibly in the galaxy, if not the entire universe. The simple biosphere that preceded it, on the other hand, may have emerged on innumerable rocky planets blessed with liquid water to survive little changed for billions of years, as have Earths’ prokaryotes, the Archaea and Bacteria.
Artist’s impression of the Ediacaran Fauna (credit: Science)
The Ediacaran biological revolution followed repeated changes in the geochemistry of the oceans, which carbon isotope data from the Cryogenian and Ediacaran suggest to have ‘gone haywire’. This turmoil involved dramatic changes in the cycling of sulfur and phosphorus that help ‘fertilise’ the marine food chain and in the production of oxygen by photosynthesis that is essential for metazoan animals. The episodes when the Earth was iced over reduced the availability of nutrients through decreased rates of ocean-floor burial of dead organisms. Such Snowball events would also have reduced penetration of sunlight in the oceans. Less photosynthesis would not only have reduced oxygen production but also the amounts of autotrophic organisms. Furthermore, decreased water temperature would have increased its viscosity thereby slowing the spread of nutrients. The food chain for heterotrophs was decimated. Each Snowball event ended with warming, ice-free conditions so that the marine biosphere could burgeon
A great deal of data and numerous theories have accumulated since the Snowball concept was first mooted, but there has been little progress in understanding the rise of multi-celled life. Four geoscientists from the Massachusetts Institute of Technology, the Santa Fe Institute and the University of Colorado (Boulder), USA have developed an interesting hypothesis for how this enormous evolutionary step may have developed (Crockett, W.W. et al. 2024. Physical constraints during Snowball Earth drive the evolution of multicellularity. Proceedings of the Royal Society B: Biological Sciences, v. 291; DOI: 10.1098/rspb.2023.2767). The concatenation of huge events during the Cryogenian and Ediacaran presented continually changing patterns of selective pressures on simple organisms that preceded that time period. Crockett et al. review them in the light of fundamental biology to suggest how multicellular animals emerged as the Ediacara Fauna. Intuitively, such harsh conditions suggest at worst mass, even complete, extinction, at best a general reduction in size of all organism to cope with scarce resources. That the size of eukaryotes should have grown hugely goes against the grain of most biologists’ outlook.
The authors consider the crucial factor to be fundamental differences between prokaryotes and early eukaryotes. Prokaryote cells are very small, and whether autotrophs of heterotrophs they absorb nutrients through their walls by diffusion. Single-celled eukaryotes are far larger than prokaryotes and typically have a flagellum or ‘tail’ so that they can move independently and more easily gather resources. Crockett et al. used computer modelling to simulate the type of life form that could grow and thrive under Snowball conditions. They found that prokaryotes could only grow smaller, being ‘stunted’ by scarce resources. On the other hand eukaryotes would be better equipped to gather resources, the more so if they adopted a simple multicellular form – a hollow, self-propelled sphere about the size of a pea, which the authors dub a choanoblastula. Although no such form is known today, it does resemble the green Volvox algae, and plausibly could have evolved further to the simple forms of the Ediacaran fauna. The next task is either to find a fossil of such an organism, or to grow one.
Readers of Earth-logs will be familiar with the way gravitational interactions between the planets that orbit the Sun control cyclical shifts in each other’s rotational and orbital behaviours. The best known are the three Milankovich cycles. The eccentricity of Earth’s orbit (deviation from a circular path) changes according to the varying gravitational pulls exerted by Jupiter and Saturn as they orbit the Sun, and is dominated by 100 ka cyclicity. The tilt (obliquity) of Earth’s rotational axis changes in 41 ka cycles. The direction in which the axis points relative to the Sun varies with its precession which has a period of about 25.7 ka. Together they control the amount of solar heating that our planet receives, best shown by the current variation in glacial-interglacial cycles. But the phenomena predicted by Milutin Milankovich show up in palaeoclimatic changes back to at least the late Precambrian. Climate changes resulting from the gravitational effect of Mars have recently been detected with a 2.4 Ma period. But that steady carousel of planetary motions hasn’t always characterised the Solar System.
Cartoon showing planet formation in the early, unstable Solar System (Credit: Mark Garlick, Science Source)
Observations of other stars that reveal the presence of their own planetary systems show that some have giant planets in much closer orbits than those that circuit the Sun. Others occur at distances that extend as far as the orbital diameters as those in the Solar System: so perhaps giant planets can migrate. A possibility began to be discussed in the late 1990s that Jupiter, Saturn, Uranus and Neptune – and a fifth now-vanished giant planet – were at the outset in neat, evenly-spaced and much closer orbits. But they were forced outwards later into more eccentric and generally askew orbits. In 2005, planetary astronomers gathered in Nice, France to ponder the possibilities. The outcome was the ‘Nice’ Model that suggested that a gravitational instability had once emerged, which set the Solar System in chaotic motion. It may even have flung gigantic masses, such as postulated fifth giant planets, into interstellar space. This upheaval may have been due to a rapid change in the overall distribution of mass in the Solar System, possibly involving gas and dust that had not yet accreted into other planets or their planetesimal precursors. Chaotic antics of monstrous bodies and shifts in their combined gravitational fields can barely be imagined: it was nothing like the staid and ever present Milankovich Effect. Geologists have reconstructed one gargantuan event that reset the chemistry of the early Earth when it collided with another body about the size of Mars. That also flung off matter that became the Moon. Evidence from lunar and terrestrial zircon grains (see: Moon-forming impact dated; March 2009) suggests the collision occurred before 4.46 billion years ago (when parts of both eventually crystallised from magma oceans), Solar System having begun to form at around 4.57 Ga. Could formation of the Moon record the early planetary chaos? Others have suggested instead that the great upheaval was the Late Heavy Bombardment, between 4.1 and 3.8 Ga, which heavily cratered much of the lunar surface and those of moons orbiting the giant planets.
Another approach has been followed by Chrysa Avdellidou of the University of Leicester, UK and colleagues from France and the US (Avdellidoli, C. et al. 2024. Dating the Solar System’s giant planet orbital instability using enstatite meteorites. Science, v. 384, p. 348-352; DOI: 10.1126/science.adg8092) after discovery of a new family of asteroids: named after its largest member Athor. The composition of their surfaces, from telescopic spectra, closely matches that of EL enstatite chondrite meteorites. Dating these meteorites should show when their parent asteroids – presumably the Athors – formed. Using argon and xenon isotopes Mario Trieloff and colleagues from the University of Heidelberg, Germany in showed that the materials in EL enstatite chondrite meteorites were assembled a mere 2 Ma after the Solar System formed (Trieloff, M. et al. 2022. Evolution of the parent body of enstatite (EL) chondrites. Icarus, v. 373, article 114762; DOI: 10.1016/j.icarus.2021.114762). Be that as it may, that the evidence came from small meteorites shows that the parent body, estimated as having had a 240 to 420 km diameter, was shattered at some later time. Moreover, at that very early date such bodies would have contained a ready heat source in the form of a short-lived isotope of aluminium (26Al) which decays to stable 26Mg, with a half-life of 0.717 Ma. 26Al is thought to have been produced by a supernova that has been suggested to have triggered the formation of the Solar System. Excessive 26Mg is found in many meteorites, evidence for metamorphism formed by such radiogenic heat. They also record the history of their cooling.
Avdellidoli et al. estimate that the 240 to 420 km Athor parental planetesimal had slowly cooled for at least 60 Ma after it formed. When it was shattered, the small fragments would have cooled instantaneously to the temperature of interplanetary space – a few degrees above absolute zero (-273.2 °C). From this they deduce the age of the chaotic restructuring of the early Solar System to be at least 60 Ma after its formation. Other authors use similar reasoning from other chondritic meteorite classes to suggest it may have happened even earlier at 11 Ma. But there are other views for a considerably later migration of the giant planets and the havoc that they wrought. The only widely agreed date, in what seems to be an outbreak of wrangling among astronomers, is for the Moon-forming collision: 110 Ma after formation of the Solar System. For me, at least, that’s good-enough evidence for when system-wide chaos prevailed. The Late Heavy Bombardment between 4.1 and 3.8 Ga seems to require a different mechanism as it affected large bodies that still exist. It may have resulted from whatever formed the asteroid belt, for it was bodies within the range of sizes of the asteroids that did the damage, in both the Inner and Outer Solar System.
In the 1950s Harold Urey of the University of Chicago and his student Stanley Miller used basic lab glassware containing 200 ml of water and a mix of the gases methane (CH4), ammonia (NH3) and hydrogen sulfide (H2S) to model conditions on the early Earth. Heating this crude analogue for ocean and atmosphere and continuous electrical discharge through it did, in a Frankensteinian manner, generate amino acids. Repeats of the Miller-Urey experiment have yielded 10 of the 20 amino acids from which the vast array of life’s proteins have been built. Experiments along similar lines have also produced the possible precursors of cell walls – amphiphiles. In fact, all kinds of ‘building blocks’ for life’s chemistry turn up in analyses of carbonaceous chondrite meteorites and in light spectra from interstellar gas clouds. The ‘embarrassment of riches’ of life’s precursors from what was until the 20th century regarded as the ‘void’ of outer space lacks one thing that could make it a candidate for life’s origin, or at least for precursors of proteins and the genetic code DNA and RNA. Both kinds of keystone chemicals depend on a single kind of connector in organic chemistry.
Reaction between two molecules of the amino acid glycene that links them by a peptide bond to form a dipeptide. (Credit: Wikimedia Commons)
Molecules of amino acids have acidic properties (COOH – carboxyl) at one end and their other end is basic (NH2 – amine). Two can react by their acid and basic ‘ends’ neutralising. A hydroxyl (OH–) from carboxyl and a proton (H+) from amine produce water. This gives the chance for an end-to-end linkage between the nitrogen and carbon atoms of two amino acids – the peptide bond. The end-product is a dipeptide molecule, which also has carboxyl at one end and amine at the other. This enables further linkages through peptide bonds to build chains or polymers based on amino acids – proteins. Only 20 amino acids contribute to terrestrial life forms, but linked in chains they can form potentially an unimaginable diversity of proteins. Formation of even a small protein that links together 100 amino acids taken from that small number illustrates the awesome potential of the peptide bond. The number of possible permutations and combinations to build such a protein is 20100 – more than the estimated number of atoms in the observable universe! Protein-based life has almost infinite options: no wonder that ecosystems on Earth are so diverse, despite using a mere 20 building blocks. Simple amino acids can be chemically synthesised from C, H, O and N. About 500 occur naturally, including 92 found in a single carbonaceous chondrite meteorite. They vastly increase the numbers of conceivable proteins and other chain-molecules analogous to RNA and DNA: a point seemingly lost on exobiologists and science fiction writers!
Serge Kranokutski of the Max Planck Institute for Astronomy at the Friedrich Schiller University in Jena, German and colleagues from Germany, the Netherlands and France have assessed the likelihood of peptides forming in interstellar space in two publications (Kranokutski S.A. and 4 others 2022. A pathway to peptides in space through the condensation of atomic carbon. Nature Astronomy, v, 6, p. 381–386; DOI: 10.1038/s41550-021-01577-9. Kranokutski, S.A. et al. 2024. Formation of extraterrestrial peptides and their derivatives. Science Advances, v. 10, article eadj7179; DOI: 10.1126/sciadv.adj7179). In the first paper the authors show experimentally that condensation of carbon atoms on cold cosmic dust particles can combine with carbon monoxide (CO) and ammonia (NH3) form amino acids. In turn, they can polymerise to produce peptides of different lengths. The second demonstrates that water molecules, produced by peptide formation, do not prevent such reactions from happening. In other words, proteins can form inorganically anywhere in the cosmos. Delivery of these products, through comets or meteorites, to planets forming in the habitable ‘Goldilocks’ zone around stars may have been ‘an important element in the origins of life’ – anywhere in the universe. Chances are that, compared with the biochemistry of Earth, such life would be alien in an absolute sense. There are effectively infinite options for the proteins and genetic molecules that may be the basis of life elsewhere, quite possibly on Mars or the moons of Jupiter and Saturn: should it or its chemical fossils be detectable.
In 1976 three scientists from Columbia and Brown (USA) and Cambridge (UK) Universities published a paper that revolutionised the study of ancient climates (Hays J.D., Imbrie J. and Shackleton N.J. 1976. Variations in the Earth’s Orbit: Pacemaker of the Ice Ages. Science, v. 194, p. 1121-1132; DOI: 10.1126/science.194.4270.1121). Using variations in oxygen isotopes from foraminifera through two cores of sediments beneath the floor of the southern Indian Ocean they verified Milutin Milankovich’s hypothesis of astronomical controls over Earth’s climate. This centred on changes in Earth’s orbital parameters induced by gravitational effects from the motions of other planets: its orbit’s eccentricity, and the tilt and precession of its rotational axis. Analysis of the frequency of isotopic variations in the resulting time series yielded Milankovich’s predictions of ~100, 41 and 21 ka periodicities respectively. The time spanned by the cores was that of the last 500 ka of the Pleistocene and thus the last 5 glacial-interglacial cycles. Subsequently, the same astronomical climate forcing has been detected for various climate-induced changes in the earlier sedimentary record, including the glacial cycles of the Carboniferous and Neoproterozoic, Jurassic climate changes due to oceanic methane emissions and many other types of cyclicity during the Phanerozoic.
One hemisphere of Mars captured by ESA’s Mars Express. Credit: ESA / DLR / FU Berlin /
As well as time series based on isotopic and other geochemical changes in marine cores, other variables such as thickness of turbidite beds or cyclical repetitions of short rock sequences such as the ‘cyclothems’ of Carboniferous age (repetitions of a limestone, sandstone, soil, coal sequence) have also been subject to frequency analysis. Sedimentary features that have not been tried are gaps or hiatuses in stratigraphic sequences where strata are missing from a deep-sea sequence. These signify erosion of sediment due to vigorous bottom currents in sequences otherwise dominated by continuous deposition under low-energy conditions. Three geoscientists from the University of Sydney, Australia and the Sorbonne University, France, have subjected records of gaps in Cenozoic sedimentation from 293 deep-sea drill cores to time-series analysis to discover what such ‘big data’ might reveal as regards climate fluctuations on the order of millions of years (Dutkiewicz, A., Boulila, S. & Müller, R.D. 2024. Deep-sea hiatus record reveals orbital pacing by 2.4 Myr eccentricity grand cycles. Nature Communications, v. 15, article 1998; DOI: 10.1038/s41467-024-46171-5).
In theory gravitational interrelationships between all the orbiting planets should have an effect on the orbital parameters of each other, and thus the amount of received solar radiation and changes in global climate. As well as the Milankovich effect, longer astronomical ‘grand cycles’ may therefore have been reflected somehow in Earth’s climatic history (Laskar, J. et al. 2004. A long-term numerical solution for the insolation quantities of the Earth. Astronomy & Astrophysics, v. 428, p. 261-285; DOI: 10.1051/0004-6361:20041335). Based on Laskar et al.’s calculations Adriana Dutkiewicz and colleagues sought evidence for two predicted ‘grand cycles’ that result from orbital interactions between Earth and Mars. These are a 2.4 Ma period in the eccentricity of Earth’s orbit and one of 1.2 Ma in the tilt of its axis.
The authors were able to detect cyclicity in the hiatus time series that is close to the 2.4 Ma Mars-induced waxing and waning of solar heating. Warming would increase mixing of ocean water through cyclones and hurricanes. That would then induce more energetic deep ocean currents and more erosion on the deep ocean floor: more gaps in sedimentation. Cooler conditions would ‘calm’ deep ocean currents so that deposition would outweigh evidence of erosion. The 1.2 Ma axial tilt cyclicity is not apparent in the data. Interestingly, the ~2.4 Ma cyclicity underwent a significant deviation at the Palaeocene-Eocene Boundary’ (56Ma), seemingly predicted by Laskar et al’s astronomical solutions as a chaotic orbital transition between 56 and 53 Ma. Dutkiewicz et al. also chart the relations between the sedimentary-hiatus time series and major tectonic, oceanographic, and climatic changes during the Cenozoic Era, and found that terrestrial processes did disrupt the Mars-related orbital eccentricity cycles.
The findings suggest that long-term astronomical climate forcing needs to be borne in mind for better understanding the future response of the ocean to global warming. Also, if Mars had such an influence so must have Venus, which is more massive and closer. That remains to be investigated, and also the effects of the giant planets. In the very distant past there behaviour may have resulted in unimaginable astronomical changes. According to the bizarrely named Nice Model a back and forth shuffling of the Giant Planets was probably responsible for the Late Heavy Bombardment 4.1 to 3.8 billion years (Ga) ago. Such errant behaviour may even have triggered the flinging of some of the Sun’s original planetary complement out of the solar system and changed the outward order of the existing eight. Fortunately, the present planetary set-up seems to be stable …
Michael Rampino and Ken Caldeira of New York University and the Carnegie Institute have for at least three decades been at the forefront of studies into mass extinctions and their possible causes, including flood-basalt volcanism, extraterrestrial impacts and climate change. As early as 1993 the duo reported an ubiquitous 26-million year cycle in plate tectonic and volcanic activity. In Rampino’s 2017 book Cataclysms: A New Geology for the Twenty-First Century the notion of a process similar to Milutin Milankovich’s prediction of Earth’s orbital characteristics underpinning climate cyclicity figured in his thinking (see Shock and Er … wait a minute, Earth-logs, October 2017). Rampino postulated then that this longer-term geological cyclicity could be linked to gravitational changes during the Solar System’s progress around the Milky Way galaxy. He was by no means the first to turn to galactic forces, Johann Steiner having made a similar suggestion in 1966. The notion stems from the Solar System’s wobbling path as it orbits the centre of the Milky Way galaxy about every 250 Ma, which may result in its passage through a vast layered variation in several physical properties aligned at right angles to galactic orbital motions. This grand astronomical theory is ‘a story that will run and run’; and it has. It is possible that the galaxy has corralled dark matter in a disc within the galactic plane, which Rampino and Caldeira latched onto that notion a year after it appeared in Physical Review Letters in 2014.
Map of the Milky Way galaxy as it would appear from a viewpoint above the galactic centre. The Solar System is located in the Orion Spur (green dot) (Credit: Wikipedia)
As I commented in my brief review of Rampino’s book: “As for Rampino’s galactic hypothesis, the statistics are decidedly dodgy, but chasing down more forensics is definitely on the cards.” Indeed they have been chased in a recent review by the pair and their colleague Sedelia Rodriguez (Rampino, M.R., Caldeira, K. & Rodriguez, S. 2023. Cycles of ∼32.5 My and ∼26.2 My in correlated episodes of continental flood basalts (CFBs), hyper-thermal climate pulses, anoxic oceans, and mass extinctions over the last 260 My: Connections between geological and astronomical cycles. Earth-Science Reviews, v. 246 ; DOI: 10.1016/j.earscirev.2023.104548; reprint available on request from Rampino). They base their amplified case on much more than radiometric dates of continental flood basalt (CFB) events matched against the stratigraphic record of biotic diversity. Among the proxies are published measurements of mercury and osmium isotope anomalies in oceanic sediments that are best explained by sudden increases in basaltic magma eruption; signs of deep ocean anoxia; new dating of marine and non-marine extinctions in the fossil record, and episodes of sudden extreme climatic heating.
Statistical analysis of the ages of anoxic events and marine extinctions has yielded cycles of 32.5 and 26.2 Ma, those for CFBs having a 32.8 Ma periodicity. A note of caution, however: their data only cover the last 266 Ma – about one orbit of the solar system around the galactic centre. The authors attribute their interpretation of the cycles “to the Earth’s tectonic-volcanic rhythms, but the similarities with known Milankovitch Earth orbital periods and their amplitude modulations, and with known Galactic cycles, suggest that, contrary to conventional wisdom, the geological events and cycles may be paced by astronomical factors”.
Whether or not a detailed record of appropriate proxies can be extended back beyond the Late Permian, remains to be seen. The main fly-in-the-ointment is the tendency of CFB provinces to form high ground so that they are readily eroded away. Pre-Mesozoic signs of their former presence lie in basaltic dyke swarms that cut through older crystalline continental crust. The marine sedimentary record is somewhat better preserved. A search for distinctive anomalies in osmium isotopes and mercury concentrations, which are useful proxies for global productivity of basaltic magmas, will be costly. Moreover, dating will depend to a large degree on the traditional palaeontology of strata, which in Palaeozoic rocks is more difficult to calibrate precisely by absolute radiometric dating.
Close to the core-mantle boundary (CMB) there are two extensive zones up to 10 km thick in the lower mantle. They have seismic-wave speeds that are much lower than expected at such depths: hence their being termed large low-velocity provinces (LLVPs). Seismic velocities being inversely proportional to the density of the material through which such waves travel, these zones have anomalously high density. The LLVPs have remained enigmatic since they were first discovered. Some have suggested that they are relics of dense subducted banded iron formations (see also: Curiously low-velocity material at the core-mantle boundary; March 2005) or simply piles of subducted slabs with an eclogite component that have gradually accumulated through Earth’s long history of plate tectonics. An alternative is that LLVPs may be connected to geochemical evidence for a heterogeneous lower mantle and perhaps are relics of Earth’s earliest history.
An artist’s impression of the collision between Theia and the proto-Earth. (Credit: Hernán Cañellas, Nature)
The Moon-forming event about 4,500 Ma ago (for more information search the Planetary Science annual logs index) that probably involved a collision between the proto-Earth and another, Mars-sized planet – dubbed ‘Theia’ – is an alternative explanation for LLVPs. Maybe they are chunks of that planet that became embedded in the early Earth’s mantle. Many geochemical approaches to such an obvious origin are inconclusive, however. The latest attempt to model the processes involved in such a planetary truck crash using computer simulation does suggest that LLVPs may indeed be relics of Theia material that sank through the molten mass that became Earth’s mantle after the collision (Yuan, Q. et al. 2023. Moon-forming impactor as a source of Earth’s basal mantle anomalies. Nature v. 623, p. 95–99; DOI: 10.1038/s41586-023-06589-1).
Qian Yuan of the California Institute of Technology, and colleagues from China, USA and the UK based their approach on geochemical anomalies in plume related ocean-island basalts. These included distinctly non-terrestrial isotopic proportions of the noble gases neon and xenon, similar to those in lunar basalts., which in turn are more iron-rich than most basalts and thus 2-3% denser. The initial assumption in their modelling was that during the collision fragments of Theia peppered the magma ocean that became Earth upper mantle. These were thoroughly mixed in this molten zone as it convected before solidifying. But melts derived from some of the fragments could have penetrated the solid mantle below 1400 km depth as blobs, to retain their chemically anomalous integrity. Being dense, the blobs could slowly sink to accumulate at the CMB to form the two LLVPs. An animation of the processes revealed by Yuan et al.’s modelling can be viewed here.
A third piece with hydrogen as its focus in a couple of months? Well, from a galactic perspective there’s a lot of it about. Modern cosmology suggests that only 4.6% of the energy in the universe consists of elemental atoms made of protons, neutrons and electrons, dwarfed by dark energy and dark matter that are something of mystery. But of the more familiar energy equivalent, tangible matter (as in E=mc2), 74% of the universe is hydrogen, 24% is helium and the other 92 elements amount to just 2%. That tiny proportion of heavier elements was created by nucleosynthesis within stars from the two products of the Big Bang (H and He). Nuclear fusion reactions formed those with atomic numbers (protons in their nuclei) up to that of iron (26), whereas the heavier elements were created through neutron- and proton capture when the largest stars destroyed themselves cataclysmically as supernovae. Yet the planet whose surface we inhabit contains only minute amounts of helium and elemental hydrogen. Of course water at and beneath the surface, in the form of atmospheric vapour and locked within minerals retains some of the cosmically available hydrogen. But current estimates suggest that hydrogen accounts for a mere 0.03% of Earth’s mass. Despite the fact that some forms of radioactive decay generate alpha particles that become helium it forms a vanishingly small proportion of terrestrial mass.
The solar system formed around 4.6 billion years ago by a complex gravitational accretion of the gas and dust of an interstellar cloud: mainly H and He. Its dynamic collapse resulted in gravitational potential energy being transformed into heat: in the case of the Sun, sufficient to set off self-sustaining nuclear fusion. As a body grows in this way so does its gravity and thus the speed needed for matter to escape from its pull (escape velocity). As temperature increases so does the speed at which atoms of each element vibrate; the lower the atomic mass the faster the vibration and the greater the chance of escape. So the ‘blend’ of elements that an astronomical body retains during its early evolution depends on its gravity and its surface temperature. The Sun is so massive that very little has escaped its pull, despite a surface temperature of about 5 to 6 thousand degrees Celsius. Its composition is thus close to the cosmic average. Those of the giant planets Jupiter, Saturn, Uranus and Neptune are not far short because of their large gravities and low surface temperatures. Even today, the smaller Inner Planets are unable to cling on to elemental hydrogen and helium and nearly all that is left of the matter from which they formed is the 2% of heavier cosmic elements locked into solids, liquids and gases.
Processes in the early solar system were far more complicated than they are today. In the mainly gaseous disc, from which the solar system evolved, gravity dragged matter towards its centre. That eventually ignited nuclear fusion of hydrogen to form our star. More remote from its gravitational pull vortices aggregated dust into bodies known as planetesimals that in turn accreted to larger protoplanets. Solar gravity dragged gas from the inner solar system leaving rocky protoplanets, whereas gas was able to be attracted to the surface of what became the gas giants where their gravity outweighed that of the far-off Sun. This was complicated by a sort of Milankovich Effect on steroids in which protoplanets continuously changed their orbits and underwent collisions. The best known of these was between the protoEarth and a Mars-sized body that formed the Earth-Moon system, both bodies having deep magma oceans as a result of the huge energy focussed on them by the collision. What may have happened to the protoplanet that became Earth before the Moon-forming collision has been addressed by three geoscientists at the University of California Los Angeles and the Carnegie Institution for Science Washington DC, USA (Young, E.D. et al. 2023. Earth shaped by primordial H2 atmospheres. Nature, v. 616, p. 306–311; DOI: 10.1038/s41586-023-05823-0 [PDF request to: eyoung@epss.ucla.edu]).
A thick hydrogen-rich atmosphere’s interacting chemically with a protoplanet (left). A possible later stage (right) where iron oxide in the magma ocean of the Early Hadean after Moon formation oxidises a hydrogen atmosphere to form surface water (Credit: Sean Raymond 2023, Fig 1)
The focus of the work of Edward Young, Anat Shahar and Hilke Schlichting is directed at the possibility that the Earth-forming protoplanets originally retained thick hydrogen atmospheres. They use thermodynamic modelling of the equilibrium between hydrogen and silicate magma oceans that had resulted from the energy of their accretion. The authors’ main assumption is that insufficient time had elapsed during accretion for the protoplanets to cool and crystallise: a distinct possibility because loss of accretionary heat by thermal radiation would have been ‘blanketed’ by actively accreting dust and gas in orbit around the growing protoplanets. Effectively, the equilibrium would have been chemical in nature: reactions between highly reducing hydrogen and oxidised silicate melts or even vaporised rock evaporated from the very hot surface. The authors suggest that protoplanets bigger than Mars (0.2 to 0.3 times that of Earth) could retain a hydrogen-rich atmosphere long enough for the chemical reactions to come to a balance, despite high temperatures. There would have been no shortage of hydrogen at this early stage in solar system evolution: perhaps as much as 0.2% percent the mass of the Earth surrounding a protoplanet about half its present size.
Two outcomes may have emerged. Reaction between hydrogen and anhydrous silicates could produce H2O in amounts up to three times that currently in the Earth’s oceans, some locked in the magma ocean, some in the dense atmosphere. A by-product would have been iron oxide, giving the current mantle its oxidising properties known from the geochemistry of basaltic magmas. Hydrogen might also have dissolved in molten iron alloys, thereby contributing to the nascent core. That second outcome would help explain why the modern core is less dense than expected for iron-nickel alloy, both solid and liquid. In fact densities calculated by geophysicists from the speeds of seismic waves that have travelled through the core are 5 to 10% percent lower than expected for the alloy. So the core must contain substantial amounts of elements with low atomic numbers.
Several other possibilities have been suggested to account for Earth’s abundance of water. Two popular ideas are comets arriving in the ‘settled’ times of the Hadean or by original accretion of hydrous chondrite meteorites, whose hydrogen isotope proportions match those of ocean water. Hydrogen as the light element needed in the core is but one possibility along with oxygen, sulfur and other ‘light’ elements. Also, the oxidising potential of the modern mantle may have resulted from several billion years of wet lithosphere being subducted. To paraphrase Sean Raymond (below), ‘other hypotheses are available’!
See also: Raymond, S.N. 2023. Earth’s molten youth had long-lasting consequences. Nature (News & Views), v. 616, p. 251-252; DOI: 10.1038/d41586-023-00979-1 [PDF request to: rayray.sean@gmail.com]
Apart from signs of water ice in permanently shadowed areas of some polar craters, the Moon’s surface has generally been considered to be very dry. Rocks returned by the various Apollo missions contain minute traces of water by comparison with similar rocks on Earth. They consist only of anhydrous minerals such as feldspars, pyroxenes and olivines. But much of the lunar surface is coated by regolith: a jumble of rock fragments and dust ejected from a vast number of impact craters over billions of years. It is estimated to be between 3 and 12 m deep. Much of the finer grained regolith is made up of silicate-glass spherules created by the most powerful impacts.
The lunar regolith at Tranquillity Base bearing an astronaut’s bootprint (Credit: Buzz Aldrin, NASA Apollo 11, Photo ID AS11-40-5877)
The scientific and economic (i.e. mining) impetus for the establishment of long term human habitation on the lunar surface hangs on the possibility of extracting water from the Moon itself. It is needed for human consumption and as a source through electrolysis of both oxygen and hydrogen for breathing and also for rocket fuel. The stupendous cost, in both monetary and energy terms, of shifting mass from Earth to the Moon clearly demands self-sufficiency in water for a lunar base occupied for more than a few weeks.
Remote sensing that focussed on the ability of water molecules and hydroxyl (OH–) ions to absorb solar radiation with a wavelength of 2.8 to 3.0 micrometres was deployed by the Indian lunar orbiter Chandrayaan-1 that collected data for several months in 2008-9. The results suggested that OH– and H2O were detectable over a large proportion of the lunar surface at concentrations estimated at between 10 parts per million (ppm) up to about 0.1%. Where did these hydroxyl ions and water molecules come from and what had locked them up? There are several possibilities for their origin: volcanic activity that tapped the Moon’s mantle (magma could not have formed had some water not been present at great depths); impacts of icy bodies such as comets; even the solar wind that carries protons, i.e. hydrogen atoms stripped of their electrons. Conceivably, protons could react with oxygen in silicate material at the surface to produce both OH– and H2O to be locked within solid particles. To assess the possibilities a group of researchers at Chinese and British institutions have examined in detail the 1.7 kg of lunar-surface materials collected and returned to Earth by the 2020 Chinese Chang’e 5 lunar sample return mission (He, H. and 27 others 2023.A solar wind-derived water reservoir on the Moon hosted by impact glass beads. Nature Geoscience, online article; DOI: 10.1038/s41561-023-01159-6)
He et al. focussed on glass spherules formed by impact melting of lunar basalts, whose bulk composition they retain. The glass ‘beads’ contain up to 0.2 % water, mainly concentrated in their outermost parts. This alone suggests that the water and hydroxyl ions were formed by spherules being bathed in the solar wind rather than being of volcanic or cometary origin and trapped in the glass. An abnormally low proportion of deuterium (2H) relative to the more abundant 1H isotope of hydrogen in the spherules is consistent with that hypothesis. Indeed, the high temperatures involved in impact melting would be expected to have driven out any ‘indigenous’ water in the source rocks. The water and OH– ions seem to have built up over time, diffusing into the glass from their surfaces rather than gradually escaping from within.
An awful lot of regolith coats the lunar surface, as many of the images taken by the Apollo astronauts amply show. So how much water might be available from the lunar regolith? The Chinese-British team reckon between 3.0 × 108 to 3.0 × 1011 metric tons. But how much can feasibly be extracted at a lunar base camp? The data suggest that a cubic metre (~2 t) of regolith could yield enough to fill 4 shot glasses (~0.13 litres). Using a solar furnace and a condenser – the one in full sunlight the other in the shade – is not, as they say, ‘rocket science’. But for a minimum 3 litres per day intake of fluids per person, a team of 4 astronauts would need to shift and process roughly 100 m3 of regolith every day. Over a year, this would produce a substantial pit. But that assumes all the regolith contains some water, yet the data are derived from the surface alone …See also:Glass beads on moon’s surface may hold billions of tonnes of water, scientists say. The Guardian, 27 March 2023.
Earth-logs 
