This month’s stunning image from Earth Science Picture of the Day, taken on 8 September this year is of Iceland’s biggest fissure eruption (video clip) since 1875, in the Holuhraun lava field, which began on 31 August this year. The flow is about to meet the Jokulsa a Fjollum, a large river flowing from Iceland’s largest ice cap Vatnajokull. At the time of writing (29 September) lava is flowing along the river bed at around 1 km each day. So far, the flow has spread over 44 square kilometres, and risks blocking the Jokulsa a Fjollum where it flows through a narrow channel bounded by older lava flows. If that happens the river will form a substantial lake until it is able to flow over and erode the bedrock, and will also leave one of the country’s spectacular waterfalls (Sellfoss) dry.
Aerial View of Jökulsá á Fjöllum, Iceland, downstream of Holuhraun (credit: Wikipedia)
The fissure is connected to the large Bárðarbunga stratovolcano that lies beneath Vatnajokull, which is currently showing signs of subsidence, at about 40 cm each day, and seismicity. There are concerns that this activity may presage an eruption there which may melt large volumes of ice and perhaps release a flood or jökulhlaup from beneath the icecap. Such a flood would likely follow the course of the Jokulsa a Fjollum river.
It is barely credible that only two decades ago geoscientists who argued that extraterrestrial impacts had once had an important role in Earth history met with scorn from many of their peers; slightly mad, even bad and perhaps dangerous to know. Yet clear evidence for impacts has grown steadily, especially in the time before 2.5 billion years ago known as the Archaean (see EPN for March 2003 , April 2005, July 2012 , May 2014). Even in the 1990s, when it should have been clear from the golden years of lunar exploration that our neighbour had been battered at the outset of the Archaean, claims for terrestrial evidence of the tail-end of that cataclysmic event were eyed askance. Now, one of the pioneer researchers into the oldest terrestrial impacts, Don Lowe of Stanford University, California has, with two colleagues, reported finds of yet more impact-related spherule beds from the famous Archaean repository of the Barberton Mountains in South Africa (Lowe, D.R. et al. 2014. Recently discovered 3.42-3.23 Ga impact layers, Barberton Belt, South Africa: 3.8 Ga detrital zircons, Archaean impact history and tectonic implications. Geology, v. 42, p. 747-750).
Barberton greenstone belt, South Africa (credit: Barberton World Heritage Site)
Like four other such layers at Barberton, those newly described contain several types of spherules, degraded to microcrystalline alteration products of the original glasses. Some of them contain clear evidence of originally molten droplets having welded together on deposition. Their contrasted geochemistry reveals target rocks ranging in composition from well-sorted quartz sands to intermediate, mafic and ultramafic igneous rocks. Some beds are overlain by chaotic deposits familiar from more recent times as products of tsunamis, with signs that the spherules themselves had been picked up and transported.
Dated by their stratigraphic relations to local felsic igneous rocks, the spherule beds arrived in pulses over a period of about 240 Ma between 3.42 to 3.23 Ga. Even more interesting, the overlying tsunami beds have yielded transported zircons that extend back to 3.8 Ga spanning the Archaean history of the Kaapvaal craton of which the Barberton greenstone belt rests and indeed that of many Eoarchaean cratons; the Earth’s oldest tangible continental crust. The zircons may reflect the depth to which the impacts penetrated, possibly the base of the continental crust. It isn’t easy to judge the size of the responsible impactors from the available evidence, but Lowe and colleagues suggest that they were much larger than that which closed the Mesozoic at the Cretaceous-Palaeogene boundary; perhaps of the order of 20-70 km across. So, although the late, heavy bombardment of the Moon seems to have closed at around 3.8 Ga, from evidence yielded by the Apollo programme, until at least half a billion years later large objects continued to hit the Earth more often than expected from the lunar record. Lowe has suggested that this tail-end of major bombardment on Earth may eventually have triggered the onset of plate tectonics as we know it now.
Aside from a swift but highly unlikely abandonment of fossil fuels, reduction of greenhouse warming depends to a large extent, possibly entirely, on somehow removing CO2 from the atmosphere. Currently the most researched approach is simply pumping emissions into underground storage in gas permeable rock, but an important target is incorporating anthropogenic carbon in carbonate minerals through chemical interaction with potentially reactive rocks. In a sense this is a quest to exploit equilibria involving carbon compounds that dominate natural chemical weathering and to sequester CO2 in solid, stable minerals.
The two most likely minerals to participate readily in weathering that involves CO2 dissolved in water are plagioclase feldspar, a calcium-rich aluminosilicate and olivine, a magnesium silicate. Both are abundant in mafic and ultramafic rocks, such as basalt and peridotite, which themselves are among the most common rocks exposed at the Earth’s surface. The two minerals, being anhydrous, are especially prone to weathering reactions involving acid waters that contain hydrogen ions, and in the presence of CO2 they yield stable carbonates of calcium and magnesium respectively. Despite lots of exposed basalts and ultramafic rocks, clearly such natural sequestration is incapable of absorbing emissions as fast as they are produced.
One means of speeding up weathering is to grind up plagioclase- and olivine-bearing rocks and spread the resulting gravel over large areas; as particles become smaller their surface area exposed to weathering increases. Yet it doesn’t take much pondering to realise that a great deal of energy would be needed to produce sufficient Ca- and Mg-rich gravel to take up the approximately 10 billion tonnes of CO2 being released each year by burning fossil fuels: though quick by geological standards the reaction rates involved are painfully slow in the sense of what the climatic future threatens to do. So is there any way in which these reactions might be speeded up?
Two biological agencies are known to accelerate chemical weathering, or are suspected to do so: plant roots and animals that live in soil. Ronald Dorn of Arizona State University set out to investigate the extent to which such agencies do sequester carbon dioxide, under the semi-arid conditions that prevail in Arizona and Texas (Dorn, R.I. 2014. Ants as a powerful biotic agent of olivine and plagioclase dissolution. Geology, v. 42, p. 771-774). His was such a simple experiment that it is a wonder it had not been conducted long ago; but it actually took more than half his working life. Spaced over a range of topographic elevations, Dorn used an augur at each site to drill five half-metre holes into the root mats of native trees, established ant and termite colonies and bare soil surfaces free of vegetation or animal colonies, filling each with sand-sized crushed basalt.
Film poster for Empire of the Ants (starring Joan Collins) (credit: Wikipedia)
Every five years thereafter he extracted the basalt sand from one of the holes at each site and each soil environment. To assess how much dissolution had occurred he checked for changes in porosity, and heated the samples to temperatures where carbonates break down to discover how much carbonate had been deposited. That way he was able to assess the cumulative changes over a 25 year period relative to the bare-ground control sites. The results are startling: root mats achieved 11 to 49 times more dissolution than the control; termites somewhat less, at 10 to 19 times; while ants achieved 53 to 177 times more dissolution. While it was certain that the samples had been continuously exposed to root mats throughout, the degree of exposure to termites and ants is unknown, so the animal enhancements of dissolution are probably minima.
Microscopic examination of mineral grains exposed to ant activity shows clear signs of surface pitting and other kinds of decay. Chemically, the samples showed that exposure to ants consistently increased levels of carbonate in the crushed basalt sand compared with controls, with levels rising by 2 to 4% by mass, with some variation according to ant species. Clearly, there is some scope for a role for ants in carbon sequestration and storage; after all, there are estimated to be around 1013 to 1016 individual ants living in the world’s soils. In the humid tropics the total mass of ants may be up to 4 times greater than all mammals, reptiles and amphibians combined. There is more to learn, but probably a mix of acid secretions and bioturbation by ants and termites is involved in their dramatic effect on weathering. One interesting speculation is that ants may even have played a role in global cooling through the Cenozoic, having evolved around 100 Ma ago.
The Arabian Peninsula from the SeaWIFS satellite (credit: Wikipedia)
From time to time between 130 and 75 ka fully modern humans entered the Levant from Africa, which is backed up by actual fossils. But up to about 2010 most palaeoanthropologists believed that they moved no further, because of the growth of surrounding deserts, and probably did not return to the Middle East until around 45 ka. The consensus for the decisive move out of Africa to Eurasia centred on crossings of the Straits of Bab el Mandab at the entrance to the Red Sea, when sea level fell to a level that would have allowed a crossing by rafting over narrow seaways. The most likely time for such n excursion was during a brief cool/dry episode around 67 ka that coincided with an 80 m fall in global sea level: the largest since the previous glacial maximum (see Evidence for early journeys from Africa to Asia).
In 2011 finds reported from the United Arab Emirates of ‘East African-looking’ Middle Palaeolithic tools in sediment layers dated at 125, 95 and 40 ka led some to speculate that there must have been an eastward move from the Levant by anatomically modern humans (see Human migration – latest news). That view stemmed from the fact that the earliest date was during the last interglacial when sea level would have been as high as it is today, and around 95 ka it would have been little different. That report coincided with others about freshwater springs having emanated from uplifted reefs around the edges of the Arabian Peninsula during the last interglacial, and the existence of substantial lakes deep within the subcontinent around that time (see Water sources and early migration from Africa). Substantial funding followed such exciting news and results of new research are just beginning to emerge (Lawler, A. 2014. In search of Green Arabia. Science, v. 345, p. 994-999).
Al Ain, a rare spring-fed oasis in the eastern Rub al Khali near the UAE-Oman border (credit: Wikipedia)
A team led by Michael Petraglia of the University of Oxford has used field surveys and remote sensing to reveal a great many, now-vanished lakes across the Arabian Peninsula, including many in the fearsome Rub al Khali or Empty Quarter. They are linked by an extensive, partly sand-hidden network of palaeochannels, which include several of the major wadis; a system that once drained towards the Persian Gulf. As well as abundant freshwater molluscs and other invertebrates, former lakeshore sediments are littered with huge numbers of stone tools, also with East African affinities (Scerri, E.M.L. et al. 2014. Unexpected technological heterogeneity in northern Arabia indicates complex Late Pleistocene demography at the gateway to Asia. Journal of Human Evolution, In Press http://dx.doi.org/10.1016/j.jhevol.2014.07.002). Using optically stimulated luminescence dating, which shows how long stone objects have been buried, the British team has found tools dating back as long as 211 ka, with a cluster of dates between 90 to 74 ka. Modern humans, Neanderthals and even Denisovans may have made these tools; only associated fossil remains will tell. Yet it is already clear that for lengthy periods – perhaps of a few hundred or thousand years – the hyper-arid interior of Arabia was decidedly habitable. It may have been a thriving outpost of emigrants from Africa, whose abandonment as climate shifted to extreme dryness as the last interglacial gave way to Ice Age conditions, could well have been the source of the great migration that colonised the rest of the habitable world. Petraglia’s team has already courted controversy with their claim for anatomically modern humans’ tools in South Indian volcanic ash beds that date to the Toba eruption around 74 ka: considerably earlier than the more widely accepted post-65 ka dates of human eastward migration.
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