Tag: Carbonaceous chondrite

Asteroid Bennu: a ‘lucky dip’ for NASA and planetary science

Published on by zooks777Leave a comment

I must have been about ten years old when I last saw a ‘lucky dip’ or ‘bran tub’ at a Christmas fair.  You paid two shillings (now £0.1) to rootle around in the bran for 30 seconds and grab the first sizeable wrapped object that came to hand:. In my case that would be a cheap toy or trinket, but you never knew your luck as regards the top prize. There is a small asteroid called 101955 Bennu, about half a kilometre across, whose orbit around the Sun crosses that of the Earth. So it’s a bit scary, being predicted to pass within 750,000 km of Earth in September 2060 and has a 1 in 1,880 chance of colliding with us between 2178 and 2290 CE. Because Earth-crossing asteroids are a cheaper target than those in the Asteroid Belt, in 2016 NASA launched a mission named OSIRIS-REx to intercept Bennu, image it in great detail, snaffle a sample and ultimately return the sample to Earth for analysis. This wasn’t a shot in the dark, as a lot of effort and funds were expended to target and then visit Bennu. But unlike me at the fair ground, NASA will be very happy with the outcome.

The asteroid Bennu, showing its oblate spheroidal shape, due to rotation, and its rubbly structure. Source: NASA/Goddard/University of Arizona via Wikimedia Commons

Bennu is a product of what might be regarded as ‘space sedimentation’, indeed a kind of conglomerate, being made up of boulders up to 58 m across set in gravelly and finer debris or ‘regolith’. High-resolution images revealed veins of carbonate minerals in the boulders. They suggest hydrothermal activity in a much larger parent body – one of many proto-planets accreted from interstellar gas and dust as the Solar System first began to form over 4.5 billion years ago. Its collision with another sizeable body knocked off debris to send a particulate cloud towards the Sun, subsequently to clump together as Bennu by mutual gravitational attraction. The carbonate veins can only have formed by circulation of water inside Benno’s  parent.

The ‘REx’ in the mission’s name is an acronym for ‘Regolith Explorer’. Sampling was accomplished on 20 October 2020 by a soft landing that drove a sample into a capsule, and then OSIRIS-REx ‘pogo-sticked’ off with the booty. The capsule was dropped off by parachute after the mission’s return on 24 September 2023, in the manner of an Amazon delivery by drone to a happy customer. So, you can understand my ‘lucky dip’ metaphor. And NASA certainly was ‘lucky’ as the contents turned out to be astonishing, as related two years later by the analytical team in the US, led by NASA’s Angel Mojarro (Mojarro, A. et al. 2025.Prebiotic organic compounds in samples of asteroid Bennu indicate heterogeneous aqueous alteration. Proceedings of the National Academy of Science, v. 122, article e2512461122; DOI: 10.1073/pnas.2512461122).

The rock itself is made from bits of carbonaceous chondrite, the most primitive matter orbiting the Sun. It contains fifteen amino acids, including all five nucleobases that make up RNA and DNA – adenine (A), guanine (G), cytosine (C), thymine (T) and uracil (U) – as in AUGC and AGCT. Benno’s complement of amino acids included 14 of the 20 used by life on Earth to synthesise proteins. The fifteenth, tryptophan, has never confidently been seen in extraterrestrial material before. Alkylated polycyclic aromatic hydrocarbons, also found in Bennu, are seen in abundance in interstellar gas clouds and comets by detecting their characteristic fluorescence when illuminated by mid-infrared radiation from hot stars using data from the Spitzer and James Webb Space Telescopes. These prebiotic organic compounds have been suggested to have played a role in the origin of life, but exposure to many produced by human activities are implicated in many cancers and cardiovascular issues.  A second paper by Japanese biochemists and colleagues from the US was also published in early December 2025 (Furukawa, Y. and 13 others 2025. Bio-essential sugars in samples from asteroid Bennu. Nature Geoscience, v. 12, online article; DOI: 10.1038/s41561-025-01838). The authors identified several kinds of sugars in a sample from Bennu, including ribose – essential for building RNA – and glucose. Bennu also contains formaldehyde – a precursor of sugars – perhaps originally in the same brines in which the amino acids formed.

Yet another publication coinciding with the aforementioned two focuses on products of the oldest event in the formation of Bennu: its content of pre-solar grains (Nguyen, A.N. et al. 2025. Abundant supernova dust and heterogeneous aqueous alteration revealed by stardust in two lithologies of asteroid Bennu. Nature Astronomy, v. 9, p. 1812-1820; DOI: 10.1038/s41550-025-02688-3).  In 1969 a 2 tonne carbonaceous chondrite fell near Allende in Mexico. The largest of this class ever found, it contained tiny, pale inclusions that eight years of research revealed to represent materials completely alien to the Solar System. They are characterised by proportions of isotopes of many elements that are very different from those in terrestrial materials. The anomalies could only have formed by decay of extremely short-lived isotopes that highly energetic cosmic rays produce in a manner analogous to neutron bombardment: they are products of nuclear transmutation. It is possible to estimate when the parent isotopes produced the anomalous ‘daughter’ products. One study found ages ranging from 4.6 to 7.5 Ga: up to three billion years before the Solar System began to form. It is likely that the grains are literally ‘star dust’ formed during supernovae in nearby parts of the Milky Way galaxy. Bennu samples contain six-times more presolar grains than any other chondritic meteorites. Nguyen et al. geochemically teased out grains with different nucleosynthetic origins. These ancient relics point to Bennu’s formation in a region of the presolar cloud that preceded the protoplanetary disk and was a mix of products from several stellar settings.

The results from asteroid Bennu support the key idea that that amino acid building blocks for all proteins and the nucleobases of the genetic code, together with other biologically vital compounds arose together in a primitive asteroid.  Its evolution provided the physical conditions, especially the trapping of water, for the interaction of simpler components manufactured in interstellar clouds. Such ‘fertile’ planetesimals and debris from them almost certainly accreted to form planets and endowed them with the potential for life. What astonishes me is that Bennu contains the five nucleobases used in terrestrial genetics and 70% of the amino acids from which all known proteins are assembled by terrestrial life. But, as I try to explain in my book Stepping Stones: The Making of Our Home World, life as we know it arose, survived and evolved through a hugely complex concatenation of physical and chemical events lasting more than 4.5 billion years. The major events and the sequences in which they manifested themselves may indeed have been unique. Earth is a product of luck and so are we!

See also: Tabor, A. et al. 2025. Sugars, ‘Gum,’ Stardust Found in NASA’s Asteroid Bennu Samples. NASA article 2 December 2025. Glavin, D.P. and 61 others 2025. Abundant ammonia and nitrogen-rich soluble organic matter in samples from asteroid (101955) Bennu. Nature Astronomy, v. 9, p. 199-210; DOI: 10.1038/s41550-024-02472-9

The peptide bond that holds life together may have an interstellar origin

Published on by zooks777Leave a comment

In the 1950s Harold Urey of the University of Chicago and his student Stanley Miller used basic lab glassware containing 200 ml of water and a mix of the gases methane (CH4), ammonia (NH3) and hydrogen sulfide (H2S) to model conditions on the early Earth. Heating this crude analogue for ocean and atmosphere and continuous electrical discharge through it did, in a Frankensteinian manner, generate amino acids. Repeats of the Miller-Urey experiment have yielded 10 of the 20 amino acids from which the vast array of life’s proteins have been built. Experiments along similar lines have also produced the possible precursors of cell walls – amphiphiles. In fact, all kinds of ‘building blocks’ for life’s chemistry turn up in analyses of carbonaceous chondrite meteorites and in light spectra from interstellar gas clouds. The ‘embarrassment of riches’ of life’s precursors from what was until the 20th century regarded as the ‘void’ of outer space lacks one thing that could make it a candidate for life’s origin, or at least for precursors of proteins and the genetic code DNA and RNA. Both kinds of keystone chemicals depend on a single kind of connector in organic chemistry.

Reaction between two molecules of the amino acid glycene that links them by a peptide bond to form a dipeptide. (Credit: Wikimedia Commons)

Molecules of amino acids have acidic properties (COOH – carboxyl) at one end and their other end is basic (NH2 – amine). Two can react by their acid and basic ‘ends’ neutralising. A hydroxyl (OH–) from carboxyl and a proton (H+) from amine produce water. This gives the chance for an end-to-end linkage between the nitrogen and carbon atoms of two amino acids – the peptide bond. The end-product is a dipeptide molecule, which also has carboxyl at one end and amine at the other. This enables further linkages through peptide bonds to build chains or polymers based on amino acids – proteins. Only 20 amino acids contribute to terrestrial life forms, but linked in chains they can form potentially an unimaginable diversity of proteins. Formation of even a small protein that links together 100 amino acids taken from that small number illustrates the awesome potential of the peptide bond. The number of possible permutations and combinations to build such a protein is 20100 – more than the estimated number of atoms in the observable universe! Protein-based life has almost infinite options: no wonder that ecosystems on Earth are so diverse, despite using a mere 20 building blocks. Simple amino acids can be chemically synthesised from C, H, O and N. About 500 occur naturally, including 92 found in a single carbonaceous chondrite meteorite. They vastly increase the numbers of conceivable proteins and other chain-molecules analogous to RNA and DNA: a point seemingly lost on exobiologists and science fiction writers!

Serge Kranokutski of the Max Planck Institute for Astronomy at the Friedrich Schiller University in Jena, German and colleagues from Germany, the Netherlands and France have assessed the likelihood of peptides forming in interstellar space in two publications (Kranokutski S.A. and 4 others 2022. A pathway to peptides in space through the condensation of atomic carbon. Nature Astronomy, v, 6, p. 381–386; DOI: 10.1038/s41550-021-01577-9. Kranokutski, S.A. et al. 2024. Formation of extraterrestrial peptides and their derivatives. Science Advances, v. 10, article eadj7179; DOI: 10.1126/sciadv.adj7179). In the first paper the authors show experimentally that condensation of carbon atoms on cold cosmic dust particles can combine with carbon monoxide (CO) and ammonia (NH3) form amino acids. In turn, they can polymerise to produce peptides of different lengths. The second demonstrates that water molecules, produced by peptide formation, do not prevent such reactions from happening. In other words, proteins can form inorganically anywhere in the cosmos. Delivery of these products, through comets or meteorites, to planets forming in the habitable ‘Goldilocks’ zone around stars may have been ‘an important element in the origins of life’ – anywhere in the universe. Chances are that, compared with the biochemistry of Earth, such life would be alien in an absolute sense. There are effectively infinite options for the proteins and genetic molecules that may be the basis of life elsewhere, quite possibly on Mars or the moons of Jupiter and Saturn: should it or its chemical fossils be detectable.

A ‘recipe’ for Earth’s accretion, without water

Published on by zooks777Leave a comment

The Earth continues to collect meteorites, the vast majority of which are about as old as our planet; indeed many are slightly older. So it has long been thought that Earth originally formed by gravitational accretion when the parental bodies of meteorites were much more abundant and evenly distributed. Meteorites fall in several classes, metallic (irons) and several kinds that contain silicate minerals, some with a metallic component (stony irons) others without, some with blebs or chondrules of once molten material (chondrites) and others that do not (achondrites), and more subtle divisions among these general groups. In the latter half of the 20th century geochemists and cosmochemists became able to compare the chemical characteristics of different meteorite classes with that of the Sun –from its radiation spectrum – and those of different terrestrial rocks – from direct analysis. The relative proportions of elements in chondrites turned out to match those in the Sun – inherited from the gas nebula from which it formed – better than did other classes. The best match with this primitive composition turned out to be the chemistry of carbonaceous chondrites that contain volatile organic molecules and water as well as silicates and sulfides. The average chemistry of one sub-class of carbonaceous chondrites (C1) has been chosen as a ‘standard of standards’ against which the composition of terrestrial rocks are compared in order that they can be assessed in terms of their formative processes relative to one another. For a while carbonaceous chondrites were reckoned to have formed the bulk of the Earth through homogeneous accretion: that is until analyses became more precise at increasingly lower concentrations. This view has shifted …

Geochemistry is a complex business(!), bearing in mind that rocks that can be analysed today predominantly come from the tiny proportion of Earth that constitutes the crust. The igneous rocks at the centre of wrangling how the whole Earth has evolved formed through a host of processes in the mantle and deep crust, which have operated since the Earth formed as a chemical system. To work out the composition of the primary source of crustal igneous rocks, the mantle, involves complex back calculations and modelling. It turns out that there may be several different kinds of mantle. To make matters worse, those mantle processes have probably changed considerably from time to time. To work back to the original formative processes for the planet itself faces the more recent discovery that different meteorite classes formed in different ways, different distances from the Sun and at different times in the early evolution of the pre-Solar nebula. Thankfully, some generalities about chemical evolution and the origin of the Earth can be traced using different isotopes of a growing suite of elements. For instance, lead isotopes have revealed when the Moon formed from Earth by a giant impact, and tungsten isotopes narrow-down the period when the Earth first accreted. Incidentally, the latest ideas on accretion involve a series of ‘embryo’ planets between the Moon and Mars in size.

An example of an E-type Chondrite (from the Ab...
An example of an enstatite chondrite (from the Abee fall) in the Gallery of Minerals at the Royal Ontario Museum. (Photo credit: Wikipedia)

Calculating from a compendium of isotopic data from various types of meteorite and terrestrial materials, Nicolas Dauphas of the University of Chicago has convincingly returned attention to a model of heterogeneous accretion of protoplanetary materials from different regions of the pre-Solar nebula (Dauphas, N. 2017. The isotopic nature of the Earth’s accreting material through time. Nature, v. 541, p. 521-524; doi:10.1038/nature20830). His work suggests that the first 60% of Earth’s accretion involved materials that were a mixture of meteorite types, half being a type known as enstatite chondrites. These meteorites are dry and contain grains of metallic iron-nickel alloy and iron sulfides set in predominant MgSiO3 the pyroxene enstatite. The Earth’s remaining bulk accumulated almost purely from enstatite-chondrite material. A second paper in the same issue of Nature (Fischer-Gödde, M. & Kleine, T. 2017. Ruthenium isotopic evidence for an inner Solar System origin of the late veneer. Nature, v. 541, p. 525-527; doi:10.1038/nature21045) reinforces the notion that the final addition was purely enstatite chondrite.

This is likely to cause quite a stir: surface rocks are nothing like enstatite chondrite and nor are rocks brought up from the upper mantle by volcanic activity or whose composition has been back-calculated from that of surface lavas; and where did the Earth’s water at the surface and in the mantle come from? It is difficult to escape the implication of a mantle dominated by enstatite chondrite From Dauphas’s analysis, for lots of other evidence from Earth materials seem to rule it out. One ‘escape route’ is that the enstatite chondrites that survived planetary accretion, which only make up 2% of museum collections, have somehow been changed during later times.  The dryness of enstatite chondrites and the lack of evidence for a late veneer of ‘moist’ carbonaceous chondrite in these analyses cuts down the options for delivery of water, the most vital component of the bulk Earth and its surface.  Could moister meteorites have contributed to the first 60% of accretion, or was  post-accretion cometary delivery to the surface able to be mixed in to the deep mantle? Nature’s News & Views reviewer, Richard Carlson of the Carnegie Institution for Science in Washington DC, offers what may be a grim outlook for professional meteoriticists: that perhaps “the meteorites in our collection are not particularly good examples of Earth’s building blocks” (Carlson, R.W. 2017. Earth’s building blocks. Nature, v. 541, p. 468-470; doi:10.1038/541468a).

Animation of how the Solar System may have formed.

Related articles

Whence Earth’s water?

Published on by zooks777Leave a comment

English: Carbonaceous chondrite Meteorite. The...
Carbonaceous chondrite meteorite. (credit: Mila Zinkova via Wikipedia)

English: Image of comet C/1996 B2 (Hyakutake),...
Comet Hyakutake. (credit: E. Kolmhofer & H. Raab via Wikipedia)

Because they can be so big, consist mainly of water ice and there are probably a great many lurking in the outer reaches of the solar system impacting comets have long been thought to have delivered the water that makes the Earth so dynamic and, so far as we know, the only place in near-space that hosts complex life. Remote sensing studies of the isotopic composition of water in one comet (Hartley 2) caused great excitement in 2011 by showing that its ratio of deuterium to hydrogen was very similar to that of Earthly ocean water. Other D:H ratios have recently been published from a suite of meteorites gleaned from the surface of Antarctic ice (Alexander, C.M.O’D. et al. 2012. The provenances of asteroids, and their contributions to the volatile inventories of the terrestrial planets. Science, v. 337, p. 721-723). These meteorites are carbonaceous chondrites thought to be the source of much of the solid material in planets of the Inner Solar System. To cut short a long and closely argued argument, it seems that the CI-type chondrites’ water is isotopically quite different from that in analysed comets, knocking another popular hypothesis on the head; that comets and carbonaceous chondrites formed in the same part of the Solar System.

Since hydrocarbons in comets – known from interplanetary dust particles – contain hydrogen with a far richer complement of its heavy isotope deuterium than does cometary water ice, the crashing of entire comets onto planets such as the Earth would not produce the observed terrestrial D:H ratio even though their water ice alone does match it. The US, British and Canadian meteoriticists conclude what seems to be a unifying explanation whereby CI chondritic solids and volatiles alone would have been able to form the Inner Planets and their various complements of water by initial accretion. Comets as a second-stage source, in this account, are relegated to mere curiosities of the Solar System with little role to play other than occasional big impacts that may, or may not, have influenced evolution by the power that they delivered not through their chemistry.

Related articles