The Martian ‘sexy beast’

Artist’s concept of NASA’s Mars Science Laboratory (Curiosity) near a canyon on Mars. (Credit: NASA-JPL via Wikipedia)

Why is ’Curiosity’ the latest Mars rover aimed to land at Gale Crater? It seems to have been filled with stratified sediments deposited in the crater over perhaps as long as two billion years after it formed by a meteorite impact. The sediments now occur as a relic of later aeolian erosion at the centre of the crater in the form of a large mound that Curiosity is designed to climb and sample. The big attraction is the detection of clays and sulfate minerals in the sediments using multispectral remote sensing. They clearly suggest the influence of water in the formation of the sediments, hence the suggestion that they are lake sediments. On that assumption, Gale Crater is hoped to be a fruitful site for seeking signs of former biological processes: given the technical circumstances of the mission it is deemed the best site there is on Mars for NASA’s Mars Science Laboratory.

Sulfates on Mars have excited geologists enormously, along with their companion clays, because they signify the influence of abundant acid water in the breakdown of Martian primary igneous rocks from which the sediments have undoubtedly been derived. Their formation is undoubtedly the geoscientific ‘sexy beast’ of the last four or five years. Given multi-channel remotely sensed data – and Mars labs are awash with them from several previous missions – sulfates are easy to detect from their distinctive reflectance spectra so there has been abundant pay-back for geologists involved with the Red Planet. But there is water and there is…water. It is hoped to be proved that the depositional medium was standing water or at least abundant subsurface aqueous fluids, which may have lingered for long enough for living organisms to have formed. But there is a possibility that sulfates can form, and so too clays, by superficial weathering processes beneath a humid atmosphere.

English: This oblique, southward-looking view ...
An oblique view of Gale crater showing the landing site and the mound of layered rocks that NASA’s Curiosity rover will investigate. The landing site is outlined in yellow. (Credit: NASA-JPL via Wikipedia)

Erwin Dehouck and  team of French geochemists set out experimentally to recreate conceivable atmospheric and climatic conditions from Mars’s early history to mimic weathering processes (Dehouck, E. et al. 2012. Evaluating the role of sulfide-weathering in the formation of sulfates or carbonates on Mars. Geochimica et Cosmochimica Acta, v. 90, p. 47-63). The experiment involved liquid water and hydrogen peroxide (detected in Mars’s present atmosphere and probably produced photochemically from water vapour) in contact with a CO2 atmosphere.  Martian surface conditions were simulated by evaporation of H2O and H2O2 to mix with dominant CO2, which allowed ‘dew’ to form on the experimental samples. The samples consisted of ground up olivine and pyroxene, important mineral constituents of basalt – feldspar was not used. – mixed with the iron sulfide pyrrhotite, commonly found in terrestrial basalts and meteorites judged to have come from Mars. Samples of each pure mineral and mixtures with the sulfide were left in the apparatus for four years and then analysed in detail.

Even in such a short exposure the silicate-sulfide mixtures reacted to produce sulfate minerals –hexahydrite (MgSO4_6H2O), gypsum (CaSO4_2H2O) and jarosite( KFe3 (OH)6(SO4)2), together with goethite (FeOOH) and hematite (Fe2O3). Without the presence of sulfides, the silicate minerals barely broke down under the simulated Martian conditions but did produce traces of magnesium carbonate. The sulfate bearing assemblages look very like those reported from many locations on Mars. The acid conditions produced by weathering of sulfides to yield sulfate ions are incompatible with preservation of carbonates, as the experiment indicates. However, there are reports of Martian sediments that do contain abundant carbonate minerals.

The researchers’ conclusions are interesting: “These results raise doubts on the need for a global acidic event to produce the sulfate-bearing assemblages, suggest that regional sequestration of sulfate deposits is due to regional differences in sulfide content of the bedrock, and pave the way for reevaluating the likelihood that early sediments preserved biosignatures from the earliest times”. Weathering by dew formation seems quite adequate to match existing observations.

A mighty sag or a big wrench for Mars

MOLA colorized relief map of the western hemis...
Colour-coded relief map of the Thatsis bulge on Mars, with Valles Marineris at left centre (Credit: Goddard Space Flight Center, NASA, via Wikipedia)

In the Solar System topographic features don’t come larger than Valles Marineris on Mars. At between 5 to 10 kilometres deep and extending along a fifth of the planet’s circumference, it makes the Grand Canyon and The Gorge of the Nile look puny.

The base and margins of this stupendous valley contains all manner of evidence for erosion, huge landslips and signs of collapse into voids in Mars’s crust. Much of the erosion on Mars seems to have stemmed from catastrophic floods several billion years ago, though whether they were all of water or if some were volcanic in origin is being debated (Leverington, D.W. 2011. A volcanic origin for the outflow channels of Mars: Key evidence and major implications. Geomorphology, v. 132, p. 51-75 http://www.webpages.ttu.edu/dleverin/leverington_mars_outflow_channels_geomorphology_2011.pdf  , but see http://www.universetoday.com/94367/did-water-or-lava-carve-the-outflow-channels-on-mars/)

It is difficult to imagine anything other than some kind of fault control over the almost straight, roughly east-west trend of Vales Marineris, but the scale suggests, again, an unmatched scale of tectonics. It has long been thought that the massive canyon resulted from extensional rifting that created a major weakness etched out by later erosion and/or collapse into huge subsurface voids in the crust. Yet there is little sign of commensurately large faults, through there are some. But the structure is an integral part of yet another superlative. It is on the eastern flank of the mighty Tharsis bulge on which several humongous volcanoes, including Mons Olympus, developed: perhaps there is a causal link between the two dominating features.

Jeffrey Andrews-Hanna of the Colorado School of Mines in the US has tried to model the bulge-chasm pair, coming to the conclusion that there is little sign of major extension. The finale of his study zeroes-in on the possibility of dominant subsidence producing the structure (Andrews-Hanna, J.C. 2012. The formation of Valles Marineris:  3. Trough formation through super-isostasy, stress, sedimentation, and subsidence.  Journal of Geophysical Research, v. 117, E06002, doi:10.1029/2012JE004059).

In this model, the Tharsis bulge and its associated volcanic province rose so high that on the scale of the planet it must have created a large positive gravitational anomaly. This remains for the most part, but in the Valles Marineris region the crust is now either in isostatic balance or has large negative gravity anomalies, complicated by the fact that the very carving of the canyon system must have resulted in some uplift through unloading. For a while the whole bulge was supported in this gravitationally unstable state by the strength of the Martian lithosphere, and most of it is still in a state of disequilibrium.

Andrews-Hanna’s novel view is that a small amount of extension allowed residual magma to rise in linear zone along the eventual length of Valles Marineris as dykes. The magmas and their heating effect reduced the strength of the lithosphere, locally removing support for the huge load, which subsided. By creating greater slope on the surface of Tharsis the subsidence would have become a focus for both erosion and sedimentation, the increased sedimentary load adding to the subsidence to give the present stupendous depth of the canyons and chasms.

Polski: NASA World Wind - Mars (MOLA Shaded el...
Simulated oblique view of the topography of Valles Marineris looking westwards (Credit: Goddard Space Flight Center, NASA, via Wikipedia)

But this isn’t the only model for the canyon system (Yin, A. Structural analysis of the Valles Marineris fault zone: Possible evidence for large-scale strike-slip faulting on Mars. Lithosphere, v. 4 doi:10.1130/L192.1). An Yin of the University of California used a combination of remote sensing data from Mars Reconnaissance Orbiter and Mars Odyssey to perform detailed lithological and structural mapping  along Valles Marineris. What emerged were several  fault zones up to 2000 km long. Instead of an expected extensional sense of movement they are strike-slip faults, with displacements of the order of 100 km in a left-lateral sense. Yin’s model is that the canyon system bean as a zone of transtensional  deformation: very different from that of Andrews-Hanna. It also begs the question of the underlying tectonic processes, because strike-slip zone on Earth are usually associated with distributed stress from plate tectonics.

Dust: heating or cooling?

In the left image, thin martian clouds are vis...
Mars: with and without dust storms in 2001. Image via Wikipedia

Once every 13 years on average dust blots out most of the surface of Mars turning it into an orange ball. The last such planet-encircling dust storm occurred in 2001, but lesser storms spring up on a seasonal basis. Yet Martian seasons have very different weather from terrestrial ones because of the greater eccentricity of Mars’s orbit, as well as the fact that its ‘weather’ doesn’t involve water. When Mars is closest to the Sun solar heating is 20% greater than the average, for both hemispheres. The approach to that perihelion marks the start of the dust season which last a half the Martian year. Unsurprisingly, the sedimentary process that dominates Mars nowadays is the whipping up and deposition of sand and dust, though in the distant past catastrophic floods – probably when subsurface ice melted – sculpted a volcanic landscape pockmarked with impact craters up to several thousand kilometres across. Waterlain sediments on early Mars filled, at least in part, many of the earlier craters and probably blanketed the bulk of its northern hemisphere that is the lowest part of the planet and now devoid of large craters. Erosion and sedimentation since that eventful first billion years has largely been aeolian. Some areas having spectacular dunes of many shapes and sizes, whereas more rugged surfaces show streamlined linear ridges, or yardangs (http://earth-pages.co.uk/2011/05/08/winds-of-change/), formed by sand blasting. Most of the dust on Mars is raised by high winds in the thin atmosphere sweeping the great plains and basins, and, by virtue of Stokes’s law, the grains are very much smaller than on Earth.

The dustiest times on Earth, which might have blotted out sizeable areas from alien astronomers, in the last million years have been glacial maxima, roughly every 100 ka with the latest 20 ka ago. Layering in the Antarctic ice core records such dust-dominated frigid periods very precisely. Less intricate records formed away from the maximum extent of ice sheets as layers of fine sediment known as loess, whose thickness variations match other proxy records of palaeoclimate nicely. Loess, either in place or redeposited in alluvium by rivers, forms the most fertile soil known – when the climate is warm and moist. The vast cereal production of lowland China and the prairies of North America coincides with loess: it may seem strange but a large proportion of 7 billion living humans survive partly because of dust storms during glacial periods of the past.

Being derived from rock-forming minerals dust carries with it a diverse range of chemical elements, including a critical nutrient common on land but in short supply in ocean water far offshore: iron in the form of oxide and hydroxide coatings on dust particles – the dust coating your car after rain often has a yellow or pinkish hue because of its iron content. Even when the well-known ‘fertilizer’ elements potassium, nitrogen and phosphorus are abundant in surface ocean water, they can not encourage algal phytoplankton to multiply without iron. Today the most remote parts of the oceans have little living in their surface layers because of this iron deficiency. Yet oceanographers and climatologists are pretty sure that this wasn’t always the case. They are confident simply because reducing the amount of atmospheric carbon dioxide and its greenhouse effect to levels that would encourage climate cooling and glacial epochs needed more carbon to be buried on the ocean floors than happens nowadays, and lifeless ocean centres would not help in that.

Dust plume off the Sahara desert over the nort...
Saharan dust carried over the Atlantic Ocean by a tropical cyclone. Image via Wikipedia

At present, the greatest source of atmospheric dust is the Sahara Desert (bartholoet, J. 2012. Swept from Africa to the Sahara. Scientific American, v. 306 (February 2012), p. 34-39). Largely derived from palaeolakes dating from a Holocene pluvial episode, Saharan dust accounts for more than half the two billion metric tonnes of particulate atmospheric aerosols dispersed over the Earth each year. Located in the SE trade-wind belt, the Sahara vents dust clouds across the Atlantic Ocean, most to fall there and contribute dissolved material to the mid-ocean near-surface biome but an estimated 40 million t reaches the Amazon basin, contributing to fertilising the otherwise highly leached tropical rain-forest soils. While over the ocean the high albedo of dust adds a cooling effect to the otherwise absorbent sea surface. Over land the fine particles help nucleate water droplets in clouds and hence encourages rainfall. The climatic functions of clouds and dusts are probably the least known factors in the climatic system, a mere 5% uncertainty in their climatic forcing may mean the difference between unremitting global warming ahead or sufficient cooling by reflection of solar radiation to compensate for the cumulative effects of industrial CO2 emissions.

Recording amounts of dust from marine sediments quantitatively is very difficult and impossible in terrestrial sediments, but superb records tied accurately to time at annual precision exist in ice sheets. Low dust levels in Greenland and Antarctic ice tally well with the so-called ‘Medieval Climate Anomaly’ (a warm period) whereas through the 13th to 19th centuries (the ‘Little Ice Age’) more dust than average circulated in the atmosphere. Crucially, for climate change in the industrial era, there has been a massive spike in dust reaching near-polar latitudes since the close of the 18th century during the period associated with signs of global warming: a counterintuitive relationship, but one that is difficult to interpret. The additional dust may well be a result of massive changes in land use across the planet following industrialised agricultural practices and growing population. There are several  questions: does the additional dust also reflect global warming with which it is correlated, i.e. evaporation of the huge former lakes in the Sahara (e.g. Lake Chad); is the dust preventing additional greenhouse warming that would have taken place had the atmosphere been clearer; is it even the ‘wrong kind of dust’, which may well reflect short-wave solar radiation away but also absorbs the longer wavelength thermal radiation emitted by the Earth’s surface, i.e. an aerosol form of greenhouse warming. Needless to say, neither clouds nor dust can be factored into climate prediction models with much confidence.