One of the elements comprising the canon of plate tectonics is that as plates spread away from constructive margins the depth to the ocean floor increases in direct proportion to the square root of the underling lithosphere’s age. This is generally considered to reflect steady passive cooling and increasing density of initially hot lithosphere produced at ridge systems. The resulting slope of the ocean floor is said to result in one of the gravitational forces that sustain plate tectonics – ‘ridge slide’. The Pacific Ocean floor is a good test for the hypothesis, but unfortunately does not show a linear depth vs Öage relationship (Adam, C. & Vidal, V. 2010. Mantle flow drives the subsidence of oceanic plates. Science, v. 328, p. 83-85). Instead, the ocean floor flattens out beyond a threshold distance, which has been a source of puzzlement for decades. However, a plot of depth against the square root of distance from the ridge along estimated lines of mantle convective flow is consistently linear. The depth curve seems therefore to reflect past changes in the direction of sea-floor spreading and changes in the deeper mantle convection, thereby linking reality to the original model for continental drift that had mantle convection at its heart. That view was discarded by geophysicists on account of a widespread belief that the asthenosphere was too weak to transmit forces from below to the rigid lithospheric plates.
End-Cretaceous mass extinction moving towards ‘closure’?
Apart from the change in name from the K-T (Cretaceous-Tertiary) to the K-Pg (Cretaceous-Palaeogene) Event, following the abolition by the International Commission on Stratigraphy of the name Tertiary – given by Giovanni Arduino to the penultimate geological Era, in favour of Cenozoic (Palaeogene + Neogene + Quaternary) the eponymous mass extinction has steadily become a less regular news item. Views had settled in to three camps: driven by an impact; by Deccan volcanism or by the two conspiring together. Yet a host of geoscientists, from institutions whose addresses take up 8 column inches in Science, have been beavering away to settle the issue one way or another (Schulte, P. and 40 others 2010. The Chicxulub asteroid impact and mass extinction at the Cretaceous-Paleogene boundary. Science, v. 327, p. 1214-1218). The main biotic changes and geochemical signatures of the K-Pg Event all coincide at 65.5 Ma with the world-wide Chicxulub ejecta layer, after two thirds of the Deccan Traps had been erupted. In an extensive and readable summary of all the evidence the authors conclude that the Chicxulub impact did trigger the massive die-off. Despite global change associated with volcanism, life went on ‘down to the wire’ (a wire once marked the finish line in horseracing). The authors rule out the Deccan volcanism as a causative factor on account of little more than a 2º C warming effect while it lasted, set against the likely near-instantaneous release of at least 100-500 billion tons of SO2 by an impact into massive sulfate-rich sediments around the Chicxulub site (the release by Deccan volcanism has been estimated at 0.05 to 0.5 Gt per year throughout its million-year duration). Such a release along with dust and water vapour flung into the atmosphere are modelled to have reduced global temperatures by up to 10º C – a reduction greater than that reached by the last glacial maximum. The re-entry of such a mass in rainfall within a few years would have acidified large areas of surface ocean water: a 3-4 orders of magnitude larger effect than that of slow release by volcanism. The authors conclude that the most important remaining work is to delve deeper into the impact site itself to quantify likely chemical emissions, and then to develop models of the actual deadly processes that ensued.
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‘Hard’ Snowball Earth softens
The original hypothesis of Neoproterozoic global glacial conditions, proposed by Joe Kirschvink (California Institute of Technology) and Paul Hoffman (emeritus at Harvard) in the 1990s was that conditions became so severe that the Earth was encased in glacial- and sea ice from pole to pole. As EPN has charted since 2000, that ‘hard’ Snowball variant has become increasingly less favoured by most geoscientists (Kerr, R.A. 2010. Snowball Earth has melted back to a profound wintry mix. Science, v. 327, p. 1186). However, evidence supporting low latitude glaciations continues to emerge (, F.A. and 9 others 2010. Calibrating the Cryogenian. . Science, v. 327, p. 1241-1243). In the latest, diamictites of the so-called ‘Sturtian’ glaciation in north-western Canada are interbedded with volcanic rocks that give a very precise age of 716.5 Ma. That age happens to coincide with outpouring of the regionally massive Franklin flood basalts whose palaeomagnetism gives equatorial latitudes, the first recorded for the Sturtian glaciation: the later Marinoan glaciation (~635 Ma) provides most low-latitude evidence for Snowball conditions. The paper by Francis Macdonald and co-workers also gives detailed carbon isotope data for a continuous sedimentary record from >811 to 583 Ma.
A potential spanner in the works for the entire Snowball Earth hypothesis is the discovery of a strange anomaly concerning palaeomagnetic pole positions during latest Neoproterozoic times (Abrajevitch, A. & van der Voo, R. 2010. Incompatible Ediacaran paleomagnetic directions suggest an equatorial geomagnetic dipole hypothesis. Earth and Planetary Science Letters, v. 293, p. 164-170). Paleomagnetism from glaciogenic rocks is the lynchpin for the notion of Snowball Earth, some occurrences recording tropical latitudes. Alexandra Abrajevitch (Kochi University, Japan) and Rob van der Voo (University of Michigan) report palaeomagnetic results for igneous rocks between 600 and 550 Ma in what are now North America and Scandinavia. The data show original inclinations of the magnetic field that are both steep and shallow, indicating high and low latitudes respectively. Plotting inclination against radiometric age for what were separate continental masses in the Ediacaran Period reveals repeated rapid changes from high to low palaeolatitudes that simply cannot be accounted for by continental drift: plate tectonic rates would have to have been unaccountably fast (~45 cm yr-1). To account for the abrupt shifts the authors turn not to true polar wander – due to changes in the geometry of the geomagnetic dipole – but to rapid flips in the orientation of the dipole between a coaxial and an equatorial alignment, perhaps due to dramatic changes of circulation within the liquid outer core. Familiar geomagnetic reversals normally shift the magnetic poles between roughly the geographic pole positions. Yet there are data showing that for brief periods the reversing poles do pass through equatorial latitudes but at very low magnetic field strength. In the cases from the Ediacaran the geomagnetic poles dwelt at tropical latitudes for long periods and maintained a strong field. Were such strange behaviour demonstrated earlier in the Neoproterozoic, during the Cryogenian period of supposed Snowball events, that would undermine the whole basis for the hypothesis. It seems inevitable that geophysicists will scurry to check the earlier palaeomagnetic data, analysing more igneous rocks on all continents at the narrowest possible time intervals.
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Crustal sagging during major volcanism
Ice sheets during the last glaciation reached more than 2 km in thickness over vast high-latitude areas of the Northern Hemisphere. Even though ice has less than half the density of continental crust, their sheer mass forced the lithosphere down into the asthenosphere by up to several hundred metres. The displaced asthenosphere resulted in a corresponding bulge around the glacial fringe. Continental flood basalts are about three times as dense as ice and reach thicknesses up to 2-3 km, so they would have produced even more subsidence, although set against that is the uplifting effect of reduced density of the crust as a result of magmatic heating. The loading effects of individual volcanoes are well known. Yet surprisingly, there have been few accounts of subsidence caused by CFB loading, and the prevailing view is that plume-related large igneous provinces are preceded by doming and even erosion. Geophysicists at the University of Colorado modelled the effects of plumes and CFB eruption and reverse the general view decisively (Leng, W. & Zhong, S 2010. Surface subsidence caused by mantle plumes and volcanic loading in large igneous provinces. Earth and Planetary Science Letters, v. 291, p. 207-214). They found that phase changes in the rising mantle plume at the 660 km deep discontinuity cause subsidence themselves, so that even before volcanism begins the surface subsides. This is borne out by preservation of basinal sediments beneath some CFB provinces, such as the Siberian and Deccan Traps. Effectively, flood basalts may fill shallow basins that they recreate and maintain due to their loading effect on the crust during successive eruptions. The high elevations of many ancient CFB provinces are a product of later tectonic processes rather than being ‘built’ by volcanism.
‘Microdating’ sedimentary sequences
There are few minerals amenable to radiometric dating that are found in all sedimentary rock types. To give ages that are stratigraphically useful they would have had to form authigenically while the sediment itself was accumulating – glauconite in ‘greensands’ is an example. Calibrated stratigraphy largely depends on dateable igneous minerals found in volcanic rocks interlayered with sediments, the most common being zircon that can be dated precisely using U-Pb methods. The vast bulk of high quality ages of this kind depend on being able to collect sufficient volcanic ash or lava to yield zircon grains. So only volcanic layers thicker than a few centimetres have been used, and they are haphazard in their occurrence in sedimentary sequences. Much thinner ash layers do occur more commonly and uniformly in sequences from arc-related sedimentary basins, and being able to date those would permit much better control over rates of sedimentation and correlation between different sequences. The key is being able to date zircons in thin section (Rasmussen, B. & Fletcher, I.R. 2010. Dating sedimentary rocks using in situ U-Pb geochronology of syneruptive zircon in ash-fall tiffs <1 mm thick. Geology, v. 38, p. 299-302). Rasmussen and Fletcher (Curtin University, Western Australia) applied ion-microprobe methods to polished this sections of diamond drill core through Archaean sediments of the Pilbara craton in Western Australia, specifically to date a thin sediment layer that contains spherules formed by a major asteroid impact. They were able to narrow its age down to that of a thin ash only 15 mm above the spherules, about 2632+7 Ma. Though with a specialised objective, they demonstrate that semi-continuous stable isotope data in sediments can be calibrated sufficiently precisely to allow global correlations
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2010: already a terrible year for disaster.
Early 2010 witnessed horrific scenes on Haiti following a magnitude 7.0 earthquake on the afternoon of 12 January to be followed early in the morning of 26 February by one of the largest ever recorded in Chile (magnitude 8.8). Haiti has suffered fatalities on a scale that match those of the Indian Ocean tsunamis of 26 December 2004, while a huge area of coastal Chile affected by seismic energies more than a hundred times greater had estimated fatalities of over 700, though rising at the time of writing. It is easy to ascribe the relative magnitudes of human tragedy, which are the opposite of the relative seismic magnitudes, entirely to the more advanced infrastructure of one of South America’s most advanced countries compared with that of one of the world’s poorest. But that is not the full story. Haiti suffered from a shallow event very close to major population centres whose energy easily reached the surface. The fault responsible involved transverse horizontal movements that sheared through thick soft coastal sediments, which liquefied beneath Port au Prince. That offshore of Chile was much deeper, on a subduction zone and involved vertical movements, so much of its energy was dissipated deep in the crust, yet the area of structural damage along Chile’s narrow coastal fringe is much larger than in Haiti.
Sure, Chile has long had stringent regulations for seismic safety of construction and a state of emergency preparedness commensurate with its history of devastating earthquakes, including the largest ever recorded on 26 May 1960 with magnitude 9.5 that released about ~32 times more energy than the recent one. It is a country well-endowed with income from its huge mining operations, well-developed wineries and much else, especially foreign investment. Haiti has nothing but the horrifying reputation of a string of governments. Until the recent tragedy the majority of its people were left to fend for themselves, close to the playgrounds of the super-rich and the offshore hidey holes of ‘non-doms’. Yet survivors in both countries face essentially the same physical privations of having to live rough and the lasting horror that no amount of wealth can remove. After experiencing the great Valdivia earthquake of 20 February 1835, also in Chile, Charles Darwin observed,
‘An earthquake like this at once destroys the oldest associations; the world, the very emblem of all that is solid, moves beneath our feet like a crust over fluid; one second of time conveys to the mind a strange idea of insecurity, which hours of reflection would never create.’
In both cases lessons may be learned, some socio-economic that are too obvious to repeat here. There is, though, one of that kind that transcends most of the others: the 21st century’s first decade has seen a seismic death toll of 640 thousand; a fourfold increase over the previous 20 years fatalities. That is a reflection of increasing drift of especially poor people to cities. If their dwellings are easily smashed they stand little chance. So far, the pledges of aid for reconstruction in Haiti amount to about US$5000 for each damaged structure. For geoscientists, however, what is beginning to emerge from these and the various large earthquakes in Indonesia, Pakistan and China since 2004 is that past seismic history is a clue to future events.
Faults zones behave in a segmented fashion, each with its own crude cyclicity but each somewhat prone to being triggered by events from nearby sectors. Between 1750 to 1770 Haiti was repeatedly devastated when the culprit fault unleashed its pent up stresses. Since then it has been locked in the vicinity of Haiti, with tectonic motions of about 8 mm per year accumulating to the 2 m or so motion undergone by the fault on 12 January. Subduction zones accumulate strain in many sectors distributed along the plate boundary, sometimes locking as seamounts start to descend to ‘clog’ them. Statistical analysis of historical earthquakes and locating their probable epicentres in relation to fault segments, with estimates of their power that would now be measurable from seismograph data, can at least highlight future risk geographically even if timely predictions remain impossible. Yet will their be action that matches up to the potential hazard? 2000 years ago the destruction of Pompeii and Herculaneum in the Bay of Naples by Vesuvius was recorded in graphic detail of which the excavations presented a gruesome reminder. Yet Naples expands to urbanise the very slopes of Europe’s most dangerous natural threat.
See also: Bilham, R. 2010. Lessons from the Haiti earthquake. Nature, v. 463, p. 878-879.
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Evolution of first land vertebrates in disarray
The finding of Tiktaalik, a supposed ‘missing link’ between bony fishes and amphibians (see A fish-quadruped missing link in EPN issue for May 2006) seemed to resolve the descent of tetrapods nicely. As is common, if inconvenient, nature has thrown a spanner in the works through a remarkable find in Polish rocks much older than those containing Tiktaalik and more evolved tetrapods (Niedźwiedski, G. et al. 2010. Tetrapod trackways from the early Middle Devonian period of Poland. Nature, v. 463, p. 43-48). Quarrymen unearthed extensive tracks appeared during excavation of intertidal limestones of the Middle Devonian Eifelian Stage (392-398 Ma). The bedding surface also shows raindrop pits and desiccation cracks, so the tracks were made by creatures able to survive out of water. The prints (up to 26 cm wide) are three times bigger than the paws of later amphibians that left fossil remains, but like them they show signs of more than 5 toes. The maker of one trackway was a good walker, having left no trace of dragging its belly through the mud, and it either had no tail or carried it aloft since there is no trail left by a tail either. Another, smaller animal left a separate trackway showing a very different gait. There seems little doubt that these animals were well advanced towards completely terrestrial lifestyles. Tiktaalik from 380 Ma sediments in Arctic Canada obviously cannot have been ancestral to them, and nor are there any fossils from the Middle Devonian that look like candidates. The hunt is on for fossilised remains of whatever walked the walk, and may emerge in the not-too-distant future from subtidal sediments of the same formation.
See also: Janvier, P. & Clément, G. 2010. Muddy tetrapod origins. Nature, v. 463, p. 40-41.
‘Roger, I think that triffid just moved’
The nasty surprise awaiting the bulk of human population blinded by radiation from a meteor shower in John Wyndham’s Day of the Triffids was that the genetically engineered, oil-yielding triffid plants could not only deal out deadly stings but they walked and ate dead meat. So it is that palaeontologists have found with the flabby, quilted bag-like organisms of the late Neoproterozoic Ediacaran fauna. They were animals of some kind, but hitherto considered to be completely sessile, except in larval form. They seem not to have been able to bite or gnaw, but probably absorbed victuals through their skins. Imagine the shock when palaeontologists from Oxford and Memorial University of Newfoundland found trackways in the famous biome of Mistaken Point in Newfoundland (Liu, A.G. et al. 2010. First evidencee for locomotion in the Ediacaran biota from the 565 Ma Mistaken Point Formation, Newfoundland. Geology, v. 38, p. 123-126). This throws an entirely new light on the very first sizeable animals: some of them were muscular. But not very adventurous, for the trails are only up to 17.2 cm long. Several of the traces show curved ridges, much like though far smaller than those left in wet sand by a buttock-shuffling baby, but ascribed by the authors to use of an ‘inflatable pedal disk’ in the manner of some cnidarians today – they ‘blurted’ along no doubt. The darned things must have had a purpose in moving, and chasing down prey springs easily to mind, only to be swiftly rejected. Alarmingly, at least for their totally torpid companions, some of the trackways clearly end in a depression: did they lie in wait? Yet not a one shows the telltale three-fold pedestal symmetry of Wyndham’s triffids…
Believable Archaean fossils
Some years back a major spat broke out over the reality of microscopic features purported to be evidence for bacterial life in 3.5 Ga rocks from Western Australia (See Doubt cast on earliest bacterial fossils in April 2002 issue of EPN), which has rumbled on ever since among highly regarded groups of palaeontologists. Those who refuted those finds as merely mineralogical structures that just seem to look biogenic have more work pending. Much more convincing evidence has been found in 3.2 Ga cherty rocks from South Africa (Javaux, E.J. et al. 2010. Organic-walled microfossils in 3.2-billion-year-old shallow marine siliciclastic deposits. Nature, v. 463, p. 934-938). They are big, by microfossil standards, 3-dimensional structures up to a third of a millimetre across, and clearly resemble cells. Some have even been separated from their matrices by dissolving away silica with hydrofluoric acid, so are not merely figments of the authors’ imagination. They are carbonaceous with very negative δ13C values typical of organically processed carbon and show abundant evidence of intricate structures found in living cells. Raman infrared spectroscopy also shows that they have been metamorphosed at the same grade as the rock that host them, so they cannot be later contaminants. In all these respects the little spherules are a cut above previously described structures reckoned to have been early Archaean life forms, convincingly taking concrete evidence for the existence of living things back a remarkable billion years: the previous oldest true fossils are about 2.2 billion years old.
In one respect the find may be truly breath taking. Spherules this size cannot be from the life-domain Archaea, and at the very least they are particularly large cells of Bacteria. Yet, bacterial cells contain little that could produce such robust little objects, which resemble single-celled eukaryotes known as acritarchs. The earliest definite acritarchs data back to 1.8 Ga. Geochemical evidence for eukaryotes was not sought in the spherules, but there has been speculation that some Archaean rocks have yielded chemical biomarkers that point to the presence of the ancestors of multicelled life at an astonishingly early date in Earth’s history. Clearly Javaux and colleagues work is a precursor of a lot more, now that we have hard-to-refute evidence for 3.2 Ga life.
A ginger dinosaur
The Early Cretaceous of SE China has become justifiably famous by providing a regular supply of superbly preserved small dinosaurs and early birds believed to have had a dinosaurian ancestry in the Jurassic. We have become accustomed to seeing computer generated graphics of brightly coloured dinosaurs since the BBC series Walking with Dinosaurs, first broadcast in 1999, but they owe more to imaginative assumptions based on strongly patterned living lizards than to fossil evidence. That is set to change, with the discovery of actual colouring agents in a Chinese find (Zhang et al. 2010. Fossilized melanosomes and the colour of Cretaceous dinosaurs and birds. Nature, v. 463, p. 1075-1078). The melanosomes are in exquisitely preserved feathers that adorned and probably warmed small dinosaurs as well as the famous bird fossils from the same sedimentary rocks. One specimen of Sinornithosaurus may have sported a coat patterned in black and russet, while Sinosauropteryx seems to have had a tail and back crest striped in shades of red-brown. Could this be for camouflage, display or some aspect of regulating heat? The big leap follows some 6 months on from the discovery of melanosomes in bird feathers from Eocene oil shales in Germany, that may have given them a starling- or hummingbird-like iridescent sheen (Vinther, J. et al. 2009. Structural coloration in a fossil feather. Biology Letters, v. 6, p. 128-131). The huge diversity of modern coloration among birds, from feathers and in the skins of lizards is widely believed to function primarily as a species-dependent means of display, with some influence from camouflage and thermal properties. Whichever, it must have been an integral aspect of speciation for a very long time indeed, yet even the best fossils cannot yield full ornament information, and reconstructions will rely on artistic licence, but now with a little more confidence that creatures didn’t just come in one colour, like Model-T Fords.
To spice up the stereotypical view that ginger = bad-tempered it seems that as well as being mottled with that hue Sinornithosaurus may have been venomous (Gong, E. et al. 2010. The birdlike raptor Sinornithosaurus was venomous. Proceedings of the National Academy of Science, v. 107 p. 766-768). Its skull shows grooved teeth, the grooves leading to a pocket at the base of the teeth. It may also have evolved to feed on birds…
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Joining the Neoproterozoic dots
Riven by the effects of at least two Wilson cycles of rifting drifting and collision, and then covered by a variety of later sediments, late-Precambrian rocks at high latitudes around today’s North Atlantic are nowhere near as coherent as their counterparts in, for instance, Africa. Also they have a long history of field investigation that began long before the unifying theory of plate tectonics, using a parochial rather than a ‘joined-up’ approach. Consequently there is a vast literature, as witness that of say the Moines or the Dalradian in Scotland, which has strangely acted as a hindrance rather than a boon to synthesisers: not that attempts haven’t been made in recent decades. Interestingly, a multi-hemisphere approach to unification, combining Australian and British geologists, seems to have made a great deal of ground (Cawood, P.A. et al. 2010. Neoproterozoic orogeny along the margin of Rodinia: Valhalla orogen, North Atlantic. Geology, v. 38, p. 99-102).
The Rodinia (‘Motherland’) supercontinent united all continental lithosphere at the end of the Mesoproterozoic era, existed between 1100 and 750 Ma, then broke into eight drifting continents during the Neoproterozoic. Like the later Pangaea (‘all of mother Earth’) formed when all these wandering masses finally clanged together again, conditions deep in the interior of Rodinia were probably tectonically and geomorphologically almost static. All the action would have been around its rim, towards which much of global sea-floor spreading ultimately was directed. Far older continental material now juxtaposed across the high-latitude North Atlantic was in just such an exposed position at the edge of the supercontinent; Greenland abutting the present Baltic crystalline mass. Local sea-floor spreading twisted Baltica from this part of Rodinia in a clockwise manner, to leave a large triangular sea in its wake. This Asgard Sea (why not Toblerone?) received debris from uplifted masses of older crust, to fill a deep sedimentary basin ready for deformation should tectonics warrant that. Two such episodes (980-910, 830-710 Ma) created the older Neoproterozoic metamorphic belts which have long drawn geologists to study Greenland, Scotland and Scandinavia in great detail: for British geologists the attraction was the complexity of the Moine Schists in which John Ramsay famously laid the foundations of modern polyphase structural analysis in the late 1950s and 1960s. A noteworthy point is that by comparison with most mountain belts, the Valhalla orogen took an awfully long time to form: around 300 Ma.
An old theory resurrected
Before the wide acceptance of sea-floor spreading and continental drift geoscientists had to seek explanations for the common occurrence of very similar fossils on now widely separated land masses. On the other hand, Alfred Wegener used observations such as the presence of fossilised tongue-like Glossopteris leaves in the Permian sediments of all the southern continents, and similar distributions of reptiles to support his theory. His detractors tried to explain away the fossil evidence by suggesting now-vanished land bridges, ‘island hopping’, floating seeds, and natural Noah’s Arks carrying animals and so on. With the discovery of irrefutable evidence for sea-floor spreading Wegener was vindicated, albeit long after his death, and the views of his detractors became ridiculed and neglected in their turn. But one puzzle remained: the fauna of Madagascar. Beginning about 170 Ma ago, Madagascar along with India parted company with Africa, to the extent that Madagascar is now more than 430 km off the East African coast (India moved much further independently).
Madagascar, of course, is famous for its lemurs but its fauna includes other animals found nowhere else. Another oddity is that late-Mesozoic Malagasy sediments have yielded no evidence for ancestors to these animals, so the fauna could not have evolved from African stock set adrift with the microcontinent. The only explanation then seems to be that the little animal ancestors drifted on vegetation rafts from Africa – note this would be more unlikely for large animals. Yet today’s current patterns make any drift toward Madagascar highly unlikely. The puzzle may have been resolved, if one believes computer modelling, by the different surface flow patterns of the Indian Ocean during the Palaeocene (Ali, J.R. & Huber, M. 2010. Mammalian biodiversity on Madagascar controlled by ocean currents. Nature, v. 463, p. 653-656). At that time the drifting island was further south than it is now, and currents would intermittently have flowed from East Africa towards it. As it was driven northwards, so it entered the influence of the westward flowing, South Equatorial Current that now isolates it from its parent continent. The idea of rafting, first developed in 1940 by George Gaylord Simpson, an opponent of anything smacking of continental drift, also seems the only possibility if the arrival of New World monkeys in South America and other oddities are to be explained.
See also: Krause, D.W. 2010. Washed up in Madagascar. Nature, v. 463, p. 613-614.
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Geochemical prospecting on Mars
Since its atmosphere is so thin, there are things you can achieve from orbit around Mars that would be unthinkable for the Earth. One is imagery free of atmospheric shimmer or scattering, another is analysing gamma rays emitted by Martian rocks using a gamma-ray spectrometer (GRS), as carried by Mars Odyssey. Two processes produce the gamma rays: the decay of long-lived naturally-occurring radiogenic isotopes of potassium, uranium and thorium with their daughter isotopes, and by the interactions of high-energy cosmic-ray particles with other elements in surface materials. Again, with little atmosphere the Martian surface is heavily bombarded by cosmic rays. Using far larger gamma-ray detecting crystals carried on low-flying aircraft it is possible to remotely sense K, U and Th concentrations at the Earth’s surface. To get data on other terrestrial elements from far off would involve unsociable irradiation of the surface by artificial means.
Results from the Mars Odyssey GRS are somewhat blurred as the analysed radiation comes from 0.5º x 0.5º sampling ‘bins’ and is then filtered to a level of 5º x 5º (~ 25 x 25 km) (Taylor G.J. et al. 2010. Mapping Mars geochemically. Geology, v. 38, p. 183-186). So, the approach cannot match geological maps made by interpretation of high resolution images of reflected or thermal radiation. However, as well as K, U and Th estimates, the data cover Fe, Si, Ca, Cl and H2O: sufficient to crudely distinguish mafic and felsic igneous rocks and to detect any regional hydrothermal or groundwater alteration. The authors claim that the GRS separates much of the Equatorial region of Mars into six kinds of geochemical province, all of roughly basaltic composition. With an estimated SiO2 range from 46.7 to 49.8% that doesn’t promise much by way of fractionation on the scale of terrestrial magmagenesis; i.e. there are no significant intermediate or felsic igneous rocks. A CaO range of 7.5 to 11.4 does indicate varying plagioclase feldspar content, but no anorthosites, unlike the Moon. The greatest variation is in K and Th content, but that does not match the much larger ranges in terrestrial basalts. The geochemical provinces do not match even a simplified photogeological map of the planet, and it seems quite likely that such variation as there is could have resulted from slight weathering and movement of dust and sand. Will a single returned sample of Mars basalt be all that is needed to characterise the Red Planet? More to the point, how does the estimated chemistry match that of purported Martian meteorites, or for that matter the analyses performed on the surface by the Martian rovers Spirit and Opportunity and by the earlier Mars Pathfinder? There is no comment…but Mars Pathfinder surface analyses revealed andesitic rocks at its landing site with up to 55% SiO2.
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A challenge to sea-level calibration
As well as revealing the Milankovich pacemaker for past climate change, studies of oxygen isotopes from deep-water of benthic foraminifera in marine sediment cores also give a guide to the height of former sea levels. That approach is based on several assumptions, of which two are central. One is that the isolation of deep-water organisms from temperature variations at the sea surface, which control the take up of 18O by near surface plankton: well supported by the measured constancy of cold deep ocean water. The other is that oxygen is rapidly and homogeneously mixed throughout the ocean water column. The reason why good mixing is critical stems from the very purpose of measuring benthic oxygen isotopes, itself based on a sound assumption. Ice masses on land lock up a proportion of evaporated ocean water. Evaporation favours the lighter 16O isotope in water molecules over the heavier, so that atmospheric water vapour has a lower 18O/16O ratio than seawater. When snow falls and turns into glacial ice that build up ice caps, surface water of the oceans becomes depleted in 16O so that its 18O/16O ratio (standardised as the δ18O value) increases. That makes oceanic δ18O values, measured from benthic foram shells, an indirect or proxy measure of both the amount of ice locked up on land and changing sea levels: the principal quantification of past global climate change whose record goes back to the oldest preserved ocean floor (Lower Jurassic, ~205 Ma). Modern humans eventually left Africa to colonise the rest of the world sometime before 60 Ma ago, the first reliable age of evidence for colonisation outside Africa. Africa is surrounded by sea, except for the narrow strip of land into Palestine that ends up in a desert dead end to further migrations. So, it seems likely that the exodus was across the outlet of the Red Sea that would have become narrower and shallower as sea level fell when the Earth moved into the last glacial epoch after 117 thousand years ago, when sea-level was as high as it is today.
The assumption of rapid, efficient mixing of the oceans has not been thoroughly tested. In fact it is estimated that any complete turnover takes around a thousand years, so there is likely to be a significant time lag in the sea-floor record. New, independent evidence also suggests that the calibration of benthic δ18O needs revision (Dorale, J.A. et al. 2010. Sea-level highstand 81,000 years ago in Mallorca. Science, v. 327, p. 860-863). It comes from caves on the Mediterranean island of Mallorca that connect directly with the sea. Stalactites and stalagmites (collectively called speleothem) have formed in the caves, their growth being affected by flooding and drying as sea level rose and fell during the last 130 ka. At each flooding level encrustations formed around the speleothem to produce bulbous growths at different heights in the caves, which are clearly forming today at mean sea level. The researchers from the US, Mallorca, Italy and Romania dated the bulbs using the U/Th method appropriate for speleothems, and found three stages of formation: at 121, 116 and 80-82 ka. The two older encrustations are at ~2.6 m above modern sea level, bang on the oxygen isotope calibration for the end of the last interglacial. However, those formed between 80-82 ka ago – a period of warming during the overall trend to colder conditions as ice sheets grew – are about a metre above modern sea level: very different from the estimate of 10-20 m below based on the benthic δ18O calibration.
It is too early to tell in what quandary palaeo-oceanographers will be placed by this large discrepancy. There are four main possibilities for the aberrant results. First, the Mediterranean might have stood higher that global sea level for some reason, but that seems highly unlikely as the connection through the Straits of Gibraltar is deep enough to have maintained flow even at the last glacial maximum when global sea level was around 120 m below the present. Second is that the means of calibration using raised coral reefs on tectonically rising coastlines of New Guinea and Barbados is seriously out for part of the last glacial period. Thirdly, somehow the Mallorcan crust was depressed during the last glacial period. The island is rising at about 0.2 mm yr-1, which would give an uplift of 16 m since 81 ka, but that conflicts with the good match with the last highest sea level at 121 and 116 ka. Finally, the authors suggest that at 81 ka the volume of the world’s ice caps was much the same as today, despite the higher-than-present δ18O values in contemporary sea-floor sediments.
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Neanderthal ‘bling’
Led by João Zilhão of the University of Bristol, UK, a team of British, French, Italian and Spanish archaeologists and anthropologists have at a stroke rid our former companions in Europe, the Neanderthals, of the popular and academic stigma of being uncultured (Zilhao, J. and 16 others 2010. Symbolic use of marine shells and mineral pigments by Iberian Neandertals. Proceedings of the National Academy of Sciences, v. 107 p. 1023-1028). They wore jewellery in the form of necklaces and pendants of bivalve shells, remains of which have turned up in large numbers in caves and rock shelters in the interior of southeast Spain. Some of the perforated shells show clear signs of having been painted, and a few show grooves worn by string. They found even a paint container and painting tools made of small bones from a horse’s foot. The container and tools retain distinct traces of pigment made from the common iron colorants goethite, jarosite and hematite. One large, perforated scallop shell shows that its white interior was painted to match its reddish exterior.
It has often been commented that Neanderthal adornments ( a few possible finds precede this work) and intricate tools were simply copied from those of fully modern humans. The deposits containing this ornamentation are around 50 thousand years old: preceding modern human occupation of the Iberian Peninsula by at least 10 ka. Evidence for artistic work by early H. sapiens comes from South Africa as far back as 165 ka (see Technology, culture and migration in the Middle Palaeolithic of southern Africa in January 2009 EPN, and When and where ‘culture’ began in EPN of November 2007). Iron-based pigments are still widely used for body painting in many societies, but obviously that use will not feature directly in archaeological finds. Association of lumps of potential pigments with hominin tools go back even further in Africa, beyond the presence of fully modern humans, but to ascribe pieces of say hematite to cultural practice needs evidence for scraping or grinding. There seems no reason why Neanderthals and modern humans maintained an ancient cultural tradition.
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