Category: Sedimentology and stratigraphy

At the end of the Miocene tectonic uplift in the region of the present Straits of Gibraltar cut the Mediterranean Sea off from the Atlantic. The only water able to flow into the isolated marine basin was that carried by the major rivers: the Rhône, Danube, Dneiper and Nile. Their volume was exceeded by evaporation, so the Mediterranean became more and more salty, eventually almost drying out completely to leave thick evaporite deposits that still underlie its deepest parts. 5.33 Ma ago, the tectonic barrier was breached so that Atlantic water flooded the whole Mediterranean basin. The Zanclean flood at the start of the Pliocene has been rated as the greatest catastrophic event in the Phanerozoic history of the oceans, but just how dramatic it was has previously only been guessed at. Seismic profiles across and along the line of flooding reveal channels several kilometres across, about 200 km long and up to 250 m deep, now filled with debris (Garcia-Castellanos, D. et al. 2009. Catastrophic flood of the Mediterranean after the Messinian salinity crisis. Nature, v. 462, p. 778-781). Using a well-established model of river incision in mountain rivers, the authors have suggested how the flooding proceeded. From an initial trickle when the original barrier subsided below Atlantic sea level, flow grew exponentially over a few thousand years to about three times that of the modern Amazon discharge (~10⁸ m s^-1), at which rate incision reached more than 0.4 m per day. Around 90% of the Mediterranean basin’s entire volume was flooded in a matter of a few months to two years, sea level rising at up to 10 m per day.

Formation of BIFs halted by Sudbury impact

The peculiar story of banded iron formations (BIFs) is one that ‘runs and runs’, as journalists say. Most of the steel on which North American capital was built comes from gigantic BIF deposits around Lake Superior that formed during the Palaeoproterozoic. Apart from a brief return in the Neoproterozoic, associated with conditions peculiar to ‘Snowball Earth’ conditions, the Superior Province BIFs are the last of any consequence. Most geologists look to a gradual shift in the oxygen content of ocean water as photosynthetic life grew to dominate the Earth after about 2.4 Ga, but the BIFs around Lake Superior turn out to be capped by a blanket of ejecta from a massive extraterrestrial impact that formed the Sudbury Complex (Slack, J.F. & Cannon, W.F. 2009. Extraterrestrial demise of banded iron formations 1.85 billion years ago. Geology, v. 37, p. 1011-1014). But how could even a monstrous bolide have changed ocean chemistry so decisively? John Slack and William Cannon of the US Geological Survey believe that the impact was so violent that it resulted in wholesale mixing of oxygen-bearing surface waters with those of the deep ocean. The evidence they cite is a coincident change in the nature of deep-water hydrothermal deposits from sulfide-bearing to those dominated by iron-oxides.

The Sudbury impact produced a crater around 150 to 270 km across (one of the three largest known on Earth), and it is dominated by remelted basaltic rocks so almost certainly struck the Palaeoproterozoic ocean floor. Its ejected debris probably covered almost 2 million km² and is found up to 800 km from Sudbury, Ontario. Yet, even with impact cavitation and massive tsunamis it seems barely feasible that an impact of a size dwarfed by those of the Lunar surface could completely remix the oceans. However, it is likely that in the Palaeoproterozoic continental crust was gathered together in a supercontinent so that tsunamis could scour much of the surrounding ocean. A plume of vaporised seawater may also have scavenged oxygen from the atmosphere. The evidence seems compelling, and another possibility is that Sudbury was not the only impact site…

And another oddity…

That a major climatic warming occurred at the end of the Palaeocene (55 Ma) is now undoubted, as is its probable cause by emission from the ocean floor of vast amounts of methane. Yet oddly the Palaeocene-Eocene Thermal Maximum (PETM) coincides with a brief geomagnetic reversal 53 ka long (Lee, Y.S. & Kodama, K. 2009. A possible link between the geomagnetic field and catastrophic climate at the Paleocene-Eocene thermal maximum. Geology, v. 37, p. 1047-1050). Both events were short, so a coincidence seems unlikely, in the authors’ opinion. They suggest a connection through the massive power imparted to climatic processes by the PETM (at least a terawatt and perhaps orders of magnitude more), including the deep thermohaline circulation of the oceans that did shift during the event. Had they exceeded a threshold power for circulation of the liquid outer core they may have triggered the brief reversal, which quickly reverted to its previous magnetic polarity. Ths association is not unique, detailed magnetic studies of the K-T boundary event at 65 Ma has revealed a similar short reversal spanning the duration of the iridium peak ascribed to the Chicxulub impact. However, Chicxulub delivered a power of the order a year’s solar radiation in about one second: vastly larger than the climate perturbation of the PETM. Are we seeing here a hidden signal of an extraterrestrial impact behind the methane release? Impacts are no longer as popular as they once were…

Banded iron formations from the late Archaean, Palaeoproterozoic, and in a few short time intervals linked with Neoproterozoic tillites, have long fascinated geoscientists with their counterintuitive occurrence at times when the oceans contained little if any oxygen. Anoxic water allows iron to exist in its Fe²⁺ form, thereby able to dissolve readily. The vast thicknesses and masses of BIFs demands an abundance of mobile iron, but being made predominantly of hematite (Fe₂O₃) their formation requires a balancing superabundance of oxygen. Many geochemists believe photosynthesising blue-green bacteria to have excreted oxygen to oxidise soluble iron to Fe³⁺ and precipitate it as the oxide in shallow water. Yet plenty of BIFs show such delicate banding that deep water is implicated. All the BIF paradoxes would be resolved if another mechanism had caused the oxidation and precipitation of iron. A new clue to what that may have been is the discovery of iron-oxide stromatolites in the monster BIF deposits around Lake Superior (Planavsky, N. et al. 2009. Iron-oxidizing microbial ecosystems thrived in late Paleoproterozoic redox-stratified oceans. Earth and Planetary Science Letters, v. 286, p. 230-242). Iron isotopes and rare earth elements are good indicators of redox conditions, and those in the BIFs indicate anoxic waters, so free oxygen was not available. The stromatolites, however, strongly suggest biogenic precipitation of iron oxide, which is possible through the action of specialist Fe-oxidising bacteria. Indeed, filamentous microfossils occur in the stromatolites. That opens the possibility of BIFs having formed by direct bacterial precipitation in the oxygen-free world before the Great Oxidation Event around 2.2 Ga, in the absence of cyanobacteria.

At a stormy meeting in August 2004at the 32nd International Geological Congress in Florence, a rearguard action was mounted by a group of stalwart geologists to thwart an attempt to expunge the last remnant of the stratigraphic divisions inspired by Giovanni Arduino’s work in the 18th century from the minds of all future geologists (see December 2004 issue of EPN). The Quaternary was under siege. Despite the fact that the International Commission on Stratigraphy (ICS) of the IUGS had already prepared the ground for a coup de gras by stating that, “This composite epoch [the “Quaternary”] is not a formal unit in the chronostratigraphic hierarchy”, its defenders seem to have won (Mascarelli, A.L. 2009. Quaternary geologists win timescale vote. Nature, v. 459, p. 624). The ICS voted on 21 May 2009 to formally define the base of the Quaternary at 2.6 Ma when the Earth began to cool, glaciation began in the Northern Hemisphere and stone tools first appeared in Africa (it was formerly set at 1.8 Ma, for no obvious reason) and to pass that to IUGS for ratification. Another minority group is enraged, with rumours of chewed carpets, as the Quaternary has annexed 800 ka of what previously was designated as Pliocene: ‘It’s kind of a land grab’, commented Philip Gibbard, a Quaternary expert from Cambridge University, possibly with a hint of glee. To me, it is a milestone decision that gives a proper place to tool making, bipedal apes – ourselves – which makes a great deal more sense that the absurd notion of the Anthropocene (see Epoch, Age, Zone or Nonsense? in March 2008 issue of EPN), whose base some deluded colleagues are trying to set at the beginning of the Industrial Revolution!

Early signs of oxygen…but in the wrong place
The so-called ‘Great Oxidation Event’ is marked by the first occurrence of iron-oxide bearing subaerial sediments or palaeosols, widely regarded as occurring at around 2400 Ma. That is probably around the time that photosynthesis overtook the rate of oxidation reactions that previously consumed the oxygen that it produced, so that oxygen could build-up continually in the air. But that date is far earlier than the origin of subaerial photosynthesis and oxygenic photosynthesis must have arisen among oceanic bacteria before then, but only those inhabiting shallow water where the sunlight is. Banded iron formations that go back into the Archaean are often cited as evidence for when such photosynthesis got underway. Their dominant mineral hematite probably formed by oxidation of soluble iron-II and combination of iron-III with free biogenic oxygen, presumed by most workers to be in shallow water. Among the oldest hematite-rich formations is the Marble Bar Chert of Western Australia, dated to 3460 Ma (Hoashi, M. et al. 2009. Primary haematite formation in an oxygenated sea 3.46 billion years ago. Nature Geoscience, v. 2, p. 301-306). The hematite crystals in the chert seem to have formed at above 60ºC in ocean-floor hydrothermal springs that were discharging abundant dissolved iron-II. The authors estimate the basin in which the cherts formed to be between 200 to 1000 m deep. Since at such depths photosynthesis would not be possible, they claim that sufficient oxygen was produced by shallow-water photosynthesis to form oxygenated intermediate and deep ocean waters, reminiscent of far later times in Earth’s history. This is a minority view, and hinges on whether or not the hematite did form directly on the sea floor. One possibility is that it could have been precipitated colloidally from iron-II-rich ocean water in the photic zone where early photosynthesisers would be, to sink to the deeper sea floor. Eventually very fine iron oxide might recrystallise.
See also: Konhauser, K. 2009. Deepening the early oxygen debate. Nature Geoscience, v. 2, p. 241-242.

Much to geologists’ surprise seismic surveys and drilling of the Mediterranean basin revealed that it is floored by an immense thickness of evaporite salts, laid down during the Late Miocene about 6 Ma ago (Messinian Stage).  The event has been dubbed the Messinian salinity crisis, and ascribed to the cutting off from the Atlantic of the Mediterranean Sea causing lowering of sea level by evaporation. The formation of the evaporite sequence has been overshadowed by what happened to restore the Mediterranean: a humongous waterfall at the Straits of Gibraltar. New modelling of the salt-forming event has had a technically surprising outcome (Govers, R. Choking the Mediterranean to dehydration: The Messinian salinity crisis. Geology, v. 37, p. 167-170). It suggests that most of the salt body formed before sea level fell. Sea level lowering reduced the load on the sea floor and allowed isostatic uplift to develop a flow barrier at the Straits of Gibraltar, further cutting off resupply of Atlantic water. The other factor seems to have been the effect of sluggish eastward subduction of a lithospheric slab that eventually resulted in subsidence so that the Atlantic could re-flood the Mediterranean basin.

High-resolution remotely sensed data (HiRISE) from the Red Planet is free of charge to registered investigators (it did cost quite a bit to acquire), whereas the Earthly equivalent costing would set you back at least US$25 per square kilometre (for Quickbird. They are wonderfully clear, as Mars’s thin atmosphere causes no haze except during dust storms. They are also in stereo, providing both 3-D views and digital terrain elevation data with a precision of 1 m. HiRISE data have revealed detail equivalent to that from aerial photos of Earth taken from about 5 km above. Not surprisingly, they show a lot of geology, including an area around 500 to 1000 km² with clear signs of layered sediments (Lewis, K.W. et al. 2008. Quasi-periodic bedding in the sedimentary rock record of Mars. Science, v. 322, p. 1532-1535). Where large craters have exposed sequences in their walls it is possible to measure bedding thickness and count individual strata. In Becquerel crater the layering is very regular, comprising two size ranges around 3.6 and 37 m, the second being made up of several of the first sized layers. The two sets of thickness remain consistent through about 300 m of section, so probably represent cyclical processes on Mars. The most likely driving forces are rotational and orbital, as they are for the Earth’s Milankovich climatic pacing. The 10:1 ratio between the two frequencies of bedding is twice that dominating the Milankovich time series (rotational precession and orbital eccentricity). One possibility for the Martian  cycles is the estimated variation of orbital eccentricity on 120 ka, 1.2 Ma and 2.4 Ma timescales, although axial tilt changes through tens of degrees; far more than does that of the Earth’s rotational axis. Thankfully, the authors stick to variations in wind-driven sedimentation to explain the bedding cycles. Changes in insolation on Mars would affect condensation and evaporation of CO₂ ice at the poles, and consequently the density of the atmosphere and its ability to move and deposit sediment. Less fortunately, they suggest water must have been involved to lithify the layers. That hardly seems necessary on a planet with low atmospheric pressure, as unconsolidated wind-blown loess in western China maintains the integrity of its layering with little cementation.

Snowball Earth challenged again

Nobody doubts that in the Neoproterozoic there were several massive climate changes that brought frigid conditions to low latitudes. Some demand that the Earth then entered a runaway cooling because the increased albedo cause by continental ice cover would have reflected away a large amount of solar radiation; the Snowball Earth hypothesis is that the entire planet then became icebound. Evidence for the global glacial epochs is in the form of sediments clearly influenced by deposition of debris carried by ice. Later glacial episodes of Late Ordovician and Carboniferous-Permian age left thin tillites – lithified boulder clay – on glaciated land surfaces in northern and southern Africa and other parts of the southern continents, but the main evidence for the much deeper chills of late Precambrian age are thick piles of sediment studded with dropstones from floating ice. These are glaciomarine diamictites as opposed to tillites. Philip Allen and James Etienne of Imperial College, London and Neftex Petroleum Consultants of Abingdon, UK have paid particular attention to the Neoproterozoic diamictites of Oman (Allen, P.A. & Etienne, J.L 2008. Sedimentary challenge to Snowball Earth. Nature Geoscience, v. 1, p. 817-825). These prime candidates for typical products of low-latitude frigidity are over 1 km thick, and therefore require massive supply of precipitation to drive the large ice flows that could transport such large amounts of sediment. Moreover, within the sequence are many sediments that show little sign of glacial influence yet abundant signs of water transport, such as deltaic bedforms. Other strata are marine and contain ripples formed by wave action; a process that would be impossible with total ice cover. Cyclicity is present, as it is in other Neoproterozoic diamictites. That suggests repeated climate change. Snowball Earth aficionados, and others besides, claim just two and possibly three cryogenic episodes in the Neoproterozoic, but Allen and Young point to the wide range of maximum and minimum ages for those diamictites that are amenable to absolute dating. They suggest that, apart from glaciers being able to develop on land at lower latitudes than in subsequent glacial epochs, the late Precambrian was not ‘special, being merely a period of prolonged climate instability akin to those of later times paced by astronomical factors.

Even for experienced geologists it is always exciting to come across direct and tangible evidence for a concept conceived in the 18^th century Scottish Enlightenment, taken up by James Hutton and immortalised by Charles Lyell as “the present is the key to the past”. The most common are ripple marks, sun cracks and raindrop impressions, usually in sandstones. Now relatively high-energy currents move sands, so that every tide on a beach or in an estuary obliterates the previous tide’s sedimentary structures: it is easy to think of them as somehow being ‘one in a billion’ chance preservations. In fact they are a lot more common than common sense might suggest. That is because photoautotropic bacteria can coat sediment surfaces quite quickly to form biofilms or microbial mats, given the right conditions. They knit the grains together, thereby armouring the structures against erosion to some extent. The October 2008 issue of GSA Today begins with a useful summary of the influence of biofilms in preserving intricate signs of sedimentary processes (Noffke, N. 2008. Turbulent lifestyle: microbial mats on Earth’s sandy beaches – today and 3 billion years ago. GSA Today, v. 18 October issue, p. 4-9). Equally important, the author shows how close examination of Archaean littoral sedimentary structures reveals clear signs of the microbial mats themselves. These are convincing evidence for ancient life, even in the absence of tangible fossil cells (the oldest undisputed fossils date back only about 2 Ga).

The Palaeozoic record of sea-level change

Variations in global sea level shift the positions where different sedimentary facies are deposited, and also shift some aspects of oceanic chemistry. Consequently they have long been of interest to petroleum explorationists because reservoir and source facies will be laid down in different areas as the sea inundates stable continental areas or withdraws from them. Plots of changing sea level can be derived indirectly from seismic sections that reveal on- and off-lapping stratal sequences with detail added from the stratigraphy of such sequences determined in the field or from well logs, and considerable detail is available globally for the Mesozoic and Cenozoic Eras. The Palaeozoic Era is not so well known, and information has been acquired piecemeal but not correlated to time. So, a semiquantitative compilation will be welcomed in many quarters (Haq, B.U. & Schutter, S.R. 2008. A chronology of Paleozoic sea-level changes. Science, v. 322, p. 64-68). The outcome reveals a steady rise, with short term ups and downs, from about modern levels to around 220 m higher through the Cambrian and Ordovician, dropping in late Ordovician times by about 80 m, perhaps due to glaciation at that time. Through the Silurian and Devonian global sea-level stood around 180 m higher than now, with only broad fluctuation, then to fall gradually through the Carboniferous to reach modern levels around 320 Ma.  The Devonian to mid-Carboniferous decline marks the onset of the longest glaciation in Earth’s history, the lasted until the late Permian. The broad shifts have a superimposed short-term eustatic fluctuations, resolved into 172 separable events that vary in amplitude from a few tens of metres to around 125 m. Parts of the record show short-term fluctuations that may correspond to the ~400 ka cycle bound up with Earth’s orbital eccentricity. Yet there is insufficient evidence outside the Carboniferous-Permian glacial epoch to suppose that 400 ka shifts in sea level had a glacial origin

Calibrating the stratigraphic column to absolute time depends, of course, on radiometrically dating geochemically suitable rocks or minerals. Yet there is a range of available methods based on decay of unstable isotopes, such as ¹⁴C, ⁴⁰K, ⁸⁷Rb, ¹⁴⁷Sm, uranium and thorium. All depend on a variety of assumptions, of which that of a constant, well-established half-life is common to all. If all were perfect, several methods applied to the same materials should give the same results. The trouble is, each parent isotope favours different minerals and different compositions of igneous rocks, so that discrepancies in the dates assigned by different methods to the same stratigraphic unit may either be due to disturbance of one isotopic system relative to the other or to the half-life of one (or both) parent isotope being inaccurate. Currently, the two most widely used and best-regarded methods are U-Pb and Ar-Ar, the latter depending on ⁴⁰K being converted to ⁴⁰Ar by neutron bombardment. The first often uses zircons, the second various potassium minerals such as alkali feldspar. Both minerals are magmatic in origin and so the same igneous rock may sometimes be dated by either method or both. It is becoming increasingly clear that the two approaches do not give the same age, which is worrisome at the detailed level permitted by the high precision of each of the methods.

A means of checking the timing parameters for radiometric dating is to compare its results with absolute age determined by a non-radiometric method. The best-calibrated and most widely possible method that does not rely on radioactive decay is based on the astronomical pacing of climate, with its 100, 41, 23 and 19 ka cycles. Analysis of cyclicity in repetitive sedimentary sequences reveals patterns of frequencies that match the astronomical signals. So, within such a sequence it is possible to chart time differences to within a few thousand years. If there are igneous rocks interlayered with the cyclical sediments it should be possible to check their radiometric age differences against the difference determined independently. A Miocene sequence in Morocco has many intercalations of igneous tephras, and therefore provides a crucial test for radiometric approaches (Kuiper, K.F. et al. 2008. Synchronizing rock clocks of Earth history. Science, v. 320, p. 500-504). The team from the University of Utrecht, the Free University of Amsterdam in the Netherlands, and the University of California, dated sanidine (K-feldspar) from the tephras using the Ar-Ar method. This involved using a standard age determined for sanidines from a similar rock type at Fish Canyon in Colorado USA. By turning the approach on its head, i.e. by using astronomically calibrated ages for the samples, they recalculated the age of the Fish Canyon standard. It seems to be 0.65% older than previously thought (from rather dodgy U-Pb dating of  zircons in the Fish Canyon Tuff).

All Ar-Ar ages involve the Fish Canyon standard. So, an underestimate of its age would imply revision of quite a lot of geological events dated by Ar-Ar, especially those that happened abruptly, such as mass extinctions, impacts and magnetic reversals. Using the new standard age puts the K/T boundary event back to 66 Ma from 65.5 Ma. The formerly 251.0 Ma mass extinction at the end of the Permian becomes 252.5 Ma, which coincides better with the outpouring of the Siberian Traps. Similarly, the once 200 Ma end-Triassic extinction, but now possibly 201.6 Ma, links better to the Central Atlantic Magmatic Province outpourings. Quite a stir may be on the horizon, if Kuiper and colleagues’ recalibration is confirmed by similar independent measures.

That radiocarbon dates need to be used with caution is well known, as the amount of ¹⁴C produced by cosmic ray bombardment of atmospheric nitrogen varies markedly over time. Again, the ‘work-around’ involves using non-radiometric ages to calibrate the fluctuating relationship between radiocarbon ages and real time. The data of choice are those from tree-ring analysis, but ice cores also preserve ages with a 1-year precision from their annual layering. The Younger Dryas cold period that interrupted the global deglaciation began when atmospheric ¹⁴C production was high. It was also a tremendously important event in the progress of human migration and perhaps even genetics – population crashes in hard times can have a ‘bottleneck’ effect on evolution. A multinational team has addressed the interrelations between radiocarbon dating, ice-core climate proxy records and tree-ring analysis for this crucial episode (Muscheler, R. et al. 2008. Tree rings and ice cores reveal calibration uncertainties during the Younger Dryas. Nature Geoscience, v. 1, p. 263-267). They combined measures of varying ¹⁴C in tree rings and ¹⁰Be in ice cores, both of which are cosmogenic. Rather than resolving the issue, they discovered that the best marine record of the carbon-cycle during the YD, in the Cariaco basin off Venezuela, has a bias caused by anomalous concentration of ¹⁴C in shallow seawater as the YD began. Their study open the possibility of resolving such changes in the marine C-cycle.

See also: Kerr, R.A. 2008. Two geological clocks finally keeping the same time. Science, v. 320, p.434-435.

The International Commission on Stratigraphy lists 37 Series/Epochs and 85 Stages/Ages in the latest version of the International Stratigraphic Chart for the 11 Systems/Periods of the Phanerozoic. A great battle against ICS’s attempt to extinguish the Quaternary, the only enduring Era originated by Giovanni Arduino (1714-1795) and Johann Gotlob Lehmann (1719-1767), now seems to have ended in a compromise (Kerr, R.A. 2008. A time war over the period we live in. Science, v. 319, p. 402-403). While that vigorous struggle has apparently petered out, the Stratigraphic Commission of the Geological Society of London has launched another by proposing a new Epoch – the Anthropocene. This follow a suggestion by Nobel laureate and chemist Paul Crutzen that the Holocene Epoch ended once humanity made a significant impact on the Earth system (Zalasiewicz, J. and 20 others 2008. Are we now living in the Anthropocene? GSA Today, v.18(ii), p. 4-8).

The device intended by the ICS to mark boundaries between Periods, Epochs and Ages in the Phanerozoic is a symbolic Global Standard Section and Point (GSSP), combining an absolute age definition and a type section. A growing number of boundaries are marked by a physical ‘golden’ spike (not necessarily made of gold) including a plaque engraved with the Period or Age names, welded into the agreed boundary itself. There is good reason for this seemingly odd behaviour; geologists need to have agreed nomenclature and locations so that their discourse can be internationally sensible. It is also a deeply exciting, even exalting moment when any geologist puts her/his finger on a boundary of global significance: and how supremely triumphant actually to wield the hammer that drives the spike home. So much so, that there have been monumental squabbles, some not far short of diplomatic ‘incidents’, about exactly where GSSPs should be placed.

But the whole bureaucratic process has its awkwardly humorous side. There is a proposal that the GSSP for the Pleistocene/Holocene boundary be located in a Greenland ice core. Is that to be in the hole left by the NGRIP core drill at the centre of Greenland, at the depth at which evidence for the warming at the end of the Younger Dryas (11.5 ka) occurs? Or should it be in the core itself – a GSSP in a fridge? Either way, it is going to be difficult to put a finger on that particular boundary Moreover, global warming and the attendant social disruption might remove both. The proposed Anthropocene might have an even stranger GSSP. For a start, when did it begin? An anthropogenic human signature appears clearly in the NGRIP core around 8 ka bp, and at a variety of levels in pollen records, but the GSL’s Stratigraphic Commission wants it to start at the beginning of the Industrial Revolution. Sadly, that is a profoundly diachronous, economic boundary. To make it Eurocentric, as Crutzen suggested, would be a bit non-PC.

Let’s face it, the Holocene is just an interglacial, similar to a great many since 2.4 Ma ago. It is noted only for the brief period in which humanity became separated into two groups: a very small one owning the means of production; the other, initially diverse, being forced to work for the first in order to survive. The Industrial Revolution marked a social simplification into two opposed classes, as clearly defined by Marx, and the increased dominance of human affairs by an inhuman entity called capital. The working through of the contradictions bound up in class society and in capital itself has been largely responsible for the huge environmental changes drawn on by Zalasiewicz et al. It seems our somewhat po-faced authors forget the great many more scholars of human affairs than there are geologists: historians and political economists. Already there are plenty of anthropocentric equivalents of GSSPs in London itself, in the form of its celebrated blue plaques. Historians and political economists might well agree that the rise to dominance of capital – and hence the emergence of rapid environmental change during the uniquely short-lived Anthropocene – began outside the Banqueting Hall on Whitehall at 2.04 pm on Tuesday 30 January 1649 with the separation of the head of the divinely righteous monarch, Charles I, from his body. Ladies and Gentlemen of the SC of the GSL, that is where you place your ‘golden’ spike. However, geology might yet have its say, any time now (and geologists cannot really foretell): a super-volcanic eruption; a comet strike or a cosmic gamma-ray burst. So you had better be quick, if your aim is posterity.

Every introductory geology course hammers home the message that the finer the grains in a sedimentary rock, the lower the energy under which it was deposited. This ‘received wisdom’ links to the ways in which grains move in moving fluids: rolling; bouncing and in suspension. A reductionist view sees this as the influence of Stokes’ Law in the boundary conditions between turbulent and laminar flow, close to the bed of flow and higher up in the fluid respectively. Stokes’ Law is invoked as that explains how spheres falling through fluids reach a steady speed related to the fluid’s viscosity. The larger the radius of the sphere, the greater that settling speed is. For the smaller size ranges settling speed is proportional to the square of the radius (laminar flow conditions), whereas for large objects it is proportional to the square root of radius (turbulent flow).  This nicely explains the upward decreasing grain sizes in graded beds, formed when a mixture of grain sizes settles from moving fluids when their speed slow, as in turbidites and the on the lee sides of sand dunes. Since we often see silts and muds being deposited in low-energy lagoons and estuaries on the coast that too seems to verify the theory. However, muds that contain clay mineral particles are quite different from scaled-down spherical grains: they are platy; often have unbalanced electrical charges and are subject to Brownian motion that helps keep them in suspension.  When clays suspended in fresh river water meet the sea, ions in sea water encourage the plates to clump together as aggregates or floccules that are much larger than the clay particles themselves. Another oddity is that, once deposited, clays are not as easily eroded as uncemented sands, partly due to their hosting biofilms that hold the particles together.

Despite the accepted explanation of mudstones as indicators of past low-energy conditions based on reductionist notions, suspicion of awkward complexity dates back to Henry Clifton Sorby, one of the founders of geology, who suggested that the study of mudstones and shales was a great challenge for sedimentology. In reality there are probably more than 30 parameters that govern the shifting and deposition of muds, many bound up with flocculation. Confidently discussing the true environmental conditions of mudstone deposition is often thwarted by their ease of weathering and by small animals that munch their way through muds to exploit often high contents of organic debris. Even the fissility of shales is a mystery in the field. Now and again, muds do reveal surprises, such as ripples and cross lamination, that surely reflect current action. Only experimentation can throw light on Sorby’s great challenge (Schieber, J. et al. 2007. Accretion of mudstone beds from migrating floccule ripples. Science, v. 318, p. 1760-1763). Schieber and colleagues from MIT and Indiana University used experimental flumes to investigate what happens to clay floccules, seeding the materials with fine hematite grains to show up any bedforms clearly. The muds used were from 5 to 63 mm in size, which produced floccules between 0.1 to 1.0 mm.  Again and again the experiments produced migrating ripples, some like tiny barchan dunes made of clay floccules. The surprise lay in the flow speeds at which they began to form: between 10 to 30 cm s^-1, much the same as those needed to produce sand ripples. Floccules were preserved in the experiments, but since they are made of clay minerals, compaction tends to destroy floccule outlines when mudstones form.

No doubt some fine-grained sedimentary rocks reflect low-energy environments, but without more careful examination of their small-scale features muds formed by energies as high as those involved in producing sandstones and many limestones will go unnoticed. Since mudstones are the most common sedimentary rocks in the geological record, some big surprises are in store.

See also: MacQuaker, J.H.S. & Bohacs, K.M. 2007. On the accumulation of mud. Science, v. 318, p. 1734-1735.

Almost all eukaryote organisms require oxygen to be available in their environment. Therefore the eukaryote cell probably appeared only after oxygen had become a permanent component of the atmosphere and hydrosphere, which itself depended on photosynthetic metabolism outweighing the scavenging of free oxygen by abundant dissolved iron. It also depends on efficient burial of dead organic matter. For the metazoa – multicellular eukaryote animals – the oxygen demand rises with their bulk. The first tangible fossils of metazoans appear in Ediacaran, after the last global glacial episode of the late-Precambrian, around 600 Ma ago.  Apart from the evidence for an oxygen bearing atmosphere after about 2.4 Ga, not much is known about actual levels of oxygen and their changes during the Precambrian. The sudden emergence of the soft-bodied but bulky Ediacaran faunas has been ascribed by many to an equally abrupt rise in the availability of oxygen, on which their evolution must have depended. How that might have occurred has been disputed and pretty vague.

The central requirements to boost oxygen levels are increased photosynthesis – difficult if the period preceding the Ediacaran was one where large tracts of ocean were covered with ice – or increased burial of dead organic matter. The second option is also difficult to imagine if ‘snowball’ conditions had reduced living marine biomass to a very low level. What geoscientists have not been able to grasp, is information on the efficiency with which dead organic matter was buried. Mineralogists and geochemists from the Universities of California (Riverside) and Maine have addressed that aspect from the standpoint of the Precambrian history of clay mineral deposition (Kennedy, M. et al. 2006. Late Precambrian oxygenation; inception of the clay mineral factory. Science, v. 311, p. 1446-1449). If organic matter is buried in porous and permeable  sea-floor sediments, the chances of its metabolism by bacterial action is high. Research on modern sea floor sediments shows that the bulk of organic debris at continental margins is adsorbed onto clay-mineral particles, thereby increasing its chance of preservation over simple incorporation as particles in silt-sized sediment. Kennedy et al. tested the hypothesis that sedimentation in the late-Precambrian changed from dominance by physically weathered micas and other silicates to one more dominated by products of chemical weathering on the continental surface, i.e. clays.

Around 700 Ma, the record of marine strontium isotopes in limestones began a major change towards higher ⁸⁷Sr/⁸⁶Sr ratios, suggesting an increase in the chemical weathering of ancient continental rocks. Australia provides a continuous sequence, from 850 to 530 Ma, of quietly deposited shelf sediments that span this transition and also contain the Ediacaran. Sure enough, the mudstones in the sequence show a distinct increase in swelling clays and kaolinite, implicated in modern preservation of dead organic matter. Rather than an abrupt step, the increase is linear from about 800 Ma, and is matched by similar data from other Precambrian cratons. What might have started this chemical weathering of the land surface? Possibly it was due to a much earlier colonisation of the land than direct evidence suggests.  The DNA-based phylogeny of mosses, fungi, lichens and liverworts – all terrestrial organisms – suggests that they arose between 700 and 600 Ma ago.  All would have contributed organic acids to the process of chemical weathering.  Kennedy et al. model the rate at which free oxygen would have increased as a result of increased deposition of clays, and conclude that between 730 and 500 Ma retention of oxygen in the environment would have increased six-fold. Thereafter, land-based organisms and further colonisation permanently increased weathering, establishing increasingly efficient marine burial of organic debris, and so creating an environment in which metazoans could evolve and radiate. If confirmed by further analyses, this work establishes yet another non-uniformitarian process in the Earth system.